Abstract:
A chemical plant and operating method therefor; the chemical plant comprises a steam turbine having a shaft, a first pressure turbine stage and a second pressure turbine stage, each being arranged on the shaft and being connected in series in terms of the steam process; steam for driving the steam turbine is obtained from a reactor plant, said reactor plant producing a hydrogen-containing substance from a carbon-containing energy-carrier stream; the steam is heated in an overheating step before being supplied to the second pressure turbine stage; the steam turbine has a third pressure turbine stage which is arranged on the shaft and which is connected between the first pressure turbine stage and the second pressure turbine stage in terms of the steam process; and the steam passes through the overheating step after exiting the third pressure turbine stage.
Abstract:
Disclosed herein are systems and methods for producing synthesis gas (syngas) using bio-oil. In some embodiments, syngas is produced by steam reforming bio-oil. In some embodiments, the bio-oil is provided in liquid form. In some embodiments at least some of the liquid bio-oil is transitioned into droplet form when entering a reformer for steam-reforming. In some embodiments, the reformer produces a gas stream comprising syngas, which may be fed to a furnace (e.g., direct reducing furnace, shaft furnace) for reducing iron ore to iron. In some embodiments, the amount of oxygen provided to the reformer is regulated based on an equivalence ratio (ER) corresponding to moles of oxygen fed to the reformer divided by moles of oxygen necessary to achieve stoichiometric combustion of the bio-oil, wherein an exemplary ER value is from about 0.1 to about 0.6.
Abstract:
The invention relates to a device for splitting water into hydrogen and oxygen by thermolysis, that is, by decomposition at elevated temperature. This device comprises: —a reactor (1) having a heating system (2), a first reactor outlet (3), a second reactor outlet (4), at least one water inlet (5) and at least one oxygen filter (6); —at least one hydrogen filter (7); —an oxygen extraction pump (8), a hydrogen extraction pump (9), at least one water injection pump (10); —a hydrogen separation chamber (11) located outside the reactor (1) and containing the hydrogen filter(s) (7); —a heat exchanger (15) comprising an inlet (31) and an outlet (13) for a first circuit and an inlet (17) and an outlet (19) for a second circuit. The particularity of such a device is that it comprises two further heat exchangers (16, 28) each comprising an inlet (14, 27) and an outlet (20, 29) for a first circuit and an inlet (22, 36) and an outlet (23, 34) for a second circuit and in that: —the inlet (31) of the first circuit of a first heat exchanger (15) is connected to an external water inlet (12) via the water injection pump (10), the outlet (13) of the first circuit of the first heat exchanger (15) is connected to the inlet (14) of a first circuit of a second heat exchanger (16); —the inlet (17) of the second circuit of the first heat exchanger (15) is connected to an outlet (18) of the hydrogen separation chamber (11), which is connected to the filter(s) (7) and the outlet (19) of the second circuit of the first heat exchanger (15) is a hydrogen outlet of the device. The invention also pertains to a process for splitting water into hydrogen using the above device.
Abstract:
The present invention is an apparatus and method for continuously separating, removing and purifying the solid residue, resulting from the conversion of hydrocarbons into carbon and hydrogen, from the homogeneous phase of different density contained in a cracking reactor with which said solid residue is not soluble, and where the separation of the solid carbon occur at two subsequent moments: a first separation occurs inside the reactor between the reaction products, including carbon, and the melting bath; a second separation then occurs outside the reactor between the carbon and the gas produced in a separation system (1) of the solid phase from the gas phase, where said separation system (1) also includes carbon purification.
Abstract:
The present invention concerns a sorption-enhanced water-gas shift (SEWGS) process for the formation of a CO2 product stream and an H2 product stream, comprising (a) a reaction step, wherein a feed gas comprising COx, wherein x=1-2, and H2O is fed into a SEWGS reactor containing a catalyst and sorbent material capable of adsorbing CO2, thereby forming the H2 product stream and a sorbent material loaded with CO2; (b) a rinse step, wherein steam is fed to the SEWGS reactor, thereby establishing a pressure in the range of 5-50 bar; (c) a pre-blowdown step, wherein the pressure in the SEWGS reactor is reduced to establish a blowdown pressure in the range of 0.5-1.5 times the partial pressure of CO and CO2 in the feed gas of step (a); (d) a blowdown step, wherein the pressure in the SEWGS reactor is reduced to the regeneration pressure in the range of 1-5 bar, thereby releasing at least part of the CO2 from the loaded sorbent material, thereby forming the CO2 product stream; and (e) a purge step, wherein steam is fed to the SEWGS reactor, thereby releasing further CO2 molecules from the SEWGS reactor, wherein the off gas released from the reactor during step (c) is collected separately from the CO2 product stream released from the reactor during step (d). The separate collection of the off gas of pre-blowdown step (c) affords a highly efficient process with excellent CO2 purity and carbon capture ratio.
