公开(公告)号：US10011777B2

公开(公告)日：2018-07-03

申请号：US14054288

申请日：2013-10-15

申请人： Virginia M. Roberts ,  Michel Daage ,  Kun Wang

发明人： Virginia M. Roberts ,  Michel Daage ,  Kun Wang

IPC分类号： C07C1/32 ,  C10G3/00 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J29/70 ,  B01J29/74 ,  B01J29/76 ,  C10G45/02 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10 ,  C10G45/12

CPC分类号： C10G3/50 ,  B01J23/02 ,  B01J23/04 ,  B01J23/10 ,  B01J29/703 ,  B01J29/7046 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7661 ,  B01J29/7692 ,  C10G3/44 ,  C10G3/45 ,  C10G45/02 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10 ,  C10G45/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10G2300/302 ,  C10G2300/305 ,  C10G2300/307 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/10 ,  Y02P30/20

摘要： Systems and methods are provided for processing a feed derived from a biomass source that contains nitrogen in the form of fatty amides, e.g., derived from hydrothermal processing of a biomass source feed, while reducing/minimizing the amount of heteroatom removal performed during subsequent/concurrent hydroprocessing. Optionally, the feed can also contain free fatty acids. This is accomplished in part by first exposing the feed to a catalyst comprising a rare earth oxide, alkali oxide, and/or alkaline earth oxide, which can remove the nitrogen heteroatoms from the compounds within the feed or can convert the nitrogen to a form readily removed in subsequent hydroprocessing. The catalyst may also suitable for catalyzing coupling (such as condensation) or conversion reactions of amides, carboxylic acids, carboxylic acid derivatives, and/or other molecules in the feed suitable for participating in the coupling reaction.

公开(公告)号：US20180002615A1

公开(公告)日：2018-01-04

申请号：US15608070

申请日：2017-05-30

申请人： ExxonMobil Research and Engineering Company

发明人： Stuart S. SHIH ,  Timothy L. HILBERT ,  Anastasios I. SKOULIDAS ,  Bryan A. PATEL ,  Michael R. CHUBA ,  Sean C. SMYTH ,  Mohan KALYANARAMAN

IPC分类号： C10G65/02 ,  B01J8/18 ,  C10G45/02 ,  B01J8/00 ,  B01J8/24 ,  B01J29/72 ,  B01J23/40

CPC分类号： C10G65/02 ,  B01J8/001 ,  B01J8/008 ,  B01J8/1872 ,  B01J8/24 ,  B01J23/40 ,  B01J29/7261 ,  B01J29/7292 ,  B01J29/7461 ,  B01J29/7492 ,  C10G45/02 ,  C10G45/62 ,  C10G45/64 ,  C10G65/04 ,  C10G2300/10 ,  C10G2300/1048 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/304 ,  C10G2400/00

摘要： Systems and methods are provided for catalytically dewaxing a diesel boiling range feed. In some aspects, catalytic dewaxing can be performed at low hydrogen treat gas rates and/or low hydrogen purity conditions. In other aspects, the systems and methods can allow for distillate dewaxing while reducing or minimizing the amount of equipment required.

公开(公告)号：US20170157600A1

公开(公告)日：2017-06-08

申请号：US15438295

申请日：2017-02-21

申请人： ADEOLA FLORENCE OJO ,  YIHUA ZHANG ,  GUAN-DAO LEI ,  STACEY IAN ZONES

发明人： ADEOLA FLORENCE OJO ,  YIHUA ZHANG ,  GUAN-DAO LEI ,  STACEY IAN ZONES

IPC分类号： B01J29/74 ,  C01B39/06 ,  B01J20/18 ,  B01J20/28 ,  C10G65/04 ,  B01J35/10 ,  B01J37/00 ,  B01J37/08 ,  B01J37/30 ,  B01J37/02 ,  C01B39/48 ,  B01J20/30

CPC分类号： B01J29/74 ,  B01J20/18 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/3057 ,  B01J20/3078 ,  B01J20/3085 ,  B01J29/7046 ,  B01J29/7492 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0018 ,  B01J37/0207 ,  B01J37/082 ,  B01J37/18 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/24 ,  B01J2229/38 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/06 ,  C01B39/48 ,  C01P2006/12 ,  C01P2006/14 ,  C10G25/03 ,  C10G29/205 ,  C10G45/64 ,  C10G47/16 ,  C10G65/043 ,  C10G2300/70

