利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

142 条记录 (耗时 0.037 秒)

    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof
    62.
    发明授权
    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof 失效

    公开(公告)号：US4418010A

    公开(公告)日：1983-11-29

    申请号：US456979

    申请日：1983-01-10

    申请人： Mark A. Sprecker ,  John B. Hall

    发明人： Mark A. Sprecker ,  John B. Hall

    IPC分类号： A24B15/34 ,  C07C29/09 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C11B9/00

    CPC分类号： C11B9/0042 ,  A24B15/345 ,  C07C29/095 ,  C07C29/172 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C2102/42

    摘要： Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.

    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof
    63.
    发明授权
    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof 失效

    公开(公告)号：US4386023A

    公开(公告)日：1983-05-31

    申请号：US335564

    申请日：1981-12-29

    申请人： Mark A. Sprecker ,  John B. Hall

    发明人： Mark A. Sprecker ,  John B. Hall

    IPC分类号： A24B15/34 ,  C07C29/09 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C11B9/00 ,  A61K7/00

    CPC分类号： C11B9/0042 ,  A24B15/345 ,  C07C29/095 ,  C07C29/172 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C07C2103/60 ,  C07C2103/66

    摘要： Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.

    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof
    64.
    发明授权
    Alkyl esters of 1-alkanoyl cycloalkanols and organoleptic uses thereof 失效
    1-烷酰基环烷醇的烷基酯及其感官用途

    公开(公告)号：US4374055A

    公开(公告)日：1983-02-15

    申请号：US314002

    申请日：1981-10-22

    申请人： Ronald P. Schreck ,  Kenneth K. Light ,  John B. Hall ,  Frederick L. Schmitt ,  Manfred H. Vock ,  William L. Schreiber ,  Joaquin F. Vinals ,  Jacob Kiwala

    发明人： Ronald P. Schreck ,  Kenneth K. Light ,  John B. Hall ,  Frederick L. Schmitt ,  Manfred H. Vock ,  William L. Schreiber ,  Joaquin F. Vinals ,  Jacob Kiwala

    IPC分类号： A24B15/34 ,  C11B9/00 ,  C11D3/50 ,  A61K7/46

    CPC分类号： A24B15/34 ,  C11B9/0026 ,  C11D3/50

    摘要： Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.

    摘要翻译： 描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法：其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基，二甲基或三甲基取代的环烷基部分 环，其中R 3是C 1 -C 3低级烷基，R 4是甲基或氢，通过使具有通式结构的化合物：在高温下具有弱酸性pH的含水银离子溶液中。 如此生产的化合物可用于消费材料如食品，食品香料，口香糖，口香糖调味剂，牙膏，牙膏调味剂，药用产品，药用香料，咀嚼烟草，咀嚼烟草香料，烟草烟草， 吸烟烟草调味剂，香料组合物，香料制品，例如阳离子，阴离子，非离子和两性离子洗涤剂，织物柔软剂组合物，干燥剂添加的织物柔软剂制品，纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl- and alkylidene-cycloalkanones
    66.
    发明授权
    2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl- and alkylidene-cycloalkanones 失效
    2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基 - 环烷酮

    公开(公告)号：US4173585A

    公开(公告)日：1979-11-06

    申请号：US932677

    申请日：1978-08-10

    申请人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    发明人： Takao Yoshida ,  Braja D. Mookherjee ,  Venkatesh Kamath ,  John B. Hall ,  William I. Taylor ,  Frederick L. Schmitt

    IPC分类号： C07C29/17 ,  C07C29/40 ,  C07C33/12 ,  C07C35/21 ,  C07C45/58 ,  C07C45/74 ,  C07C49/21 ,  C07C49/653 ,  C11B9/00 ,  C07C49/46 ,  C07C49/48

    CPC分类号： C07C29/175 ,  C07C29/17 ,  C07C29/40 ,  C07C33/12 ,  C07C35/21 ,  C07C45/58 ,  C07C45/74 ,  C07C49/21 ,  C07C49/653 ,  C11B9/003 ,  C11B9/0034 ,  C07C2101/08 ,  C07C2101/10 ,  C07C2101/14