Abstract:
An apparatus for producing synthesis gas at high capacity is described, wherein particularly fast conversion and operation for a long time without interruption is obtained. The apparatus comprises a reactor (1) having a reactor chamber (2) which comprises at least one first inlet (5) connected to a source of hydrocarbon fluid and at least one outlet (15); further a plasma burner (7) having a burner part (11) which is adapted to produce a plasma; and at least one second inlet (6) connected to a source of CO2 or H2O. The reactor chamber (2) defines a flow path from the first inlet (5) to the outlet (15), wherein the burner part is located, with respect to the flow path, between the first inlet (5) for hydrocarbon fluid and the second inlet (6) for CO2 or H2O; and wherein the second inlet (6) is located with respect to the flow path such that the second inlet (6) is at a location where between 90% and 95% of the hydrocarbon fluid is thermally decomposed. Further a method for operating an apparatus for producing synthesis gas is described.
Abstract:
A reactor system for carrying out an endothermic catalytic chemical reaction in a given temperature range upon bringing a reactant into contact with a catalyst material. The reactor system includes a reactor unit arranged to accommodate catalyst material including one or more ferromagnetic macroscopic supports susceptible for induction heating where the one or more ferromagnetic macroscopic supports are ferromagnetic at temperatures up to an upper limit of the given temperature range. The one or more ferromagnetic macroscopic supports are coated with an oxide, and the oxide is impregnated with catalytically active particles. The reactor system moreover includes an induction coil arranged to be powered by a power source supplying alternating current and being positioned so as to generate an alternating magnetic field within the reactor unit upon energization by the power source, whereby the catalyst material is heated to a temperature within the temperature range by the alternating magnetic field.
Abstract:
The invention discloses a methanol-water mixture reforming hydrogen production generator, including an electronic control system, a methanol-water mixture feed system, a hydrogen production system and a power generation system, where the electronic control system includes a control mainboard, a power supply device and a power output port, and the control mainboard controls operations of the methanol-water mixture feed system, the hydrogen production system and the power generation system; the power supply device includes a rechargeable battery; the methanol-water mixture feed system includes a main feed pipe, a transfer pump, a start-up feed solenoid valve, a start-up feed branch pipe, a hydrogen production feed solenoid valve and a hydrogen production feed branch pipe. All the systems coordinate with each other well, the electronic control system provides stable control. power from external power sources is not needed when during start-up, and the methanol-water mixture feed system has low costs and good cohesion.
Abstract:
A safety means for protecting a plant section located on the pressure side of a jet compressor connected with a propellant system against the exceedance of an admissible pressure, comprising a controlled safety valve actuated by external energy, whose control means measures is connected with the plant section to be protected via at least one pressure tapping line, wherein the safety valve is arranged such that upon exceedance of the pressure in the protected plant section it can vent propellant from the propellant system.
Abstract:
A hydrogen generator comprises a reformer configured to generate a hydrogen-containing gas through a reforming reaction in an internal space thereof using a material gas and steam; a material gas supply passage through which the material gas is supplied to the reformer; a material gas supplier which is provided at the material gas supply passage to supply the material gas to the reformer; a first valve configured to open and close the material gas supply passage; an evaporator configured to generate a steam supplied to the reformer; a water supplier configured to supply water to the evaporator; a communicating passage for allowing the reformer to communicate with atmosphere; a second valve configured to open and close the communicating passage; and a controller configured to stop the material gas supplier and the water supplier and close the first valve and the second valve at shutdown of the hydrogen generator; and open the second valve prior to opening the first valve when the material gas supplier resumes supply of the material gas to the reformer after the shutdown.