Crystalline phosphorus-containing molecular sieves
    61.
    发明授权
    Crystalline phosphorus-containing molecular sieves 失效
    结晶含磷分子筛

    公开(公告)号:US06379646B1

    公开(公告)日:2002-04-30

    申请号:US08877267

    申请日:1997-06-17

    申请人: Stephen J. Miller

    发明人: Stephen J. Miller

    IPC分类号: C01B3708

    摘要: Molecular sieves comprising (1) phosphorus oxide; (2) a first oxide comprising an oxide of silicon, germanium or mixtures thereof; and (3) a second oxide comprising an oxide of aluminum, boron or mixtures thereof, said molecular sieve having a mole ratio of the first oxide to the second oxide of greater than 1, containing at least about 10 weight percent phosphorus oxide in the crystal framework, and having pores greater than 5 Å in diameter are useful as catalysts in hydrocarbon conversion reactions.

    摘要翻译: 分子筛包含(1)氧化磷; (2)包含硅,锗或其混合物的氧化物的第一氧化物; 和(3)包含铝,硼或其混合物的氧化物的第二氧化物,所述分子筛具有大于1的第一氧化物与第二氧化物的摩尔比,其含有至少约10重量%的晶体中的氧化磷 骨架,直径大于5埃的孔可用作烃转化反应中的催化剂。

    Method of isomerizing olefins
    62.
    发明授权
    Method of isomerizing olefins 失效
    烯烃异构化方法

    公开(公告)号:US5801293A

    公开(公告)日:1998-09-01

    申请号:US780197

    申请日:1997-01-10

    申请人: Stephen J. Miller

    发明人: Stephen J. Miller

    IPC分类号: C07C5/27 C07C41/06 C07C41/42

    摘要: The invention includes a method for skeletal isomerization of C.sub.4-5 olefins. The method includes contacting in a FCC zone, at FCC conditions, an n-C.sub.4-5 olefins-containing etherification zone raffinate, with an FCC catalyst, where at least a portion of the n-C.sub.4-5 olefins in the n-C.sub.4-5 olefins-containing etherification zone raffinate are converted to iso-C.sub.4-5 olefins.

    摘要翻译: 本发明包括C4-5烯烃的骨架异构化方法。 该方法包括在FCC条件下,在含有n-C4-5烯烃的醚化萃取区萃余液的FCC区域中与FCC催化剂接触,其中n-C4-烯烃中的至少一部分n- 含烯烃的醚化区萃余液转化为异C4-5烯烃。

    Method for controlling multistage reforming process to give high octane
barrel per calendar day throughput
    65.
    发明授权
    Method for controlling multistage reforming process to give high octane barrel per calendar day throughput 失效
    用于控制多级重整过程的方法,以在每个日历日期之前提供高OCTONBARREL

    公开(公告)号:US5171691A

    公开(公告)日:1992-12-15

    申请号:US488155

    申请日:1990-03-02

    IPC分类号: C10G35/24

    CPC分类号: C10G35/24 Y10T436/12

    摘要: A method is provided of selecting operating parameters for a reforming process having at least penultimate and final reforming stages, each containing a respective catalyst, for optimum OB/CD production of product reformate having a selected RON and/or over a particular run length. The catalyst lives are determined at constant LHSV for the penultimate and final stage catalysts for a give feed octane to each stage as a function of the change in RON from that of the feed to that of the C.sub.5 + effluent from the respective stage. The penultimate stage C.sub.5 + effluent RON is selected to be such that the lives of the catalysts in each stage are substantially equal. Preferably the yield of C.sub.5 + effluent from each stage and the life of the catalyst used in each stage is determined as a function of the reforming pressure of that stage. The operating pressures of the stages are then selected to be within about 30% of that which gives the highest OB/CD.

    摘要翻译: 提供了一种选择具有至少倒数第二和最后重整阶段的重整工艺的操作参数的方法,每个重整步骤包含相应的催化剂,以获得具有选定RON和/或特定流程长度的产物重整产物的最佳OB / CD生产。 催化剂寿命以恒定的LHSV确定,用于从每个阶段给出进料辛烷至每个阶段的反应物和最终阶段催化剂,作为从进料到从相应阶段的C5 +流出物的RON变化的函数的函数。 选择倒数第二级C5 +流出物RON使得每个阶段的催化剂的寿命基本相等。 优选地,每个阶段的C5 +流出物的产率和每个阶段中使用的催化剂的寿命作为该阶段的重整压力的函数来确定。 然后将级的操作压力选择为提供最高OB / CD的操作压力的约30%。

    Dehydrocyclization or catalytic reforming sulfur tolerant zeolite
catalyst
    66.
    发明授权
    Dehydrocyclization or catalytic reforming sulfur tolerant zeolite catalyst 失效
    脱氢或催化重整硫醇耐沸虫催化剂

    公开(公告)号:US5169813A

    公开(公告)日:1992-12-08

    申请号:US488332

    申请日:1990-03-02

    摘要: A process is provided for catalytic reforming or dehydrocyclization of hydrocarbons using a catalyst comprising a noble metal, and an intermediate pore size crystalline silicate having a high silica to alumina ratio and a relatively low alkali content. Preferably, the crystalline silicate is in the form of small crystallite size, such as less than 5 microns. The reforming or dehydrocyclization process is sulfur tolerant so that the reforming can be carried out in the presence of sulfur or with periodic exposure to sulfur.

    摘要翻译: 提供了使用包含贵金属的催化剂和具有高二氧化硅与氧化铝比和较低碱含量的中等孔径的结晶硅酸盐进行烃的催化重整或脱氢环化的方法。 优选地,结晶硅酸盐为微晶尺寸小的形式,例如小于5微米。 重整或脱氢环化方法是耐硫的,因此重整可以在硫的存在下或者周期性地暴露于硫下进行。

    Hydrogenation of a hydrocrackate using a hydrofinishing catalyst
comprising palladium
    70.
    发明授权
    Hydrogenation of a hydrocrackate using a hydrofinishing catalyst comprising palladium 失效
    使用包含钯的加氢精制催化剂氢化加氢裂化剂

    公开(公告)号:US4673487A

    公开(公告)日:1987-06-16

    申请号:US826941

    申请日:1986-02-06

    申请人: Stephen J. Miller

    发明人: Stephen J. Miller

    CPC分类号: B01J23/8966 C10G45/10

    摘要: An improved nickel-tin hydrogenation catalyst additionally comprising palladium provides a highly active catalyst more easily activated than conventional nickel hydrogenation catalysts, and a process employing the improved catalyst to stabilize lubricating oils to ultraviolet radiation is disclosed.

    摘要翻译: 另外包含钯的改进的镍 - 锡氢化催化剂提供了比常规镍氢化催化剂更容易活化的高活性催化剂,并且公开了使用改进的催化剂将润滑油稳定到紫外线辐射的方法。