    摘要： Described are perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing 2,2,3-trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones having the generic structure: ##STR1## wherein one of the lines +++++ is a carbon-carbon double bond and the other of the lines +++++ is a carbon-carbon single bond; wherein X is carbinol having the structure: ##STR2## or carbonyl having the structure ##STR3## wherein A' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; wherein B' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; where n is 0, 1 or 2; wherein each of the dashed lines are the same and each represents a carbon-carbon single bond or no bond; wherein A' and B' are both --CH.sub.2 -- when n is 1 or 2 and the dashed line is a carbon-carbon single bond or A' is hydrogen and B' is C.sub.2 H.sub.5 or CH.sub.3 or both A' and B' are each CH.sub.3 or A' is C.sub.2 H.sub.5 and B' is CH.sub.3 when n is 0 and the dashed line represents no bond, which imparts thereto rich, musky, cedar woody, sandalwood, sweet, floral, ionone-like, soft-fruity (apricot), green and earthy aromas with resinous topnotes and nutty oily nuances. Also described is a process for preparing such compounds according to the reaction schemes: ##STR4## wherein the lines +++++ A', B', the dashed lines and n are as defined above wherein M is alkaline metal.

    摘要翻译： 描述了香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下通用结构的2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮的香水制品， 其中线+++++之一是碳 - 碳双键，另一条线+++++是碳 - 碳单键; 其中X是具有以下结构的甲醇：具有结构的羰基，其中A'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中B'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中n为0,1或2; 其中每个虚线相同并且各自表示碳 - 碳单键或无键; 其中当n为1或2并且虚线为碳 - 碳单键或A'为氢且B'为C 2 H 5或CH 3时，A'和B'均为-CH 2 - ，或者A'和B'均为CH 3 或A'为C 2 H 5，B'为CH 3，n为0，虚线表示无键，赋予其丰富，麝香，雪松木香，檀香，甜，花，紫罗兰酮，软果（杏），绿 和土质的香气与树脂的顶部和坚果油的细微差别。 还描述了根据反应方案制备这些化合物的方法：其中线+++++ A'，B'，虚线和n如上所定义，其中 M是碱金属。

    Soap composition
    67.
    发明授权
    Soap composition 失效
    肥皂组成

    公开(公告)号：US4131557A

    公开(公告)日：1978-12-26

    申请号：US847210

    申请日：1977-10-31

    申请人： John B. Hall ,  Wilhelmus J. Wiegers

    发明人： John B. Hall ,  Wilhelmus J. Wiegers

    IPC分类号： C07C37/14 ,  C07C39/17 ,  C11B9/00 ,  C11D9/44

    CPC分类号： C07C37/14 ,  C11B9/0046 ,  C07C2102/42

    摘要： Described is a soap composition containing as a key ingredient, a mixture of compounds having a sandalwood aroma produced according to a process which comprises:(1) Reacting catechol with camphene in the presence of a Friedel Crafts Catalyst to form a first alkylation product; and then(2) Treating said first alkylation product with hydrogen in the presence of a hydrogenation catalyst, thus forming, initially, diol intermediates and then, on continuing the hydrogenation, the mixture useful in the perfume compositions of our invention.

    摘要翻译： 描述了含有作为关键成分的皂组合物，根据以下方法制备的具有檀香香气的化合物的混合物，其包含：

    Perfume compositions containing catechol-camphene reaction products
    68.
    发明授权
    Perfume compositions containing catechol-camphene reaction products 失效
    含有儿茶酚camp烯反应产物的香料组合物

    公开(公告)号：US4104203A

    公开(公告)日：1978-08-01

    申请号：US846960

    申请日：1977-10-31

    申请人： John B. Hall ,  Wilhelmus Johannen Wiegers

    发明人： John B. Hall ,  Wilhelmus Johannen Wiegers

    IPC分类号： C07C37/14 ,  C07C39/17 ,  C11B9/00

    CPC分类号： C07C37/14 ,  C11B9/0046 ,  C07C2102/42

    摘要： Described is a novel perfume material and cologne containing as a key ingredient a mixture of compounds having a sandalwood aroma prepared by a process which comprises:(1) Reacting catechol with camphene in the presence of a Friedel Crafts Catalyst to form a first alkylation product; and then(2) Treating said first alkylation product with hydrogen in the presence of a hydrogenation catalyst, thus forming, initially, diol intermediates and then, on continuing the hydrogenation, the mixture useful in the perfume compositions of our invention.

