公开(公告)号：US20070037055A1

公开(公告)日：2007-02-15

申请号：US11500363

申请日：2006-08-08

申请人： Yuka Yamada ,  Nobuyasu Suzuki ,  Hidehiro Sasaki

发明人： Yuka Yamada ,  Nobuyasu Suzuki ,  Hidehiro Sasaki

IPC分类号： H01M4/52 ,  B05D5/12

CPC分类号： H01M4/04 ,  B82Y30/00 ,  H01M4/02 ,  H01M4/0421 ,  H01M4/0426 ,  H01M4/38 ,  H01M4/52 ,  H01M4/667 ,  H01M4/8803 ,  H01M4/8867 ,  H01M4/90 ,  H01M2004/021

摘要： The present invention provides an electrochemical electrode wherein transition metal (nickel) nanoparticles are used to form an active layer having a large surface area without using a conductive support while maintaining dispersibility and stability, and a method for producing the same. The present invention provides an electrochemical electrode having a conductive substrate and an active layer formed on the conductive substrate, wherein (1) the active layer has a nickel-containing nanostructured material having a dendritic structure formed by agglomerating a plurality of primary particles, and (2) each primary particle has a core and a shell surrounding the core wherein the core is formed of a nickel nanocrystal and the shell is formed of a nickel oxide film; and the present invention also provides a method for producing such an electrochemical electrode comprising: Step 1 of obtaining nickel nanocrystal particles, Step 2 of obtaining primary particles by forming a nickel oxide film on the surface of each nickel nanocrystal particle, and Step 3 of forming a dendritic structure by agglomerating a plurality of the primary particles by depositing the primary particles substantially perpendicular to a conductive substrate.

摘要翻译： 本发明提供了一种电化学电极及其制造方法，其中使用过渡金属（镍）纳米颗粒形成具有大表面积的活性层而不使用导电载体，同时保持分散性和稳定性。 本发明提供一种电化学电极，其具有形成在导电性基板上的导电性基板和有源层，其中，（1）活性层具有通过使多个一次粒子附聚而形成的树枝状结构的含镍纳米结构材料，（ 2）每个初级颗粒具有芯和围绕芯的壳，其中芯由镍纳米晶体形成，壳由氧化镍膜形成; 本发明还提供一种电化学电极的制造方法，其特征在于，具有：获得镍纳米晶粒子的工序1，在每个镍纳米晶粒子的表面形成氧化镍膜得到一次粒子的工序2， 通过使基本上垂直于导电基底的一次粒子沉积而使多个初级粒子聚集的树枝状结构。

公开(公告)号：US20060243321A1

公开(公告)日：2006-11-02

申请号：US11448917

申请日：2006-06-08

申请人： Yuka Yamada ,  Nobuyasu Suzuki ,  Yasunori Morinaga ,  Hidehiro Sasaki

发明人： Yuka Yamada ,  Nobuyasu Suzuki ,  Yasunori Morinaga ,  Hidehiro Sasaki

IPC分类号： H01L31/00

CPC分类号： B01J35/023 ,  B01J35/004 ,  H01G9/2027 ,  H01M14/005 ,  Y02E10/542 ,  Y02P70/521

摘要： An object of the present invention is to provide a photovoltaic cell that demonstrates a superior photoelectric conversion function. The present invention relates to a photovoltaic cell comprising a semiconductor electrode, an electrolyte and a counter electrode, wherein (1) the semiconductor electrode contains an oxide semiconductor layer having photocatalytic activity, (2) the oxide semiconductor layer contains secondary particles in which primary particles comprising a metal oxide are aggregated, (3) the average particle diameter of the primary particles is from 1 nm to 50 nm, and the average particle diameter of the secondary particles is from 100 nm to 10 μm, and (4) the photovoltaic cell generates electromotive force by radiating light of a wavelength substantially equal to the average particle diameter of the secondary particles onto the semiconductor electrode.

公开(公告)号：US20060001012A1

公开(公告)日：2006-01-05

申请号：US11219714

申请日：2005-09-07

申请人： Nobuyasu Suzuki ,  Yasunori Morinaga ,  Hidehiro Sasaki ,  Yuka Yamada

发明人： Nobuyasu Suzuki ,  Yasunori Morinaga ,  Hidehiro Sasaki ,  Yuka Yamada

IPC分类号： H01B1/00

CPC分类号： C01G45/02 ,  C01P2004/04 ,  C01P2006/40 ,  C23C14/081 ,  C23C14/28 ,  H01M4/8825 ,  H01M4/9016 ,  Y10S977/811

摘要： An object of the present invention is to provide an oxygen reduction electrode having excellent oxygen reduction properties (oxygen reduction catalyst abilities). The present invention encompasses: (1) A method for manufacturing a nanostructured manganese oxide having a dendritic structure formed from an agglomeration of primary particles, wherein the method comprises the steps of: removing components from a target plate that comprises one or more kinds of manganese oxides by irradiating the target plate with laser light in an atmosphere comprising a mixed gas of inert gas and oxygen gas, the content of the oxygen gas in the mixed gas being no less than 0.05% but no more than 0.5% as measured by mass flow rate; and depositing the removed components on a substrate that is opposed to the target plate substantially in parallel to obtain the nanostructured manganese oxide, and (2) an oxygen reduction electrode comprising a nanostructured transition metal oxide having a dendritic structure formed from an agglomeration of primary particles.

