Abstract:
Complexes are made by reacting a solid ammonium molybdate and a solid alkali metal molybdate with ethylene glycol. Stripping of water of reaction subsequent to complex formation is preferred. The ratio of moles of alkylene glycol to total gram atoms of molybdenum should be in the range from about 7:1 to about 20:1 and the ratio of gram atoms of molybdenum in the ammonium molybdate to gram atoms of molybenum in the alkali metal molybdenum should be in the range of about 1:1 to about 20:1. Solutions of the complexes are excellent catalysts for the reaction of propylene with an organic hydroperoxide such as tertiary butyl hydroperoxide to form proplyene oxide and tertiary butyl alcohol.
Abstract:
Complexes made by reacting an ammonium-containing molybdenum compound with an alkylene glycol in the presence of water at an elevated temperature are described. Mild stripping of the water subsequent to complex formation is preferred. If some of the water is left in the complex, it may serve as an excellent olefin epoxidation catalyst. The ratio of moles of alkylene glycol to gram atoms of molybdenum in the complex forming reaction ranges from 7:1 to 20:1. Ethylene glycol and propylene glycol are the particularly preferred alkylene glycols.
Abstract:
Lighting devices using selectively permeable barrier elements, graphite sheet materials, and/or browning agent destroyers/sequestering agents are disclosed. In one embodiment a lighting device may include a body or housing with a selectively permeable barrier element, such as a silicone membrane or o-ring to allow diffusion of contaminants from one or more interior volumes to the exterior environment. Contaminants may be mitigated through use of a sequestering agent/browning agent destroyer. Heat conduction between elements of the housing, such as to aid removal of heat generated from a lighting element such as an LED, may be improved through use of graphite materials, such as PGS sheets between housing elements.
Abstract:
A support frame for a drawer-type dishwasher includes a top section and opposing side sections formed from a plurality of support members which define an open lattice work and establish a cavity for a slidable dishwasher drawer. The support frame also includes first and second rail supports that are provided on respective ones of the opposing side sections. The first and second rail supports are designed to support corresponding first and second extensible rails which, in turn, support the wash tub for movement relative to the frame. In addition, the support frame includes lid support elements for a mechanism that provides shifting of a lid member relative to the wash tub.
Abstract:
A lubricating oil composition comprising:(a) a major amount of an oil of lubricating viscosity; and(b) a minor amount of a synergistic combination of an antioxidant-dispersant additive and a dispersant additive, said combination comprising:(i) a polyisobutylene succinimide;(ii) an ethylene-propylene succinimide; and(iii) an akylated phenothiazine represented by the formula ##STR1## wherein R.sup.1 is a linear or branched (C.sub.4 -C.sub.24) alkyl, heteronlykl or alkylary group; and R.sup.2 is H or a linear or branched (C.sub.4 -C.sub.24) alkyl group.
Abstract:
Disclosed is a method wherein t-butanol is reacted with methanol in one step to provide methyl t-butyl ether at a temperature of about 20.degree. C. to 250.degree. C. and a pressure of about atmospheric to about 1000 psig employing a heterogenous catalyst comprising a Group IV oxide having an alkylsulfonic acid covalently bonded thereto, particularly alkylsulfonic acid covalently bonded to silica gel and having the structure: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms and n is an integer in the range of 3 to 10.
Abstract:
A corrosion-inhibited antifreeze composition is disclosed. Specifically, the antifreeze composition comprises a major portion of a liquid alcohol freezing point depressant and a minor portion of at least one hydroxyl-substituted aromatic carboxylic acid having the hydroxyl radical disposed proximate to the carboxylic radical. The above described acid is employed as a corrosion inhibitor. Other conventional corrosion inhibitors may be employed in conjunction with the acids.In another embodiment, the present invention relates to a process for inhibitig the corrosion of metals present in the cooling system of an internal combustion engine which comprises intimately contacting the metal surface to be inhibited against corrosion with the antifreeze composition described above. Most preferably, the target substrate is high lead solder.
Abstract:
It has been surprisingly discovered in accordance with the present invention that when 1,3-dioxolane is reacted with formaldehyde in the presence of an organic peroxide and an ionizable, at least sparingly soluble metal salt, the reaction preferentially involves an addition of the formaldehyde to the 2-methylene group of the 1,3-dioxolane with only minor reaction with the 4-methylene and 5-methylene groups of the 1,3-dioxolane whereby the reaction product that is formed contains significant quantities of 2-hydroxyalkyl-1,3-dioxolanes. 2-Hydroxyalkyl-1,3-dioxolanes are hydrolyzed with comparative ease to ethylene glycol and the corresponding glycol aldehyde (CHO--CH.sub.2 --OH). The glycol aldehyde in turn can be catalytically hydrogenated to form additional quantities of ethylene glycol.
Abstract:
An enhanced yield of 2-(2-hydroxyethoxy)ethylamine is obtainable when diethylene glycol is reductively aminated over a catalyst consisting of cobalt, copper and ceria or thoria or a mixture thereof.
Abstract:
Novel borate catalyst systems useful for the esterification of olefins are described. The catalyst system is made up of two or more transition metal borates which are co-precipitated. Typical are the zirconyl-cobalt borate, zirconyl-nickel borate and vanadyl-cobalt borate systems.