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61.发明申请公开(公告)号：US20090275788A1
公开(公告)日：2009-11-05
申请号：US12447096
申请日：2007-11-09
IPC分类号： C07C5/10
CPC分类号： B01J21/08 , B01J21/12 , B01J23/26 , B01J23/30 , B01J23/32 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/48 , B01J23/72 , B01J23/74 , B01J23/75 , B01J27/185 , B01J35/002 , B01J35/0066 , B01J35/008 , B01J35/06 , B01J35/10 , B01J35/1009 , B01J37/0207 , B01J37/06 , B01J37/28 , B01J37/30 , C07C5/02 , C07C5/10 , C07C2521/12 , C07C2523/30 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2523/75 , C10G45/52 , C07C13/18
摘要： Hydrogenation processes using a catalyst composition which, preferably comprises a glass substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface. A substantially nonporous substrate has (i) a total surface area between about 0.01 m2/g and 10 m2/g; and (ii) a predetermined isoelectric point (IEP) obtained in a pH range greater than 0, preferably greater than or equal to 4.5, or more preferably greater than or equal to 6.0, but less than or equal to 14. At least one catalytically-active region may be contiguous or discontiguous and has a mean thickness less than or equal to about 30 nm, preferably less than or equal to 20 nm and more preferably less than or equal to 10 nm. Preferably, the substrate is a glass composition having a SARCNa less than or equal to about 0.5.
摘要翻译： 使用催化剂组合物的氢化方法，催化剂组合物优选包含玻璃基底，其中一个或多个功能性表面活性成分集成在基底表面上和/或基底表面。 基本上无孔基材具有（i）约0.01m 2 / g至10m 2 / g之间的总表面积; 和（ii）在大于0，优选大于或等于4.5，或更优选大于或等于6.0，但小于或等于14的pH范围内获得的预定等电点（IEP）。至少一种催化 活性区域可以是连续的或不连续的，并且具有小于或等于约30nm，优选小于或等于20nm，更优选小于或等于10nm的平均厚度。 优选地，基底是具有小于或等于约0.5的SARCNa的玻璃组合物。
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62.发明授权Apparatus and process for the synthesis of hydrogen peroxide directly from hydrogen and oxygen 失效用于直接从氢和氧合成过氧化氢的装置和方法公开(公告)号：US07115192B1
公开(公告)日：2006-10-03
申请号：US10309725
申请日：2002-12-04
申请人： Kurt M. Vanden Bussche , Anil R. Oroskar , Jeffery C. Bricker , Laszlo T. Nemeth , Gavin P. Towler
发明人： Kurt M. Vanden Bussche , Anil R. Oroskar , Jeffery C. Bricker , Laszlo T. Nemeth , Gavin P. Towler
IPC分类号： C25B9/10 , B01J10/00 , C25B1/10 , C01B15/029
CPC分类号： B01J8/025 , B01F5/0057 , B01F15/0201 , B01J10/007 , B01J19/002 , B01J2219/00013 , B01J2219/00263 , B01J2219/00889 , C01B15/029 , C07D223/10 , C07D301/12 , C07D313/04
摘要： A device is disclosed for the generation of hydrogen peroxide. The device produces hydrogen peroxide on an as-needed basis through the use of electrolysis of water, remixing hydrogen and oxygen in an appropriate ratio, and reacting the hydrogen and oxygen in water in a reactor.
摘要翻译： 公开了用于产生过氧化氢的装置。 该设备通过使用水的电解，以适当的比例重新混合氢气和氧气，并在反应器中使氢气和氧气在水中反应，根据需要生产过氧化氢。
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公开(公告)号：US06358400B1
公开(公告)日：2002-03-19
申请号：US09318089
申请日：1999-05-25
IPC分类号： C10G3509
CPC分类号： C10G35/065
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a large-pore molecular-sieve catalyst containing a uniformly distributed platinum-group metal component, and a tin component incorporated into the large-pore molecular sieve by secondary synthesis. The use of this catalyst results in greater selectivity of conversion of paraffins to aromatics and in improved catalyst stability.
摘要翻译： 通过使用含有均匀分布的铂族金属组分的大孔分子筛催化剂和通过二次合成掺入大孔分子筛中的锡组分，可以选择性地将烷烃脱氢环化到芳族化合物的重整方法。 使用该催化剂导致链烷烃转化为芳族化合物和提高催化剂稳定性的更大选择性。
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64.发明授权Layered catalyst composition and processes for preparing and using the composition 有权分层催化剂组合物和制备和使用该组合物的方法公开(公告)号：US06280608B1
公开(公告)日：2001-08-28
申请号：US09580136
申请日：2000-05-30
申请人： Robert H. Jensen , Jeffery C. Bricker , Qianjun Chen , Masaru Tatsushima , Kenji Kikuchi , Masao Takayama , Koji Hara , Isao Tsunokuma , Hiroyuki Serizawa
发明人： Robert H. Jensen , Jeffery C. Bricker , Qianjun Chen , Masaru Tatsushima , Kenji Kikuchi , Masao Takayama , Koji Hara , Isao Tsunokuma , Hiroyuki Serizawa
IPC分类号： C10G4500
CPC分类号： B01J23/626 , B01J23/40 , B01J29/06 , B01J29/7007 , B01J37/0219 , B01J37/0242 , B01J37/0246 , Y10T428/2991 , Y10T428/2993
摘要： This invention relates to a layered catalyst composition, a process for preparing the composition and processes for using the composition. The catalyst composition comprises an inner core such as alpha-alumina, and an outer layer bonded to the inner core composed of an outer refractory inorganic oxide such as gamma-alumina. The outer layer has uniformly dispersed thereon a platinum group metal such as platinum and a promoter metal such as tin. The composition also contains a modifier metal such as lithium. The catalyst composition shows improved durability and selectivity for dehydrogenating hydrocarbons.
