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164 条记录 (耗时 0.038 秒)

    Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene
    61.
    发明授权
    Catalysts and process to manufacture 2,3,3,3-tetrafluoropropene 有权
    催化剂和制备2,3,3,3-四氟丙烯的方法

    公开(公告)号：US08487145B2

    公开(公告)日：2013-07-16

    申请号：US13417582

    申请日：2012-03-12

    申请人： Mario Joseph Nappa ,  Andrew Jackson

    发明人： Mario Joseph Nappa ,  Andrew Jackson

    IPC分类号： C07C17/00

    CPC分类号： C07C17/25 ,  B01J23/26 ,  B01J35/1019 ,  C07C21/18

    摘要： Disclosed is a process for the manufacture of 2,3,3,3-tetrafluoropropene comprising: (a) contacting 1,1,1,2,3-pentafluoropropane with a catalyst comprised of chromium (III) oxide having a surface area of at least 150 m2/g and having an alkali metal loading of at least 7 milligrams of alkali metal per 100 square meters of catalyst surface area, to produce a product mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride; and (b) recovering said 2,3,3,3-tetrafluoropropene from the product mixture produced in (a).

    摘要翻译： 公开了一种制备2,3,3,3-四氟丙烯的方法，包括：（a）将1,1,1,2,3-五氟丙烷与由表面积为 至少150m2 / g，并且每100平方米的催化剂表面积具有至少7毫克碱金属的碱金属负荷，以产生包含2,3,3,3-四氟丙烯和氟化氢的产物混合物; 和（b）从（a）中制备的产物混合物回收所述2,3,3,3-四氟丙烯。

    Process for making 1,1,1,4,4,4-Hexafluoro-2-butene
    62.
    发明授权
    Process for making 1,1,1,4,4,4-Hexafluoro-2-butene 有权
    制备1,1,1,4,4,4-六氟-2-丁烯的方法

    公开(公告)号：US08436216B2

    公开(公告)日：2013-05-07

    申请号：US12922858

    申请日：2009-03-18

    申请人： Xuehui Sun ,  Mario Joseph Nappa ,  Win-Chung Lee

    发明人： Xuehui Sun ,  Mario Joseph Nappa ,  Win-Chung Lee

    IPC分类号： C07C21/00 ,  C07C17/00 ,  C22C9/00

    CPC分类号： C07C17/269 ,  C07C21/18

    摘要： A process is disclosed for making 1,1,1,4,4,4-hexafluoro-2-butene. The process involves reacting 2,2-dichloro-1,1,1-trifluoroethane with copper in the presence of an amide solvent and 2,2′-bipyridine. A process is also disclosed for making 1,1,1,4,4,4-hexafluoro-2-butene. The process involves reacting 2,2-dichloro-1,1,1-trifluoroethane with copper in the presence of an amide solvent and a Cu(I) salt. A process is further disclosed for making 1,1,1,4,4,4-hexafluoro-2-butene. The process involves reacting 2,2-dichloro-1,1,1-trifluoroethane with copper in the presence of an amide solvent, 2,2′-bipyridine and a Cu(I) salt.

    摘要翻译： 公开了制备1,1,1,4,4,4-六氟-2-丁烯的方法。 该方法包括在酰胺溶剂和2,2'-联吡啶的存在下使2,2-二氯-1,1,1-三氟乙烷与铜反应。 还公开了制备1,1,1,4,4,4-六氟-2-丁烯的方法。 该方法包括在酰胺溶剂和Cu（I）盐的存在下使2,2-二氯-1,1,1-三氟乙烷与铜反应。 进一步公开了制备1,1,1,4,4,4-六氟-2-丁烯的方法。 该方法包括在酰胺溶剂，2,2'-联吡啶和Cu（I）盐的存在下使2,2-二氯-1,1,1-三氟乙烷与铜反应。

    SELECTIVE CATALYTICAL DEHYDROCHLORINATION OF HDROCHLOROFLUOROCARBONS
    65.
    发明申请
    SELECTIVE CATALYTICAL DEHYDROCHLORINATION OF HDROCHLOROFLUOROCARBONS 有权
    高氯高氯酸盐的选择性催化脱氢

    公开(公告)号：US20120215038A1

    公开(公告)日：2012-08-23

    申请号：US13370397

    申请日：2012-02-10

    申请人： XUEHUI SUN ,  Mario Joseph Nappa

    发明人： XUEHUI SUN ,  Mario Joseph Nappa

    IPC分类号： C07C17/25

    CPC分类号： C07C17/25 ,  C07C19/10 ,  C07C21/18

    摘要： A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein said catalyst comprises MY supported on carbon, and wherein Rf is a perfluorinated alkyl group, M=K, Na or Cs, and Y=F, Cl or Br.

