Simultaneous coking of residual oil and partial gasification and
desulfurization of coal
    61.
    发明授权
    Simultaneous coking of residual oil and partial gasification and desulfurization of coal 失效
    残油同时焦化和煤的部分气化脱硫

    公开(公告)号:US4511459A

    公开(公告)日:1985-04-16

    申请号:US512509

    申请日:1983-07-11

    IPC分类号: C10G9/32

    CPC分类号: C10G9/32

    摘要: Coking of residual oil and devolatization/partial gasification and desulfurization of solid particulate fuel are carried out in a single reactor. The particulate fuel is burned in a combustion zone in the bottom of the reactor. A bed of particulate fuel is fluidized above the combustion zone with gases rising from the combustion zone. The fluidized bed is maintained at a temperature which cokes the residual oil and volatizes the particulate fuel. A high temperature, low velocity zone is maintained between the combustion zone and the fluidized bed for calcination and desulfurization of the solid fuel.

    摘要翻译: 残留油的焦化和固体颗粒燃料的脱挥发分/部分气化和脱硫在单个反应器中进行。 颗粒燃料在反应器底部的燃烧区燃烧。 颗粒燃料床在燃烧区上流动,气体从燃烧区升起。 流化床保持在一定温度下,该温度会吸附残留的油并使颗粒燃料挥发。 在燃烧区和流化床之间保持高温低速区,用于固体燃料的煅烧和脱硫。

    Production of low-metal and low-sulfur coke from high-metal and
high-sulfur resids
    62.
    发明授权
    Production of low-metal and low-sulfur coke from high-metal and high-sulfur resids 失效
    从高金属和高硫残留物生产低金属和低硫焦炭

    公开(公告)号:US4481101A

    公开(公告)日:1984-11-06

    申请号:US411141

    申请日:1982-08-25

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    摘要: A process for demetallation and desulfurization of resids by visbreaking an admixture of resids, particulate solids, and steam and/or hydrogen, and then subjecting the visbroken mixture to high temperature settling and separating to provide a first vapor product, a liquid product, and a recycled underflow solids stream. The process further comprises coking the liquid product to produce a second vapor product and coke and then distilling the combined first and second vapor products to yield a plurality of demetallized and desulfurized liquid hydrocarbon products. A fraction of the recycled underflow from the settler/separator is removed as a purge stream and burned for recovery of heat and metals. If hydrogen is used in the visbreaking step, the first vapor product is condensed to separate the hydrogen for recycling.

    摘要翻译: 通过减少残渣,颗粒固体和蒸汽和/或氢气的混合物来对残渣进行脱金属脱硫和脱硫的方法,然后将耐磨损的混合物进行高温沉降和分离以提供第一蒸气产物,液体产物和 再循环下流固体物流。 该方法还包括将液体产物焦化以产生第二蒸气产物和焦炭,然后蒸馏合并的第一和第二蒸气产物以产生多个脱金属和脱硫的液体烃产物。 将来自沉降器/分离器的再循环底流的一部分作为吹扫流除去并燃烧以回收热量和金属。 如果在减粘裂化步骤中使用氢气,则将第一蒸气产物冷凝以分离氢气以便再循环。

    Zone combustion of high sulfur coal to reduce SO.sub.x emission
    63.
    发明授权
    Zone combustion of high sulfur coal to reduce SO.sub.x emission 失效
    高硫煤的区域燃烧,以减少SOx排放

    公开(公告)号:US4469032A

    公开(公告)日:1984-09-04

    申请号:US419106

    申请日:1982-09-16

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    IPC分类号: F23B7/00

    CPC分类号: F23B90/06 F23B7/00

    摘要: In the combustion of high sulfur coal, SO.sub.x emission is reduced by pyrolizing the coal in a reducing atmosphere to form char and convert the sulfur compounds to combustible gases including H.sub.2 S. The H.sub.2 S is reacted with the coal and the char to produce ash containing sulfur which is easily removed from the combustion process. A three zone furnace includes a zone in which the coal is pyrolized in a reducing atmosphere to convert the sulfur compounds to combustible gas which reacts with the coal and char.

    摘要翻译: 在高硫煤的燃烧中,通过在还原气氛中热解煤而形成炭,并将硫化合物转化为可燃气体(包括H 2 S)来减少SO x排放。 H 2 S与煤和焦炭反应产生含硫的灰分,其易于从燃烧过程中除去。 三区炉包括在还原气氛中将煤焦化的区域,以将硫化合物转化成与煤和焦炭反应的可燃气体。

    Ion exchange process using resins of high loading capacity, high
chloride tolerance and rapid elution for uranium recovery
    64.
    发明授权
    Ion exchange process using resins of high loading capacity, high chloride tolerance and rapid elution for uranium recovery 失效
    离子交换过程使用高负载能力的树脂,高氯化物耐受性和快速洗脱铀回收

    公开(公告)号:US4418042A

    公开(公告)日:1983-11-29

    申请号:US327395

    申请日:1981-12-04

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    IPC分类号: C22B60/02 C01G56/00

    CPC分类号: C22B60/0265

    摘要: The present invention relates to a process for effectively recovering uranium from dilute solutions, particularly alkaline carbonate leachates from an in-situ leaching process. The uranium complexes are made unstable by adjusting the pH of the leachate to about 6.5 using mineral acids or carbon dioxide. The solution is then passed over ion exchanger resin which induces percipitation of uranium. This non-exchangeable uranium on the resin is then eluted or leached with acid or carbonate solution to obtain eluate of high uranium concentration.