    摘要翻译： 描述了一种新颖的香水材料和古龙水，其包含通过以下方法制备的具有檀香香气的化合物的混合物的混合物，该方法包括：

    Process for the production of isosolanone and solanone, intermediates useful in said process and organoleptic uses of said intermediates
    70.
    发明授权
    Process for the production of isosolanone and solanone, intermediates useful in said process and organoleptic uses of said intermediates 失效
    用于生产异溶胶酮和溶胶酮的方法，可用于所述方法的中间体和所述中间体的感官用途

    公开(公告)号：US4609754A

    公开(公告)日：1986-09-02

    申请号：US609348

    申请日：1984-06-22

    申请人： John B. Hall ,  James M. Sanders ,  James N. Siano

    发明人： John B. Hall ,  James M. Sanders ,  James N. Siano

    IPC分类号： A24B15/32 ,  C07C29/40 ,  C07C33/02 ,  C07C45/54 ,  C07C45/67 ,  C07C45/75 ,  C07C49/203 ,  C11D3/50 ,  C07C69/72

    CPC分类号： C11D3/50 ,  A24B15/32 ,  C07C29/40 ,  C07C33/02 ,  C07C45/54 ,  C07C45/67 ,  C07C45/676 ,  C07C45/75 ,  C07C49/203 ,  C07C67/03 ,  C07C69/72

    摘要： Described is a novel genus of compounds defined according to the structure: ##STR1## wherein Z represents hydrogen, MgX and the moiety having the structure: ##STR2## and X represents chlor, bromo, or iodo; as well as 5-isopropyl-8-methyl-5,8-nonadien-2-one; uses of same as intermediates in a process for producing isosolanone and solanone; and organoleptic uses of 5-isopropyl-8-methyl-5,8-nonadien-2-one and 2,6-dimethyl-5-methylene-1-hepten-4-ol.The novel process of our invention involved the steps of:(i) formation of the compound having the structure: ##STR3## by means of reacting 3-methyl-2-methylenebutanal with the compound having the structure: ##STR4## (ii) acid hydrolysis of the resulting compound in order to form 2,6-dimethyl-5-methylene-1-heptene-4-ol;(iii) reaction of 2,6-dimethyl-5-methylene-1-hepten-4-ol with methyl aceto acetate in order to form 2,6-dimethyl-5-methylene-1-hepten-4-yl aceto acetate or, directly, 5-isopropyl-8-methyl-5,8-nonadiene-2-one;(iv) reacting 2,6-dimethyl-5-methylene-1-hepten-4-yl aceto acetate in the presence of an appropriate catalyst to form the 5-isopropyl-8-methyl-5,8-nonadiene-2-one; and(v) isomerizing the 5-isopropyl-8-methyl-5,8-nonadien-2-one in order to form a mixture of solanone and the isosolanone or 5-isopropyl-8-methyl-5,8-nonadiene-2-one.

    摘要翻译： 描述了根据以下结构定义的化合物的新颖属性：其中Z表示氢，MgX和具有以下结构的部分：＆lt; IMAGE＆gt; X表示氯，溴或碘; 以及5-异丙基-8-甲基-5,8-壬二烯-2-酮; 在制备异山芋酮和solanone的方法中使用与中间体相同的物质; 和5-异丙基-8-甲基-5,8-壬二烯-2-酮和2,6-二甲基-5-亚甲基-1-庚烯-4-醇的感官用途。 本发明的新方法涉及以下步骤：（i）通过使3-甲基-2-亚甲基丁醛与具有以下结构的化合物反应形成具有以下结构的化合物：（ⅱ）酸 水解所得化合物以形成2,6-二甲基-5-亚甲基-1-庚烯-4-醇; （iii）2,6-二甲基-5-亚甲基-1-庚烯-4-醇与乙酰乙酸甲酯的反应，以形成2,6-二甲基-5-亚甲基-1-庚烯-4-基乙酸乙酯或 直接得到5-异丙基-8-甲基-5,8-壬二烯-2-酮; （iv）使2,6-二甲基-5-亚甲基-1-庚烯-4-基乙酸乙酯在合适的催化剂存在下反应，形成5-异丙基-8-甲基-5,8-壬二烯-2-酮 ; 和（v）异构化5-异丙基-8-甲基-5,8-壬二烯-2-酮，以形成Solone和二异丙基酮或5-异丙基-8-甲基-5,8-壬二烯-2-酮的混合物 -一。