    摘要翻译： 公开了一种脱氯化氢方法。 该方法包括使RfCHClCH2Cl与反应区中的催化剂接触以产生包含RfCCl = CH 2的产物混合物，其中所述催化剂包含负载在碳上的MY，其中Rf是全氟化烷基，M = K，Na或Cs，Y = F，Cl或Br。

    Catalytic production processes for making tetrafluoropropenes and pentafluoropropenes
    67.
    发明授权
    Catalytic production processes for making tetrafluoropropenes and pentafluoropropenes 有权
    用于制备四氟丙烯和五氟丙烯的催化生产方法

    公开(公告)号：US07982073B2

    公开(公告)日：2011-07-19

    申请号：US12373594

    申请日：2007-07-11

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao

    IPC分类号： C07C17/25

    CPC分类号： B01J27/132 ,  B01J23/26 ,  B01J35/1014 ,  B01J37/26 ,  C07C17/25 ,  Y02P20/582 ,  C07C21/18

    摘要： A process is disclosed for making CF3CF═CHF. The process involves contacting at least one hexafluoropropane selected from the group consisting of CF3CF2CH2F and CF3CHFCHF2 with a chromium oxyfluoride catalyst in a reactor to obtain a product mixture comprising CF3CF═CHF, and recovering CF3CF═CHF from the product mixture.A process is disclosed for making CF3CH═CHF. The process involves contacting CF3CH2CHF2 with a chromium oxyfluoride catalyst in a reactor to obtain a product mixture comprising CF3CH═CHF, and recovering CF3CH═CHF from the product mixture.A process is disclosed for making CF3CF═CH2. The process involves contacting CF3CF2CH3 with a chromium oxyfluoride catalyst in a reactor to obtain a product mixture comprising CF3CF═CH2, and recovering CF3CF═CH2 from the product mixture.

    摘要翻译： 公开了一种制备CF 3 CF = CHF的方法。 该方法包括在反应器中使至少一种选自CF 3 CF 2 CH 2 F和CF 3 CHFCHF 2的六氟丙烷与氟氧化铬催化剂接触，以获得包含CF 3 CF = CHF的产物混合物，并从产物混合物中回收CF 3 CF = CHF。 公开了一种制造CF3CH = CHF的方法。 该方法包括在反应器中将CF 3 CH 2 CHF 2与氟氧化铬催化剂接触以获得包含CF 3 CH = CHF的产物混合物，并从产物混合物中回收CF 3 CH = CHF。 公开了制备CF 3 CF = CH 2的方法。 该方法包括在反应器中将CF 3 CF 2 CH 3与氟氧化铬催化剂接触以获得包含CF 3CF≡CH2的产物混合物，并从产物混合物中回收CF 3 CF = CH 2。

    Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF
    68.
    发明授权
    Processes for producing 2,3,3,3-tetrafluoropropene, a process for producing 1-chloro-2,3,3,3-pentafluoropropane and azeotropic compositions of 1-chloro-2,3,3,3-tetrafluoropropene with HF 有权

    公开(公告)号：US07906693B2

    公开(公告)日：2011-03-15

    申请号：US12442955

    申请日：2007-10-31

    申请人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    发明人： Mario Joseph Nappa ,  Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/00 ,  C07C19/08

    CPC分类号： C07C17/25 ,  C07C17/23 ,  C07C17/278 ,  C07C21/18 ,  C07C19/08 ,  C07C19/10

    摘要： A process is disclosed for making CH2═CFCF3. The process involves contacting CH2ClCF2CF3 with H2 in a reaction zone in the presence of a catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina, to produce CH2═CFCF3. The mole ratio of H2 to the CH2ClCF2CF3 fed to the reaction zone is between about 1:1 and about 4:1. Also disclosed is another process for making CH2═CFCF3 that involves (a) reacting CH2ClCF2CF3 with H2 in the presence of a catalytically effective amount of hydrogenation catalyst to form CH3CF2CF3; and (b) dehydrofluorinating CH3CF2CF3 from (a) to form CH2═CFCF3; and another process for making CH2═CFCF3 that involves (1) dehydrofluorinating CH2ClCF2CF3 in the presence of a catalytically effective amount of dehydrofluorination catalyst to form CHCl═CFCF3; and (2) hydrogenating CHCl═CFCF3 from (1) in the presence of a hydrogenation catalyst including a catalytically effective amount of palladium supported on a support selected from chromium oxide, fluorinated chromium oxide, chromium fluoride, aluminum oxide, aluminum fluoride and/or fluorinated alumina to form CH2═CFCF3. Also disclosed is a process for making CH2ClCF2CF5. This process involves reacting CH2ClF with CF2═CF2 in a reaction zone in the presence of a catalytically effective amount of an aluminum halide composition having a bulk formula of AlClxBryF3-x-y wherein the average value of x is 0 to 3, the average value of y is 0 to 3-x, provided that the average values of x and y are not both 0. Also disclosed is an azeotropic composition including CF3CF═CHCl and HF.

    Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3 Pentafluoropropene Using Aluminum Catalyst
    69.
    发明申请
    Catalytic Isomerization Between E and Z Isomers of 1,2,3,3,3 Pentafluoropropene Using Aluminum Catalyst 失效
    使用铝催化剂的1,2,3,3,3-五氟丙烯的E和Z异构体之间的催化异构化

    公开(公告)号：US20100197979A1

    公开(公告)日：2010-08-05

    申请号：US12674961

    申请日：2008-08-14

    申请人： Mario Joseph Nappa

    发明人： Mario Joseph Nappa

    IPC分类号： C07C21/18

    CPC分类号： C07C17/358 ,  C07C21/18

    摘要： A starting material comprising 1,2,3,3,3-pentafluoropropene is contacted with an aluminum chlorofluoride (AlClxF3-x) catalyst to obtain a final product wherein the Z/E ratio of 1,2,3,3,3-pentafluoropropene is either increased or decreased relative to the Z/E ratio of 1,2,3,3,3-pentafluoropropene in said starting material.

    摘要翻译： 将包含1,2,3,3,3-五氟丙烯的起始材料与氯化铝铝（AlCl x F 3-x）催化剂接触以获得最终产物，其中1,2,3,3,3-五氟丙烯的Z / E比 相对于所述原料中的1,2,3,3,3-五氟丙烯的Z / E比增加或降低。