摘要： A new crystalline molecular sieve designated SSZ-95 is disclosed. In general, SSZ-95 is synthesized from a reaction mixture suitable for synthesizing MTT-type molecular sieves and maintaining the mixture under crystallization conditions sufficient to form product. The product molecular sieve is subjected to a pre-calcination step, and ion-exchange to remove extra-framework cations, and a post-calcination step. The molecular sieve has a MTT-type framework and a H-D exchangeable acid site density of 0 to 50% relative to molecular sieve SSZ-32.

公开(公告)号：US09637692B2

公开(公告)日：2017-05-02

申请号：US13636182

申请日：2011-03-24

申请人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

发明人： Yoshiyuki Nagayasu ,  Kazuaki Hayasaka ,  Hideki Ono ,  Takaya Matsumoto

IPC分类号： B01J29/06 ,  C10G45/00 ,  C07C5/27 ,  C10G45/64 ,  C10G45/62 ,  C10G65/04 ,  B01J29/76 ,  B01J29/78 ,  B01J29/74 ,  B01J37/02 ,  B01J37/18 ,  B01J37/30 ,  B01J37/00

CPC分类号： C10G45/64 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J29/7661 ,  B01J29/7684 ,  B01J29/7692 ,  B01J29/7861 ,  B01J29/7884 ,  B01J29/7892 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/18 ,  B01J37/30 ,  B01J2229/20 ,  B01J2229/42 ,  C07C5/2708 ,  C07C5/2775 ,  C10G45/62 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/1081 ,  C10G2300/30 ,  C10G2300/70 ,  C10G2400/10

摘要： The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.

公开(公告)号：US09433936B2

公开(公告)日：2016-09-06

申请号：US14196019

申请日：2014-03-04

申请人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partidge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia

发明人： Scott J. Weigel ,  Joseph Emmanuel Gatt ,  Darryl Donald Lacy ,  Randall D. Partidge ,  Kun Wang ,  Lei Zhang ,  Christine Nicole Elia

IPC分类号： B01J29/06 ,  B01J29/76 ,  B01J29/12 ,  B01J29/74 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/78 ,  C10G45/64 ,  C10G45/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G3/00 ,  B01J37/00

CPC分类号： B01J29/7661 ,  B01J29/12 ,  B01J29/126 ,  B01J29/14 ,  B01J29/44 ,  B01J29/46 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J29/7615 ,  B01J29/7815 ,  B01J29/7861 ,  B01J37/0009 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C10G3/44 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G45/02 ,  C10G45/06 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G45/64 ,  C10G2300/1014 ,  C10G2400/02 ,  C10G2400/04 ,  Y02P30/20

摘要： Provided are catalysts including: a zeolite component selected from zeolites having 10-member ring pores, zeolites having 12-member ring pores and a combination thereof, 0.1 to 5 weight % of a hydrogenation component selected from Pt, Pd, Ag, Ni, Co, Mo, W, Rh, Re, Ru, Ir and a mixture thereof, and a hydrothermally stable binder component selected from tantalum oxide, tungsten oxide, molybdenum oxide, vanadium oxide, magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, niobium oxide, tungstated zirconia, cobalt molybdenum oxide, cobalt molybdenum sulfide, nickel molybdenum oxide, nickel molybdenum sulfide, nickel tungsten oxide, nickel tungsten sulfide, cobalt tungsten oxide, cobalt tungsten sulfide, nickel molybdenum tungsten oxide and nickel molybdenum tungsten sulfide, cobalt molybdenum tungsten oxide and cobalt molybdenum tungsten sulfide, wherein the weight ratio of the zeolite to the hydrothermally stable binder is 85:15 to 25:75.

