公开(公告)号：US09126889B2

公开(公告)日：2015-09-08

申请号：US14459375

申请日：2014-08-14

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C11D3/37 ,  C11D3/24 ,  C09D11/00 ,  C07C21/18 ,  C07C57/03 ,  C07C43/178 ,  C07C309/06 ,  C07C323/25 ,  C07C229/12 ,  C08F14/18 ,  C08F214/18 ,  C07C41/03

CPC classification number: C07C19/16 ,  C07C21/18 ,  C07C41/03 ,  C07C43/137 ,  C07C43/1786 ,  C07C57/03 ,  C07C229/12 ,  C07C309/06 ,  C07C323/03 ,  C07C323/25 ,  C08F14/18 ,  C08F214/18

Abstract: To address the problem of insufficient biodegradability of perfluorinated surfactants, the present invention provides biodegradable fluorosurfactants derived from olefins having —CHR, —CHRf, —CHF, and/or —CH2 groups, where R is an alkyl group and Rf is a perfluoro or fluroroalkyl group. Preferably, the —CHR, —CHRf, —CHF, and/or —CH2 groups are contained within partially fluorinated alkenes.

Abstract translation: 为了解决全氟化表面活性剂生物降解性不足的问题，本发明提供了衍生自具有-CHR，-CHRf，-CHF和/或-CH 2基团的烯烃的可生物降解的含氟表面活性剂，其中R是烷基，Rf是全氟或氟烷基 组。 优选地，-CHR，-CHRf，-CHF和/或-CH 2基团包含在部分氟化的烯烃中。

公开(公告)号：US09095737B2

公开(公告)日：2015-08-04

申请号：US13862517

申请日：2013-04-15

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Robert C. Johnson ,  Hsueh S. Tung ,  Rajiv R. Singh ,  Ian Shankland

IPC: A62D1/06 ,  C11D3/43 ,  C11D7/50 ,  C11D11/00 ,  G03F7/42 ,  C09K5/04 ,  B01F17/00 ,  C09K3/00 ,  C09K21/08 ,  C11D7/30 ,  C08J9/14 ,  H05K3/26

CPC classification number: C09K5/044 ,  A62D1/06 ,  B01F17/0035 ,  C08J9/144 ,  C09K3/00 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/102 ,  C09K2205/104 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/126 ,  C10M101/02 ,  C10M171/008 ,  C10M2203/003 ,  C10N2220/302 ,  C10N2240/30 ,  C11D3/43 ,  C11D7/30 ,  C11D7/5018 ,  C11D11/0047 ,  C23G5/02809 ,  C23G5/02825 ,  F25B1/00 ,  F25B31/002 ,  G03F7/426 ,  H05K3/26 ,  Y02C20/30

Abstract: Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO-HFO-1233, or HFO-1354, having properties highly beneficial in foaming and blowing agent applications, articles and methods.

Abstract translation: 基于使用含有3至4个碳原子的氟代烯烃和至少一个碳 - 碳双键的组合物和方法，例如HFO-1214，HFO-HFO-1233或HFO-1354，具有在发泡和 发泡剂应用，物品和方法。

公开(公告)号：US20150175867A1

公开(公告)日：2015-06-25

申请号：US14643500

申请日：2015-03-10

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Robert C. Johnson ,  Hsueh S. Tung ,  Rajiv R. Singh ,  Ian Shankland

IPC: C09K5/04

CPC classification number: C09K5/044 ,  A62D1/06 ,  B01F17/0035 ,  C08J9/144 ,  C09K3/00 ,  C09K5/045 ,  C09K21/08 ,  C09K2205/102 ,  C09K2205/104 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/126 ,  C10M101/02 ,  C10M171/008 ,  C10M2203/003 ,  C10N2220/302 ,  C10N2240/30 ,  C11D3/43 ,  C11D7/30 ,  C11D7/5018 ,  C11D11/0047 ,  C23G5/02809 ,  C23G5/02825 ,  F25B1/00 ,  F25B31/002 ,  G03F7/426 ,  H05K3/26 ,  Y02C20/30

Abstract: Compositions and methods based on the use of fluoroalkene containing from 3 to 4 carbon atoms and at least one carbon-carbon double bond, such as HFO-1214, HFO—HF0-1233, or HF0-1354 having properties highly beneficial in foaming and blowing agent applications, articles and methods.

