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1.发明授权
公开(公告)号：US5414162A
公开(公告)日：1995-05-09
申请号：US150917
申请日：1993-11-12
申请人： John R. Sanderson , John F. Knifton
发明人： John R. Sanderson , John F. Knifton
IPC分类号： B01J21/04 , B01J23/44 , B01J35/02 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C409/04
CPC分类号： B01J23/44 , C07C29/132 , C07C31/12 , B01J21/04 , B01J35/008 , B01J35/026
摘要： A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of pentagonally cross-sectioned alumina having palladium deposited thereon and is brought into contact with the catalyst in liquid phase with agitation under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.
摘要翻译： 一种制备叔丁醇的方法，其中将叔丁基过氧化氢在叔丁醇中的溶剂溶液或叔丁醇与异丁烷的混合物的原料装入含有催化有效量的氢过氧化物分解催化剂的氢过氧化物分解反应区， 基本上是其中沉积有钯的五边形横截面的氧化铝，并且在氢过氧化物分解反应条件下，在搅拌下与液相中的催化剂接触，将叔丁基氢过氧化物转化成分解产物，主要是叔丁醇。
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2.发明授权
公开(公告)号：US5354917A
公开(公告)日：1994-10-11
申请号：US150914
申请日：1993-11-12
IPC分类号： B01J23/46 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12
CPC分类号： C07C29/132
摘要： A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of alumina or carbon having rhodium deposited thereon and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.
摘要翻译： 一种制备叔丁醇的方法，其中将叔丁基过氧化氢在叔丁醇中的溶剂溶液或叔丁醇与异丁烷的混合物的原料装入含有催化有效量的氢过氧化物分解催化剂的氢过氧化物分解反应区， 基本上是氧化铝或碳，其上沉积有铑，并在氢过氧化物分解反应条件下与液相中的催化剂接触，将叔丁基氢过氧化物转化成分解产物，主要是叔丁醇。
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3.发明授权One step synthesis of methyl t-butyl ether from t-butanol using hydrogen fluoride-modified zeolite catalysts 失效使用氟化氢改性沸石催化剂从叔丁醇中一步合成甲基叔丁基醚
公开(公告)号：US5300697A
公开(公告)日：1994-04-05
申请号：US986193
申请日：1992-12-07
申请人： John F. Knifton , John R. Sanderson
发明人： John F. Knifton , John R. Sanderson
CPC分类号： C07C41/09 , B01J29/084
摘要： A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in one step to provide methyl tert-butyl ether and the improvement of accomplishing the reaction which comprises:a. Using a catalyst consisting of a crystalline aluminosilicate faujasite Y-type zeolite which has been treated with hydrogen fluoride;b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20.degree. C. to about 250.degree. C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl tert-butyl ether product wherein the product mix separates into an isobutylene-MTBE product-rich phase and a heavier aqueous methanol phase.
摘要翻译： 公开了一种方法，其中在一个步骤中使叔丁醇与甲醇在反应区中反应，得到甲基叔丁基醚，并改进了完成反应，其包括：a。 使用已经用氟化氢处理的结晶硅铝石八面沸石Y型沸石组成的催化剂; b。 在约20℃至约250℃的温度和大约大气压的压力下，使所述叔丁醇和甲醇以约0.1至10摩尔甲醇/摩尔叔丁醇与所述催化剂连续接触 至约1000psig，得到甲基叔丁基醚产物，其中产物混合物分离成异丁烯 - 富含MTBE的相和较重的甲醇水相。
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4.发明授权
公开(公告)号：US5243118A
公开(公告)日：1993-09-07
申请号：US803811
申请日：1991-12-09
CPC分类号： C07C2/10 , B01J21/06 , B01J27/053 , B01J29/06 , B01J37/088 , C07C2/12 , C07C2521/06 , C07C2529/06
摘要： An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using sulfate-activated molecular sieves as catalyst.
摘要翻译： 公开了用于制备合成润滑剂基础油料的改进方法。 通过使用硫酸盐活化分子筛作为催化剂使线性烯烃低聚制备合成润滑剂基础油料。
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5.发明授权Process for oligomerizing olefins to prepare base stocks for synthetic lubricants 失效低聚烯烃以制备合成润滑剂的基础油的方法
公开(公告)号：US5053569A
公开(公告)日：1991-10-01
申请号：US500631
申请日：1990-03-28
IPC分类号： B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C10M107/12
CPC分类号： C10M107/12 , B01J21/16 , C07C2/08 , C07C2/14 , C07C2/22 , C07C9/22 , C10G50/02 , C10M107/10 , C07C2521/16 , C07C2527/128 , C07C2527/138 , C07C2527/25 , C10M2205/003 , C10M2205/0285 , C10M2205/043
摘要： A process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts. When the oligomers are hydrogenated, they provide a synthetic lubricant base stock having excellent properties.