摘要翻译： 提供的催化剂包括：选自具有10元环孔的沸石的沸石组分，具有12元环孔的沸石及其组合，0.1〜5重量％的选自Pt，Pd，Ag，Ni，Co的氢化组分 ，Mo，W，Rh，Re，Ru，Ir及其混合物，以及选自氧化钽，氧化钨，氧化钼，氧化钒，氧化镁，氧化钙，氧化钇，氧化镧，铈的水热稳定的粘合剂成分 氧化物，氧化铌，钨酸氧化锆，钴钼氧化物，钴硫化钼，镍钼氧化物，镍钼硫化物，镍钨氧化物，镍硫化钨，钴钨氧化物，硫化钴硫化物，镍钼钨氧化物和镍钼硫化钨， 钴钼氧化钨和钴钼硫化钨，其中沸石与水热稳定粘合剂的重量比为85:15至25:75。

公开(公告)号：US20160237004A1

公开(公告)日：2016-08-18

申请号：US15014300

申请日：2016-02-03

申请人： Kun WANG ,  Robert T. CARR ,  Elise MARUCCHI-SOOS

发明人： Kun WANG ,  Robert T. CARR ,  Elise MARUCCHI-SOOS

IPC分类号： C07C5/333 ,  C07C2/58 ,  C07C5/03

CPC分类号： C07C5/3337 ,  B01J29/12 ,  B01J29/22 ,  B01J29/44 ,  B01J29/7415 ,  B01J29/7461 ,  B01J29/7492 ,  B01J2229/186 ,  C07C2/12 ,  C07C2/58 ,  C07C2529/74 ,  C10G50/00 ,  C10G2300/1081 ,  C07C9/16 ,  C07C9/14

摘要： A process for converting paraffins, especially light paraffins, e.g. C3-C8 paraffins, to higher boiling range paraffinic liquid hydrocarbons comprises endothermically dehydrogenating the light paraffin combined with a thermally coupled, exothermic reaction such as olefin oligomerization to supply heat for the endothermic conversion.

摘要翻译： 链烷烃，特别是轻链烷烃的转化方法。 C3-C8链烷烃与较高沸点的链烷烃液体烃包括将光链烷烃与热偶合的放热反应（例如烯烃低聚）组合进行吸热脱氢，以提供热量进行吸热转化。

公开(公告)号：US20160167028A1

公开(公告)日：2016-06-16

申请号：US14902690

申请日：2014-06-23

申请人： BHARAT PETROLEUM CORPORATION LTD.

发明人： Mathew JOHN ,  Yogesh Suresh NIWATE ,  S.A. Kishore KUMAR ,  Shivanand Mukund PAI ,  Bharat Lakshman NEWALKAR

IPC分类号： B01J29/74 ,  C07C5/27 ,  B01J37/02 ,  B01J37/08 ,  B01J37/00

CPC分类号： B01J29/7492 ,  B01J29/068 ,  B01J29/44 ,  B01J29/67 ,  B01J29/74 ,  B01J29/7484 ,  B01J35/0066 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  B01J37/086 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/34 ,  C07C5/2791 ,  C07C2529/74

摘要： A method for modification of pretreated acidic porous material via selective cation exchange using suitable solvent to obtain higher noble metal dispersion is described herein. The solvent system required for cation exchange should have its dielectric constant in the range of 25-45, wherein this solvent property is found to impart significant effect on cation loading and distribution, which in turn defines the stability, dispersion of the noble metals. The catalyst so obtained has higher noble metal dispersion and when used for hydroisomerization reaction, leads to higher selectivity even at significantly high conversion values.

摘要翻译： 本文描述了通过使用合适的溶剂通过选择性阳离子交换改性预处理的酸性多孔材料以获得更高贵金属分散体的方法。 阳离子交换所需的溶剂系统的介电常数应在25-45的范围内，其中发现这种溶剂性质对阳离子负载和分布具有显着的影响，从而限定了贵金属的稳定性，分散性。 如此获得的催化剂具有更高的贵金属分散体，并且当用于加氢异构化反应时，即使在显着高的转化率下也导致更高的选择性。

公开(公告)号：US20140315710A1

公开(公告)日：2014-10-23

申请号：US14322221

申请日：2014-07-02

申请人： SHELL OIL COMPANY

发明人： Ann Marie LAURITZEN ,  Ajay Madhav MADGAVKAR

IPC分类号： B01J29/44

CPC分类号： B01J29/44 ,  B01J29/068 ,  B01J29/67 ,  B01J29/7492 ,  B01J37/0009 ,  B01J37/0201 ,  B01J2229/42 ,  C07C2/76 ,  C07C2529/44 ,  C07C2529/67 ,  C07C2529/74 ,  C10G11/05 ,  C10G45/68 ,  Y02P20/52 ,  C07C15/00

摘要： A process for producing aromatic hydrocarbons which comprises (a) contacting one or more lower alkanes with a dehyroaromatization aromatic catalyst which is comprised of 0.005 to 0.1% wt platinum, not more than 0.2% wt of an amount of an attenuating metal wherein the amount of platinum is not more than about 0.02% wt more than the amount of the attenuating metal, from about 10 to about 99.9% wt of an aluminosilicate, and a binder, and (b) separating methane, hydrogen, and C2-5 hydrocarbons from the reaction products of step (a) to produce aromatic reaction products including benzene.