Abstract translation: 基于使用含有3至4个碳原子的氟代烯烃和至少一个碳 - 碳双键的组合物和方法，例如HFO-1214，HFO-HF0-1233或HF0-1354，其具有在发泡和吹塑中非常有益的性质 代理申请，文章和方法。

公开(公告)号：US20150147280A1

公开(公告)日：2015-05-28

申请号：US14610528

申请日：2015-01-30

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Rajat Basu ,  Leslie Bement ,  Kane Cook ,  Ryan Hulse ,  Gary Knopeck ,  Hang T. Pham ,  Rajiv R. Singh ,  David J. Williams

IPC: C09K5/04 ,  A61K47/06 ,  A61K9/08 ,  C10M131/04 ,  C09K3/00 ,  B01F17/00 ,  C09K3/30 ,  C11D7/50 ,  A61K8/30

CPC classification number: C09K3/30 ,  A61K8/046 ,  A61K8/30 ,  A61K8/34 ,  A61K8/69 ,  A61K9/08 ,  A61K9/124 ,  A61K47/06 ,  A61K2800/10 ,  A61K2800/5922 ,  A61Q5/06 ,  A61Q15/00 ,  A61Q19/00 ,  B01F17/0035 ,  B01F17/0085 ,  C08J9/127 ,  C08J9/144 ,  C08J9/149 ,  C08J2203/06 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2205/052 ,  C08J2375/04 ,  C09K3/00 ,  C09K5/044 ,  C09K2205/12 ,  C09K2205/122 ,  C09K2205/22 ,  C09K2205/32 ,  C10M131/04 ,  C10M2211/022 ,  C10M2211/06 ,  C11D7/261 ,  C11D7/28 ,  C11D7/505 ,  C11D7/5054 ,  C11D7/5081 ,  C11D17/0043 ,  C23G5/02809 ,  C23G5/02825

Abstract: An azeotrope-like mixture consisting essentially of chlorotrifluoropropene and at least one component selected from the group consisting of a C1-C3 alcohol, a C5-C6 hydrocarbon, a halogenated hydrocarbon, methylal, methyl acetone, water, nitromethane, and combinations thereof.

Abstract translation: 基本上由氯三氟丙烯和至少一种选自C 1 -C 3醇，C 5 -C 6烃，卤代烃，甲缩醛，甲基丙酮，水，硝基甲烷及其组合的组分组成的类共沸混合物。

公开(公告)号：US20150065746A1

公开(公告)日：2015-03-05

申请号：US14459375

申请日：2014-08-14

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C309/20 ,  C07C21/18 ,  C07C57/03 ,  C07C43/178 ,  C07C323/58 ,  C07C229/30

CPC classification number: C07C19/16 ,  C07C21/18 ,  C07C41/03 ,  C07C43/137 ,  C07C43/1786 ,  C07C57/03 ,  C07C229/12 ,  C07C309/06 ,  C07C323/03 ,  C07C323/25 ,  C08F14/18 ,  C08F214/18

Abstract: To address the problem of insufficient biodegradability of perfluorinated surfactants, the present invention provides biodegradable fluorosurfactants derived from olefins having —CHR, —CHRf, —CHF, and/or —CH2 groups, where R is an alkyl group and Rf is a perfluoro or fluroroalkyl group. Preferably, the —CHR, —CHRf, —CHF, and/or —CH2 groups are contained within partially fluorinated alkenes.