公开(公告)号：US20050153198A1

公开(公告)日：2005-07-14

申请号：US11004898

申请日：2004-12-07

申请人： Masa-aki Suzuki ,  Yuka Yamada ,  Nobuyasu Suzuki ,  Yasunori Morinaga ,  Hidehiro Sasaki ,  Tadashi Sotomura

发明人： Masa-aki Suzuki ,  Yuka Yamada ,  Nobuyasu Suzuki ,  Yasunori Morinaga ,  Hidehiro Sasaki ,  Tadashi Sotomura

IPC分类号： H01M4/00 ,  H01M4/86 ,  H01M4/88 ,  H01M4/96

CPC分类号： H01M4/8605 ,  H01M4/8828 ,  H01M4/8875 ,  H01M4/96

摘要： Methods of effectively utilizing yeast-containing waste products generated after yeast use can be applied to absorbing agents, drying agents, soil conditioners, catalysts, and other common applications in the same manner as to charcoal-based materials of other materials by carbonizing the waste product, but a new search was needed in order to broaden the industrial utilization of these products. By supporting a particulate or powdered charcoal-based material obtained by carbonizing a yeast-containing material on an electrically conductive gas-permeable base, an electrode can be obtained that is capable of the electrochemical reduction of oxygen. The present charcoal-based material can provide new applications that have not been hitherto proposed, in the sense that oxygen can be electrochemically reduced smoothly and at a small overvoltage (resistance), and a large electromotive force can be obtained, by placing the charcoal-based material at the intersection of the ion path and the oxygen path.

摘要翻译： 酵母使用后产生的酵母含有废弃物的方法可以以与其他材料的炭基材料相同的方式应用于吸收剂，干燥剂，土壤调理剂，催化剂和其它常用应用，方法是将废物碳化 ，但是为了扩大这些产品的工业利用率，需要进行新的搜索。 通过在导电性透气性基底上含有通过将含酵母的材料碳化而获得的颗粒状或粉末状的炭系材料，能够得到能够进行电化学还原氧的电极。 本发明的炭基材料可以提供迄今为止尚未提出的新应用，在这种意义上，氧可以通过电化学方式平滑地并且以小的过电压（电阻）降低，并且可以获得大的电动势，通过将炭 - 在离子路径和氧气路径的交点处的基体材料。

公开(公告)号：US6024798A

公开(公告)日：2000-02-15

申请号：US76740

申请日：1998-05-13

申请人： Yuka Yamada ,  Ikuo Hiruta

发明人： Yuka Yamada ,  Ikuo Hiruta

IPC分类号： B05B5/00 ,  B05B5/08 ,  B05B13/04 ,  B05D1/12 ,  B22F3/00 ,  G02F1/1339 ,  B05C5/00

CPC分类号： B05B13/0473 ,  B05B13/0468 ,  B05B5/002 ,  B05D1/12 ,  B22F3/004 ,  G02F1/13392 ,  B05B5/08 ,  B22F2999/00

摘要： A substrate placed on a movable table movable in the X-direction and a spreading nozzle swingable in the Y-direction are relatively moved such that an extended line of the center axis of the spreading nozzle draws a zigzag trace on the substrate. During this relative movement, spacers are spread from the spreading nozzle while the substrate is sequentially discharged by a discharging bar in the moving direction of the substrate by a discharging bar. When the spreading nozzle passes each of folded portions where the trace is folded, the spread amount of the spacers from the spreading nozzle is reduced.