摘要翻译： 一种制备芳族烃的方法，其包括（a）使一种或多种低级烷烃与脱氢芳香族芳族催化剂接触，所述脱氢芳香族催化剂由0.005至0.1％重量的铂，不超过0.2％重量的一种减弱金属的量组成， 铂比减量金属的量不大于约0.02重量％，约10至约99.9重量％的硅铝酸盐和粘合剂，和（b）从甲烷，氢和C 2-5烃分离 步骤（a）的反应产物产生包括苯在内的芳族反应产物。

公开(公告)号：US20130109899A1

公开(公告)日：2013-05-02

申请号：US13286553

申请日：2011-11-01

申请人： Paula L. Bogdan ,  Hui Wang ,  Richard R. Willis

发明人： Paula L. Bogdan ,  Hui Wang ,  Richard R. Willis

IPC分类号： C07C5/22

CPC分类号： B01J29/06 ,  B01J29/126 ,  B01J29/22 ,  B01J29/44 ,  B01J29/67 ,  B01J29/74 ,  B01J29/7446 ,  B01J29/7469 ,  B01J29/7476 ,  B01J29/7484 ,  B01J29/7492 ,  B01J35/002 ,  B01J35/08 ,  B01J35/1042 ,  B01J37/12 ,  B01J37/16 ,  B01J2229/186 ,  C07C5/2732 ,  C07C5/277 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/08 ,  C07C41/06 ,  C07C43/046 ,  C07C1/20 ,  C07C11/02 ,  C07C7/08 ,  C07C11/08

摘要： The subject invention comprises a hydrocarbon-conversion process using a zeolitic catalyst comprising very low concentrations of non-zeolitic material and featuring a gradient in crystallinity decreasing from the outer portion to the center and an intrusion pore volume of at least 0.6 cc/gram. The catalyst is particularly effective in a xylene-isomerization process comprising ethylbenzene conversion.

摘要翻译： 本发明包括使用沸石催化剂的烃转化方法，所述沸石催化剂包含非常低浓度的非沸石材料，并且具有从外部至中心减小的结晶度梯度和至少0.6cc /克的侵入孔体积。 催化剂在包含乙苯转化的二甲苯异构化方法中特别有效。

公开(公告)号：US08372263B2

公开(公告)日：2013-02-12

申请号：US12666422

申请日：2008-01-31

申请人： Kazuaki Hayasaka

发明人： Kazuaki Hayasaka

IPC分类号： C10G73/02

CPC分类号： B01J29/076 ,  B01J29/064 ,  B01J29/7461 ,  B01J29/7484 ,  B01J29/7492 ,  B01J37/18 ,  B01J2229/18 ,  B01J2229/42 ,  C10G45/62 ,  C10G45/64

摘要： A hydroisomerization catalyst according to the present invention is obtained by calcining a catalyst composite including an ion-exchanged molecular sieve or a calcined material thereof which is obtained by performing ion exchange of a molecular sieve containing an organic template in a solution containing a cation species and using water as a main solvent and at least one metal which is selected from a group consisting of metals belonging to Groups 8-10 of the Periodic Table of the Elements, molybdenum, and tungsten supported on the ion-exchanged molecular sieve or a calcined material thereof.

摘要翻译： 本发明的加氢异构化催化剂是通过将包含离子交换分子筛或其煅烧材料的催化剂复合物煅烧而得到的，所述催化剂复合物是通过在含有阳离子种的溶液中进行离子交换包含有机模板的分子筛而获得的， 使用水作为主要溶剂和至少一种金属，其选自属于元素周期表第8-10族的金属，负载在离子交换分子筛上的钼和钨或煅烧材料 其中。