Abstract translation: 为了解决全氟化表面活性剂生物降解性不足的问题，本发明提供了衍生自具有-CHR，-CHRf，-CHF和/或-CH 2基团的烯烃的可生物降解的含氟表面活性剂，其中R是烷基，R f是全氟或氟烷基 组。 优选地，-CHR，-CHRf，-CHF和/或-CH 2基团包含在部分氟化的烯烃内。

公开(公告)号：US20140366540A1

公开(公告)日：2014-12-18

申请号：US14474814

申请日：2014-09-02

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Gary Zyhowski ,  Ryan J. Hulse ,  Haridasan K. Nair ,  David Nalewajek ,  Rajiv R. Singh

IPC: C09K5/04 ,  C07C21/18 ,  F01K25/08

Abstract: Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R1, R2, R3, and R4 are each independently selected from the group consisting of: H, F, Cl, Br, and C1-C6 alkyl, at least C6 aryl, at least C3 cycloalkyl, and C6-C15 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.

Abstract translation: 本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H ，F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷芳基，其中式（I）含有至少一个 F和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。 工作流体在兰金循环系统中有用，可有效地将工业过程产生的废热（如燃料电池的发电）转化为机械能或进一步电力。 本发明的工作流体也可用于采用其它热能转换过程和循环的设备中。

公开(公告)号：US08791309B2

公开(公告)日：2014-07-29

申请号：US14099560

申请日：2013-12-06

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C17/00 ,  C07C17/23

CPC classification number: C07C17/23 ,  C07C17/25 ,  C07C21/22

Abstract: In accordance with the present invention, processes of synthesizing 3,3,3-trifluoropropyne from 1,3,3,3-tetrafluoropropene, 1-chloro-3,3,3-trifluoropropene, and/or 1,1,1,3,3-pentafluoropropane are provided.

Abstract translation: 根据本发明，从1,3,3,3-四氟丙烯，1-氯-3,3,3-三氟丙烯和/或1,1,1,3,3-四氟丙烯合成3,3,3-三氟丙炔的方法 ，提供3-五氟丙烷。

公开(公告)号：US20140179961A1

公开(公告)日：2014-06-26

申请号：US14099560

申请日：2013-12-06

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C17/23

CPC classification number: C07C17/23 ,  C07C17/25 ,  C07C21/22

Abstract: In accordance with the present invention, processes of synthesizing 3,3,3-trifluoropropyne from 1,3,3,3-tetrafluoropropene, 1-chloro-3,3,3-trifluoropropene, and/or 1,1,1,3,3-pentafluoropropane are provided.

Abstract translation: 根据本发明，从1,3,3,3-四氟丙烯，1-氯-3,3,3-三氟丙烯和/或1,1,1,3,3-四氟丙烯合成3,3,3-三氟丙炔的方法 ，提供3-五氟丙烷。

公开(公告)号：US20220112349A1

公开(公告)日：2022-04-14

申请号：US17506581

申请日：2021-10-20

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Rajiv R. Singh ,  David J. Williams ,  Robert G. Richard

IPC: C08J9/14 ,  C08G18/08 ,  C08G18/48 ,  C08G18/76

Abstract: This invention relates to compositions and methods which make advantageous use of vinylidene fluoride (CH2═CF2), and in particular embodiments, to heat transfer fluids and heat transfer methods, blowing agents, and thermoplastic foams which utilize vinylidene fluoride (CH2═CF2). Compositions of the present invention include from about 0.1 to about 60 percent, on a weight basis, of a co-agent and from about 99.0 to about 40 percent, on a weight basis, of vinylidene fluoride (CH2═CF2).

公开(公告)号：US20210300846A1

公开(公告)日：2021-09-30

申请号：US17221314

申请日：2021-04-02

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Rajiv R. Singh ,  Hang T. PHAM ,  Gary KNOPECK

IPC: C07C19/08 ,  C07C19/10 ,  C07C21/18 ,  C09K3/30 ,  C09K5/04

Abstract: Various compostions, including particularly aerosol compositions, containing fluorinated olefins, including particularly tetra- and penta-fluorpropenes, in a variety of applications are disclosed.