摘要翻译： 公开了制备合成润滑剂基础油料的方法。 可以通过使用某些酸性钙蒙脱石粘土催化剂使线性烯烃低聚来制备合成润滑剂基础油料。 当低聚物被氢化时，它们提供具有优异性能的合成润滑剂基础油料。
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公开(公告)号：US5025112A
公开(公告)日：1991-06-18
申请号：US580035
申请日：1990-09-10
IPC分类号： B01J21/16 , B01J27/182 , C07B61/00 , C07C7/148 , C07C15/085
摘要： A method for purifying a cumene recycle stream by removing 2-phenyl-2-propanol and cumene hydroperoxide before the cumene is distilled and recycled to the peroxidation reactor which comprises reacting the recycle cumene in the presence of an acid treated montmorillonite clay of the formula:M.sub.x/n.sup.n+.sub..y H.sub.2 O(Al.sub.4-x Mg.sub.x) (Si.sub.8)O.sub.20 (OH).sub.4or in the presence of a catalyst comprising phosphoric acid on silica.
摘要翻译： 一种在异丙基苯蒸馏并再循环至过氧化反应器之前通过除去2-苯基-2-丙醇和异丙基氢过氧化氢来净化枯烯循环物流的方法，该方法包括在下列通式的酸处理蒙脱石粘土存在下使回收枯烯反应： Mx / nn + .yH2O（Al4-xMgx）（Si8）O20（OH）4或在二氧化硅上含有磷酸的催化剂存在下进行。
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公开(公告)号：US4912266A
公开(公告)日：1990-03-27
申请号：US94174
申请日：1987-09-08
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： In order to prepare a feedstock, isobutane is reacted with oxygen in an oxidation zone to provide an oxidation product comprising a solution of tertiary butyl hydroperoxide in unreacted isobutane. A catalyst may be present to catalyze the reaction of the oxygen with the isobutane if desired.The feedstock is charged to a catalytic decomposition zone wherein the tertiary butyl hydroperoxide is decomposed in the presence of an imidazole-promoted metal phthalocyanine catalyst to provide a decomposition reaction product characterized by a compartively high conversion rate and a compartively high selectively of tertiary butyl hydroperoxide to tertiary butyl alcohol.
摘要翻译： 为了制备原料，异丁烷在氧化区与氧反应以提供包含叔丁基过氧化氢在未反应的异丁烷中的溶液的氧化产物。 如果需要，可以存在催化剂来催化氧与异丁烷的反应。 将原料装入催化分解区，其中叔丁基过氧化氢在咪唑促进金属酞菁催化剂存在下分解，得到特征在于高转化率和高选择性的叔丁基过氧化氢的分解反应产物， 叔丁醇。
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8.发明授权One step synthesis of methyl t-butyl ether from t-butanol using alkylsulfonic acid-modified oxide catalysts 失效使用烷基磺酸改性氧化物催化剂从叔丁醇一步合成甲基叔丁基醚
公开(公告)号：US5338890A
公开(公告)日：1994-08-16
申请号：US92963
申请日：1993-07-19
申请人： John F. Knifton , John R. Sanderson
发明人： John F. Knifton , John R. Sanderson
CPC分类号： C07C41/09
摘要： Disclosed is a method wherein t-butanol is reacted with methanol in one step to provide methyl t-butyl ether at a temperature of about 20.degree. C. to 250.degree. C. and a pressure of about atmospheric to about 1000 psig employing a heterogenous catalyst comprising a Group IV oxide having an alkylsulfonic acid covalently bonded thereto, particularly alkylsulfonic acid covalently bonded to silica gel and having the structure: ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms and n is an integer in the range of 3 to 10.
摘要翻译： 公开了一种方法，其中叔丁醇与甲醇在一个步骤中反应以在约20℃至250℃的温度和约大气压至约1000psig的压力下提供甲基叔丁基醚，使用异种催化剂 包括与其共价键合的烷基磺酸的IV族氧化物，特别是与硅胶共价键合的烷基磺酸，具有以下结构：其中R是具有1至3个碳原子的烷基，n是整数范围 为3至10。
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9.发明授权Production of detergent range alcohols and ketones using acetylacetonate catalysts 失效使用乙酰丙酮催化剂生产洗涤剂范围的醇和酮
公开(公告)号：US4978800A
公开(公告)日：1990-12-18
申请号：US428703
申请日：1989-10-30
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal acetylacetonate catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal itself may be iron, ruthenium, chromium and mixtures thereof. If iron acetylacetonate is used as a catalyst, copper (II) acetate may be usefully employed as a co-catalyst.
摘要翻译： 描述了在过渡金属乙酰丙酮化物催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。 过渡金属本身可以是铁，钌，铬及其混合物。 如果使用乙酰丙酮铁作为催化剂，乙酸铜（II）可用作助催化剂。
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公开(公告)号：US4922036A
公开(公告)日：1990-05-01
申请号：US94175
申请日：1987-09-08
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a borate-promoted metal phthalocyanine catalyst such as a Group IB, VIIB or VIIIB metal phthalocyanine and a Group IA, IIA or IIB metal borate, for example, chloroferric phthalocyanine and lithium borate, barium borate, zinc borate or sodium metaborate.
摘要翻译： 在硼酸盐促进的金属酞菁催化剂如IB，VIIB或VIIIB族金属酞菁和IAA IIA族的存在下，通过叔丁基过氧化氢的催化分解，优选在叔丁醇溶液中催化分解叔丁醇。 或IIB金属硼酸盐，例如氯代酞菁和硼酸锂，硼酸钡，硼酸锌或偏硼酸钠。
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