    摘要翻译: 本发明涉及一种从原位浸出法从稀溶液,特别是碱性碳酸盐浸出液中有效回收铀的方法。 通过使用无机酸或二氧化碳将渗滤液的pH调节至约6.5,使铀配合物变得不稳定。 然后将溶液通过离子交换树脂,引起铀的沉淀。 然后用酸或碳酸盐溶液洗脱或浸出树脂上的这种不可交换的铀,以获得高铀浓度的洗脱液。

    Conversion of heavy hydrocarbon oils
    65.
    发明授权
    Conversion of heavy hydrocarbon oils 失效
    重质烃油的转化

    公开(公告)号:US4363717A

    公开(公告)日:1982-12-14

    申请号:US225284

    申请日:1981-01-15

    摘要: This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products.The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

    摘要翻译: 本发明提供了一种将重质烃油升级为机动车燃料产品的方法。 在超临界条件下将重质烃油与金属卤化物催化剂和溶剂组分混合以形成(1)含有精炼烃裂化物的致密气体溶剂相,其基本上不含金属卤化物催化剂含量; 和(2)残留沥青相。

    Liquefaction of solid organic wastes
    67.
    发明授权
    Liquefaction of solid organic wastes 失效
    固体有机废物的液化

    公开(公告)号:US4145188A

    公开(公告)日:1979-03-20

    申请号:US743740

    申请日:1976-11-22

    IPC分类号: C10G1/04 C10L1/18

    CPC分类号: C10G1/04

    摘要: This invention provides a method for solubilizing municipal refuse and other solid organic wastes in a highly aromatic refinery petroleum solvent to produce a homogeneous heavy oil or bitumen composition.

    摘要翻译: 本发明提供了一种在高度芳香族炼油石油溶剂中增溶市政垃圾等固体有机废弃物的方法,以产生均匀的重油或沥青组合物。

    Rejuvenated catalytic oxidation of waste water, particularly for removal
of cyanide and sulfur compounds
    69.
    发明授权
    Rejuvenated catalytic oxidation of waste water, particularly for removal of cyanide and sulfur compounds 失效
    废水的再生催化氧化,特别是用于除去氰化物和硫化合物

    公开(公告)号:US5635078A

    公开(公告)日:1997-06-03

    申请号:US227749

    申请日:1994-04-13

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    摘要: The rejuvenative catalytic oxidation of offensive substances, such as cyanides, sulfides, sulfites, thiosulfates, mercaptans, disulfides, ammonia and mixtures thereof, contained in waste water. The process involves the addition of a low concentration of a metal compound to the waste water to be treated and then passing the waste water along with a source of oxygen over an adsorbent material, thus catalytically oxidizing the offensive substances contained in the waste water. The process reduces the catalytic impact of the loss of metal from the adsorbent material due to leaching and allows the catalyst to be rejuvenated and allows recovery from process upsets in the treating system without unit shutdown and catalyst replacement. An example of the catalytic support is activated carbon and an example of the metal is copper.

    Two phase removal of halides from liquid hydrocarbons cross-reference to
related applications
    70.
    发明授权
    Two phase removal of halides from liquid hydrocarbons cross-reference to related applications 失效
    液相碳氢化合物的两相脱除相互参照相关应用

    公开(公告)号:US5595648A

    公开(公告)日:1997-01-21

    申请号:US367501

    申请日:1994-12-30

    申请人: Tsoung Y. Yan

    发明人: Tsoung Y. Yan

    CPC分类号: C10G19/073

    摘要: Acidic halides, especially chlorides, are removed from dry liquid hydrocarbon streams such as catalytic reformate by contact with large particles of low surface area solid caustic such as a bed of NaOH pellets. Effective neutralization is achieved in a bed which is essentially free of any aqueous phase. Salt formed by the neutralization reaction deposit as solids on the surface of the solid caustic. A process for producing a low chloride, dry reformate product is also disclosed.

    摘要翻译: 通过与大颗粒的低表面积固体苛性碱如NaOH颗粒床接触,将酸性卤化物,特别是氯化物从干燥液体烃流中除去,例如催化重整产物。 在基本上不含任何水相的床中实现有效的中和。 通过中和反应形成的盐作为固体沉积在固体苛性碱的表面上。 还公开了一种生产低氯化物,干重整产品的方法。