摘要翻译： 本发明涉及层状催化剂组合物，制备组合物的方法和使用该组合物的方法。 催化剂组合物包含内核如α-氧化铝，和外层结合到内核，由外部难熔无机氧化物如γ-氧化铝组成。 外层在其上均匀分散有铂族金属如铂和助催化剂金属如锡。 该组合物还含有改性金属如锂。 催化剂组合物显示改进的耐久性和对于脱氢烃的选择性。
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65.发明授权Caustic free liquid/liquid process for sweetening a sour hydrocarbon fraction 失效无酸液体/液体方法，用于使酸性烃馏分变甜
公开(公告)号：US5093296A
公开(公告)日：1992-03-03
申请号：US572824
申请日：1990-08-27
CPC分类号： B01J31/0239 , B01J31/183 , B01J2531/025 , B01J2531/845
摘要： This invention relates to a liquid-liquid process for treating a sour hydrocarbon fraction. The process comprises contacting the hydrocarbon fraction in the presence of an oxidizing agent with an aqueous solution containing ammonium hydroxide, a metal chelate and an onium compound selected from the group consisting of quaternary ammonium, phosphonium, arsonium, stibonium, oxonium and sulfonium compounds. A preferred onium compound is a quaternary ammonium compound with an especially preferred compound being a quaternary ammonium halide. This invention also relates to a catalyst comprising an aqueous solution containing ammonium hydroxide, a metal chelate and an onium compound, for oxidizing mercaptans contained in a sour hydrocarbon fraction. The aqueous solution which is the catalyst can also be used to improve the activity of a fixed bed mercaptan oxidation catalyst.
摘要翻译： 本发明涉及一种用于处理酸性烃馏分的液 - 液方法。 该方法包括在氧化剂存在下将烃馏分与含有氢氧化铵的水溶液，金属螯合物和选自季铵，鏻，砷，锑，氧鎓和锍化合物的鎓化合物接触。 优选的鎓化合物是季铵化合物，特别优选的化合物是季铵卤化物。 本发明还涉及包含含有氢氧化铵的水溶液，金属螯合物和鎓化合物的催化剂，用于氧化含在酸性烃馏分中的硫醇。 作为催化剂的水溶液也可用于提高固定床硫醇氧化催化剂的活性。
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66.发明授权
公开(公告)号：US5064525A
公开(公告)日：1991-11-12
申请号：US657013
申请日：1991-02-19
IPC分类号： B01J23/755 , B01J21/16 , B01J31/02 , B01J31/22 , C10G27/06 , C10G27/10 , C10G45/06 , C10G45/08 , C10G67/12
摘要： This invention relates to a process for sweetening a sour hydrocarbon fraction. The process involves two steps. In one step the mercaptans in the sour hydrocarbon fraction are reacted with hydrogen in the presence of a selective hydrogenolysis catalyst to selectively hydrogenolyse the tertiary mercaptans. In another step, the mercaptans are oxidized by reacting them with an oxidizing agent in the presence of oxidation catalyst and a basic component. The selective hydrogenolysis step and the oxidation step may be carried out in any order, i.e., either hydrogenolysis first followed by oxidation or vice versa.
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67.发明授权
公开(公告)号：US4992157A
公开(公告)日：1991-02-12
申请号：US441869
申请日：1989-11-27
IPC分类号： C10G45/22
CPC分类号： C10G45/22
摘要： This invention relates to a process for improving the color and color stability of a hydrocarbon fraction. The process involves contacting the hydrocarbon fraction with a selective hydrogenation catalyst in the presence of hydrogen at reaction conditions. This results in the selective hydrogenation of conjugated unsaturates, thereby improving the color and color stability of the hydrocarbon fraction. The process uses small quantities of hydrogen and is run under mild conditions. A preferred selective hydrogenation catalyst is sulfided nickel on an alumina/clay support.
摘要翻译： 本发明涉及一种改进烃馏分的颜色和颜色稳定性的方法。 该方法包括在反应条件下在氢存在下使烃馏分与选择性氢化催化剂接触。 这导致共轭不饱和物的选择性氢化，从而提高烃馏分的颜色和颜色稳定性。 该方法使用少量氢气，并在温和条件下运行。 优选的选择性氢化催化剂是氧化铝/粘土载体上的硫化镍。
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公开(公告)号：US4705620A
公开(公告)日：1987-11-10
申请号：US942147
申请日：1986-12-16
IPC分类号： C10G11/00 , B01D53/48 , B01D53/86 , B01J23/44 , B01J31/22 , C07B61/00 , C07C67/00 , C07C313/00 , C07C319/06 , C07C321/02 , C10G19/02 , C10G19/08 , C10G53/02 , C10G19/00 , C10G45/00
摘要： A process is disclosed for treating a sour hydrocarbon stream comprising extracting the mercaptans contained in said hydrocarbon stream with an alkaline solution in an extraction zone, oxidizing the mercaptans to disulfides in the presence of an oxidation catalyst, separating said disulfide from said alkaline solution, reducing the residual disulfides in said alkaline solution to mercaptans and recycling said alkaline solution to the extraction zone. Two ways are disclosed to effect the reduction of the disulfides to mercaptans: (1) hydrogenation with a supported metal catalyst and (2) electrochemical reduction.
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