摘要:
A method and device for operating a fuel cell system. A recirculation loop coupled to a fuel cell cathode ensures that fluids passing through the cathode are recycled, thereby enabling reaction between residual oxygen in the recycled fluid and fuel that has been introduced into the recirculation loop until substantially all of the oxygen is reacted, leaving a substantially oxygen-free, predominantly nitrogen compound in the cathode and related flowpath. Thereafter, this compound can be redirected to purge the remaining residual hydrogen resident in the fuel cell's anode and related flowpath. While the present invention is usable during any period of system operation, it is especially valuable for operational conditions associated with starting up and shutting down a fuel cell system to inhibit the formation of high voltage potentials that could otherwise damage fuel cell catalysts or catalysts supports.
摘要:
Processes to shut down a fuel cell system are described. In one implementation (300), a load (215) is cyclically engaged and disengaged across a fuel cell stack (205) so as to deplete the fuel available to the system's fuel cells (205). Voltage and/or current thresholds may be used to determine when to engage and disengage the load (215) and when to terminate the shutdown operation. In another implementation (500), a variable load (405) is engaged and adjusted so as to deplete the fuel available to the system's fuel cells (205). As before, voltage and/or current thresholds may be used to determine when to adjust the load (405) and when to terminate the shutdown process. In still another implementation, a load (215 or 405) may be periodically engaged and disengaged during some portion of the shutdown process and engaged but adjusted during other portions of the shutdown process.
摘要:
A UEA for a fuel cell having an active region and a feed region is provided. The UEA includes an electrolyte membrane disposed between a pair of electrodes. The electrolyte membrane and the pair of electrodes is further disposed between a pair of DM. The electrolyte membrane, the pair of electrodes, and the DM are configured to be disposed at the active region of the fuel cell. A barrier film coupled to the electrolyte membrane is configured to be disposed at the feed region of the fuel cell. The dimensions of the electrolyte membrane are thereby optimized. A fuel cell having the UEA, and a fuel cell stack formed from a plurality of the fuel cells, is also provided.
摘要:
A fuel processor system capable of circulating fuel processor system gases, such as reformate, anode exhaust, and/or combustor exhaust, through the fuel processor to provide a number of distinct advantages. The fuel processor system having a plurality of fuel cells discharging an H2-containing anode effluent and an O2-containing cathode effluent. A fuel processor is also provided for converting a hydrogen-containing fuel to H2-containing reformate for fueling the plurality of fuel cells. A catalytic combustor is positioned in series downstream from the plurality of fuel cells and a vaporizer reactor is coupled to the catalytic combustor. A bypass passage is finally provided that interconnects an outlet of at least one of the group consisting of the fuel processor, the plurality of fuel cells, the catalytic combustor, and the vaporizer reactor to the inlet of the fuel processor. The bypass passage is operable to circulate a fuel processor system gas to the inlet of the fuel processor.
摘要:
A diffusion medium for use in a PEM fuel cell comprising a thin perforated layer having variable size and frequency of perforation patterns incorporated into a microporous layer on a first side of a porous substrate layer, wherein the diffusion medium is adapted to improve water management and performance of the fuel cell.
摘要:
Between adjacent MEA's is a bipolar plate assembly having a first sub-plate with a flow channel which is open to the anode side of the one of the MEA's. A second sub-plate has a flow channel which is open to the cathode side of the adjacent MEA. The sub-plates are nested together to form a coolant flow channel between the sub-plates. The coolant flow path has a height dimension wherein the distance between the adjacent MEA's is substantially unaffected by the height dimension of the coolant flow path. A method of manufacturing a bi-polar plate assembly includes forming a closed coolant flow channel between the sub-plates by nesting the sub-plates together. A method of operating a fuel cell includes passing the coolant through a flow path having a height dimension which is substantially aligned with the height dimension of the hydrogen flow path, the oxygen flow path, or both.
摘要:
Apparatus and method for mixing fuel and an oxidant for use in an autothermal reformer that provides hydrogen to a fuel cell. The apparatus includes a mixing vessel (10), a first inlet (4) to the mixing vessel for movement of gaseous fuel or oxidant therethrough, a second inlet for movement of gaseous fuel or oxidant therethrough, and an exit (60) from the vessel adjacent the autothermal reformer. The discharge ends of the inlets are spaced apart from each other and from the exit which is near a POX reactor (61) that combusts the mixture of fuel and oxidant exiting from the mixing vessel. The first inlet is comprised of a plate (26) with a plurality of tubes (24) extending therefrom through which fuel or oxidant passes. The tubes extend into the mixing vessel and towards the exit of the vessel such that the fuel does not come into contact with the oxidant until the gaseous fuel or oxidant discharges from the ends (30) of the tubes thereby mixing the fuel with the oxidant in the gaseous state prior to passing to the POX reactor.
摘要:
An apparatus for premixing fuel and air prior to combustion in a gas turbine engine, including: a linear mixing duct having a circular cross-section defined by a wall; a centerbody located along a central axis of the mixing duct and extending substantially the full length of the mixing duct, the centerbody having a plurality of orifices therein to inject fuel into the mixing duct with an axial velocity component; a fuel supply in flow communication with the centerbody orifices; an outer annular swirler located adjacent an upstream end of the mixing duct and including a plurality of circumferentially spaced vanes oriented so as to swirl air flowing therethrough in a first direction; an inner annular swirler located adjacent the mixing duct upstream end and including a plurality of circumferentially spaced vanes, the vanes having an outer radial portion having a leading edge and a trailing edge oriented so as to swirl air flowing therethrough in a second direction opposite the first swirl direction by the outer annular swirler vanes and an inner radial portion with a leading edge and a trailing edge oriented so as to provide a boundary layer of air substantially along the centerbody; and, a hub separating the inner and outer annular swirlers to permit independent rotation of an air stream therethrough. The outer annular swirler may also include vanes having an inner radial portion with a leading edge and a trailing edge oriented so as to swirl the air flow therethrough and an outer radial portion having a leading edge and a trailing edge oriented so as to provide a boundary layer of air substantially along the mixing duct wall. High pressure air is injected from a compressor into the mixing duct through the inner and outer annular swirlers and fuel is injected into the mixing duct so that the high pressure air and the fuel is uniformly mixed therein, whereby minimal formation of pollutants is produced when the fuel/air mixture is exhausted out the downstream end of the mixing duct into a combustor and ignited.
摘要:
Methods for starting a fuel cell system are provided. In one embodiment, the method includes providing hydrogen to an inlet of an anode of the fuel cell pressurizing the anode to a pressure; determining whether a blocked cell condition exists; if a blocked cell condition exists, if no blocked cell condition exists, initiating a normal start sequence, alternately reducing the pressure of the anode and increasing the pressure of the anode until an exit condition exists, the exit condition selected from a voltage of the fuel cell being stable, or a temperature of the fuel cell being greater than about 0° C., or both, and when the exit condition exists, initiating the normal start sequence.
摘要:
A fuel cell stack assembly is disclosed that includes a porous member disposed within a flow path for a reactant. A fluid collection member is provided within the flow path adjacent to and in fluid communication with the porous member. The porous member and the fluid collection member cooperate to collect liquid water from the reactant flowing in the flow path, wherein the collected liquid water may be drained from the fluid collection member.