摘要翻译： 放置在可沿X方向移动的可移动台上的基板和在Y方向上摆动的扩展喷嘴相对移动，使得扩展喷嘴的中心轴的延伸线在基板上绘制锯齿形迹线。 在这种相对移动期间，间隔物从扩展喷嘴扩散，同时通过放电杆在衬底的移动方向上通过排出杆顺序地排出衬底。 当扩散喷嘴通过折叠部分的折叠部分时，来自扩展喷嘴的间隔物的扩展量减小。

公开(公告)号：US08586262B2

公开(公告)日：2013-11-19

申请号：US13256490

申请日：2010-03-18

申请人： Kuroudo Maeda ,  Takashi Iseki ,  Yuka Yamada ,  Kazuyuki Nakanishi

发明人： Kuroudo Maeda ,  Takashi Iseki ,  Yuka Yamada ,  Kazuyuki Nakanishi

IPC分类号： H01M2/16 ,  B32B15/04 ,  B32B5/00 ,  B21C23/21

CPC分类号： H01M8/0206 ,  C22F1/00 ,  C22F1/008 ,  C22F1/18 ,  C22F1/183 ,  C23C8/44 ,  C23C8/80 ,  C23C16/0272 ,  C23C16/26 ,  C23C28/042 ,  H01M8/0213 ,  H01M8/0228 ,  H01M2008/1095 ,  Y02P70/56 ,  Y10T428/265 ,  Y10T428/31678

摘要： A method of manufacturing a titanium-based material includes: rolling a titanium base material via rolling oil that includes carbon to form a rolling-altered layer that includes titanium carbide on a surface of the base material; and depositing a carbon film on the surface on which the rolling-altered layer has been formed.

摘要翻译： 制造钛基材料的方法包括：通过包含碳的轧制油轧制钛基材料，以在基材的表面上形成包括碳化钛的滚动改变层; 以及在已经形成有滚动变化层的表面上沉积碳膜。

公开(公告)号：US08414758B2

公开(公告)日：2013-04-09

申请号：US13453669

申请日：2012-04-23

申请人： Masahiro Deguchi ,  Satoshi Yotsuhashi ,  Yuka Yamada

发明人： Masahiro Deguchi ,  Satoshi Yotsuhashi ,  Yuka Yamada

IPC分类号： C25B3/04 ,  H01M6/30 ,  H01M8/22

CPC分类号： C25B1/003 ,  C25B1/00 ,  C25B3/04

摘要： A device for reducing carbon dioxide includes a cathode chamber including a cathode electrolyte solution and a cathode electrode, an anode chamber including an anode electrolyte solution and an anode electrode, and a solid electrolyte membrane. The anode electrode includes a nitride semiconductor region on which a metal layer is formed. The metal layer includes at least one of nickel and titanium. A method for reducing carbon dioxide by using a device for reducing carbon dioxide includes steps of providing carbon dioxide into the cathode solution, and irradiating at least part of the nitride semiconductor region and the metal layer with a light having a wavelength of 250 nanometers to 400 nanometers, thereby reducing the carbon dioxide contained in the cathode electrolyte solution.

摘要翻译： 一种二氧化碳还原装置包括阴极室，包括阴极电解质溶液和阴极电极，阳极室包括阳极电解质溶液和阳极电极以及固体电解质膜。 阳极包括形成有金属层的氮化物半导体区域。 金属层包括镍和钛中的至少一种。 通过使用用于还原二氧化碳的装置来还原二氧化碳的方法包括向阴极溶液中提供二氧化碳的步骤，以及使用波长为250纳米至400埃的光照射至少部分氮化物半导体区域和金属层 纳米，从而减少阴极电解质溶液中所含的二氧化碳。

公开(公告)号：US08318374B2

公开(公告)日：2012-11-27

申请号：US12794381

申请日：2010-06-04

申请人： Daisuke Ino ,  Mitsuru Hashimoto ,  Akira Taomoto ,  Nobuyasu Suzuki ,  Yuka Yamada

发明人： Daisuke Ino ,  Mitsuru Hashimoto ,  Akira Taomoto ,  Nobuyasu Suzuki ,  Yuka Yamada

IPC分类号： H01M8/10

CPC分类号： H01M4/8657 ,  H01M4/8605 ,  H01M4/92

摘要： An oxygen electrode used in the fuel cell and includes a plurality of carbon particles, a carbon thin-film, and surface nanostructure. The carbon particles are bonded to one another with the carbon thin-film, and the surface nanostructure is formed on the surface of the carbon thin-film. The surface nanostructure comprises catalyst nanoparticles made of platinum (Pt) and carbon nanoparticles. According to this combination of these elements, the catalyst nanoparticles are confined within three-dimensional structure to be formed by the carbon nanoparticles and are immobilized without losing space which allows any reactant to be accessed to the surface of the catalyst nanoparticles.

摘要翻译： 用于燃料电池中的氧电极，包括多个碳颗粒，碳薄膜和表面纳米结构。 碳颗粒通过碳薄膜彼此结合，并且在碳薄膜的表面上形成表面纳米结构。 表面纳米结构包括由铂（Pt）和碳纳米颗粒制成的催化剂纳米颗粒。 根据这些元素的这种组合，催化剂纳米颗粒被限制在由碳纳米颗粒形成的三维结构内，并且被固定化而不会损失允许任何反应物进入催化剂纳米颗粒表面的空间。

公开(公告)号：US20120231374A1

公开(公告)日：2012-09-13

申请号：US13511175

申请日：2010-12-24

申请人： Takashi Iseki ,  Kazuyuki Nakanishi ,  Yasuhiro Ozawa ,  Yuka Yamada ,  Hajime Hasegawa ,  Masafumi Koizumi ,  Katsutoshi Fujisawa ,  Naoki Ueda ,  Hirohiko Hisano

发明人： Takashi Iseki ,  Kazuyuki Nakanishi ,  Yasuhiro Ozawa ,  Yuka Yamada ,  Hajime Hasegawa ,  Masafumi Koizumi ,  Katsutoshi Fujisawa ,  Naoki Ueda ,  Hirohiko Hisano

IPC分类号： H01M8/02 ,  C23C16/503

CPC分类号： C01B31/02 ,  B82Y30/00 ,  C01B32/05 ,  H01M8/021 ,  H01M8/0228 ,  H01M8/0234 ,  Y02P70/56

摘要： A bipolar plate for a fuel cell comprises a substrate formed of stainless steel; an oriented amorphous carbon film formed at least on a surface of the substrate facing an electrode, and containing C as a main component, 3 to 20 at. % of N, and more than 0 at. % and not more than 20 at. % of H, and when the total amount of the C is taken as 100 at. %, the amount of C having an sp2 hybrid orbital (Csp2) being not less than 70 at. % and less than 100 at. %, and (002) planes of graphite being oriented along a thickness direction; a mixed layer generated in an interface between the substrate and the oriented amorphous carbon film and containing at least one kind of constituent atoms of each of the substrate and the oriented amorphous carbon film; and a plurality of projections protruding from the mixed layer into the oriented amorphous carbon film and having a mean length of 10 to 150 nm.

摘要翻译： 用于燃料电池的双极板包括由不锈钢形成的基板; 至少在面向电极的基板的表面上形成并含有C为主要成分的定向非晶碳膜，3至20at。 N的百分比，超过0。 ％，不超过20。 H的百分比，当C的总量取为100时。 ％，具有sp2混合轨道（Csp2）的C的量不小于70at。 ％和小于100。 ％和（002）面的石墨沿厚度方向取向; 在所述基板和所述取向非晶碳膜之间的界面中产生并且含有所述基板和所述取向非晶碳膜中的至少一种构成原子的混合层; 以及从混合层突出到取向非晶碳膜中并具有10〜150nm的平均长度的多个突起。

公开(公告)号：US20120183887A1

公开(公告)日：2012-07-19

申请号：US13497475

申请日：2010-12-24

申请人： Takashi Iseki ,  Yuka Yamada ,  Kazuyuki Nakanishi ,  Yasuhiro Ozawa ,  Shingo Ohta

发明人： Takashi Iseki ,  Yuka Yamada ,  Kazuyuki Nakanishi ,  Yasuhiro Ozawa ,  Shingo Ohta

IPC分类号： H01M8/02 ,  H01B1/04 ,  H01M4/66 ,  C23C16/26

CPC分类号： C01B31/02 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/05 ,  C01B32/182 ,  C23C16/26 ,  C23C16/503 ,  H01M4/625 ,  H01M4/663 ,  H01M4/96 ,  H01M8/0202

摘要： The oriented amorphous carbon film contains C as a main component, 3 to 20 at. % of N, and more than 0 at. % and not more than 20 at. % of H, and when the total amount of the C is taken as 100 at. %, the amount of C having an sp2 hybrid orbital (Csp2) being not less than 70 at. % and less than 100 at. %, and (002) planes of graphite being oriented along a thickness direction. This film has a novel structure and exhibits a high electric conductivity. This film can be formed by DC plasma CVD method in which an electric discharge is generated by applying a voltage of not less than 1500 V to reaction gas including at least one kind of compound gas selected from gas of a carbocyclic compound containing Csp2 and gas of an N-containing heterocyclic compound containing Csp2, and nitrogen and/or silicon, and nitrogen gas.

摘要翻译： 取向非晶碳膜含有C为主要成分，3〜20at。 N的百分比，超过0。 ％，不超过20。 H的百分比，当C的总量取为100时。 ％，具有sp2混合轨道（Csp2）的C的量不小于70at。 ％和小于100。 ％和（002）面的石墨沿厚度方向取向。 该膜具有新颖的结构并具有高电导率。 该膜可以通过DC等离子体CVD法形成，其中通过施加不低于1500V的电压而产生放电，包括至少一种选自含有Csp2的碳环化合物的气体和 含有Csp2的含氮杂环化合物，氮和/或硅，以及氮气。