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公开(公告)号：US06531550B1
公开(公告)日：2003-03-11
申请号：US09584438
申请日：2000-05-31
IPC分类号： C08F464
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F4/65916 , C08F4/025
摘要： A process of using a catalyst composition to polymerize at least one monomer to produce a polymer. The process comprising contacting the catalyst composition, at least one monomer in a polymerization zone under polymerization conditions to produce the polymer. The catalyst composition is produced by a process comprising contacting at least one organometal compound, at least one solid mixed oxide compound, and at least one organoaluminum compound. The solid mixed oxide compound comprises oxygen and at least two elements selected from the group consisting of groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, and 15 of the periodic table, including lanthanides and actinides.
摘要翻译： 使用催化剂组合物聚合至少一种单体以制备聚合物的方法。 该方法包括在聚合条件下使催化剂组合物，聚合区中的至少一种单体接触以产生聚合物。 催化剂组合物通过包括使至少一种有机金属化合物，至少一种固体混合氧化物化合物和至少一种有机铝化合物接触的方法制备。 固体混合氧化物化合物包含氧和至少两种元素，其选自周期性的第2,3,4,5,5,6,7,8,9,10,11,12,13,14和15组， 表，包括镧系元素和锕系元素。
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公开(公告)号：US06369000B1
公开(公告)日：2002-04-09
申请号：US09398654
申请日：1999-09-17
IPC分类号： B01J3200
CPC分类号： B01J23/06 , B01J23/02 , B01J37/023 , Y10S502/524
摘要： A process of making a metal aluminate catalyst support by incorporating, preferably impregnating, alumina, preferably gamma alumina, with a metal component to thereby provide a metal-incorporated alumina which is then calcined under a calcining condition to thereby provide a metal aluminate catalyst support. Such calcining condition includes a temperature in the range of from about 600° C. to about 1350° C. Preferably the metal component has been melted under a melting condition to thereby provide a melted metal component.
摘要翻译： 通过将氧化铝，优选γ氧化铝与金属组分并入，优选将氧化铝浸渍，从而提供掺入金属的氧化铝，然后在煅烧条件下煅烧从而提供金属铝酸盐催化剂载体，从而制备金属铝酸盐催化剂载体的方法。 这种煅烧条件包括在约600℃至约1350℃范围内的温度。优选地，金属组分在熔融条件下熔化，从而提供熔融的金属组分。
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公开(公告)号：US06254766B1
公开(公告)日：2001-07-03
申请号：US09382935
申请日：1999-08-25
IPC分类号： C10G2904
CPC分类号： C10G25/003 , B01J20/0225 , B01J20/0244 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/30 , B01J20/3204 , B01J20/3236 , C10G2400/02
摘要： Particulate sorbent compositions comprising a mixture of zinc oxide, silica, alumina and a substantially reduced valence nickel are provided for the desulfurization of a feedstream of cracked-gasoline or diesel fuels in a desulfurization zone by a process which comprises the contacting of such feedstreams in a desulfurization zone followed by separation of the resulting low sulfur-containing stream and sulfurized-sorbent and thereafter regenerating and activating the separated sorbent before recycle of same to the desulfurization zone.
摘要翻译： 提供了包含氧化锌，二氧化硅，氧化铝和基本上降低的价铬的混合物的颗粒吸附剂组合物，用于通过包括使这种原料流在一个或多个中的接触的方法在脱硫区中对裂化汽油或柴油燃料的原料流进行脱硫 脱硫区，然后分离所得的低硫含量物流和硫化吸附剂，然后在将其再循环到脱硫区之前再生和活化分离的吸附剂。
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公开(公告)号：US5489565A
公开(公告)日：1996-02-06
申请号：US418038
申请日：1995-04-06
IPC分类号： B01J23/50 , B01J23/58 , B01J23/66 , B01J27/12 , B01J37/26 , C07B61/00 , C07C5/05 , C07C11/02 , C07C11/08 , B01J23/00
CPC分类号： B01J37/26 , B01J23/58 , B01J23/66 , B01J27/12 , C07C5/05 , B01J23/50 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2523/06 , C07C2523/44 , C07C2523/66 , C07C2527/12
摘要： A supported catalyst composition, which is effective as a diolefin hydrogenation catalyst, comprises palladium, silver and alkali metal fluoride. This catalyst composition is employed in the selective hydrogenation of C.sub.4 -C.sub.10 diolefins (preferably 1,3-butadiene) with hydrogen gas to the corresponding monoolefins.
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公开(公告)号：US5296515A
公开(公告)日：1994-03-22
申请号：US893165
申请日：1992-06-03
IPC分类号： C08F8/50
CPC分类号： C08F8/50
摘要： A method is provided for hydrovisbreaking hydrocarbon polymers, particularly those derived from scrap articles, in which a mixture of at least one hydrocarbon polymer and a solvent is contacted with hydrogen under conditions sufficient to hydrovisbreak the polymer. The solvent comprises a combined weight percentage of C.sub.n H.sub.2n-8 and C.sub.n H.sub.2n-10 hydrocarbons of at least about 10 weight percent, where n is an integer of at least 8 in C.sub.n H.sub.2n-8 and n is an integer of at least 10 in C.sub.n H.sub.2n-10. The hydrovisbroken polymer can be fed to a catalytic cracker for cracking to cracked products.
摘要翻译： 提供了一种用于加氢裂解烃聚合物，特别是衍生自废料的那些烃聚合物的方法，其中至少一种烃聚合物和溶剂的混合物在足以使聚合物破裂的条件下与氢气接触。 溶剂包括CnH2n-8和CnH2n-10烃的至少约10重量％的组合重量百分数，其中n是C n H 2n-8中的至少8的整数，n是C n H 2n-10中的至少10的整数 。 加氢分解聚合物可以进料到催化裂化器中以开裂裂化产物。
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公开(公告)号：US5208405A
公开(公告)日：1993-05-04
申请号：US845128
申请日：1992-03-03
CPC分类号： C07C5/05 , B01J23/892 , C07C2523/50 , C07C2523/755 , C07C2523/89 , C07C2527/25 , C07C2531/04
摘要： A process for selectively hydrogenating C.sub.4 -C.sub.10 diolefins to the corresponding monoolefins is carried out with a catalyst comprising (a) nickel metal and/or compound(s), (b) silver metal and/or compound(s), and (c) a solid inorganic support material (preferably alumina).
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公开(公告)号：US5171798A
公开(公告)日：1992-12-15
申请号：US637897
申请日：1991-01-02
IPC分类号： C08F10/00
CPC分类号： C08F10/00
摘要： High surface aluminas are pre-calcined to form gamma-alumina. In one embodiment, the gamma-alumina is treated with an anhydrous solution of a fluorine-containing compound. In a second embodiment, alumina is precipitated in the pores of the gamma-alumina and then treated with a fluorine-containing compound. In a third embodiment a cogel of aluminum trifluoride and aluminum hydroxide is prepared. The three inventive fluorided alumina supports can be impregnated with a transition metal, preferably chromium, to form a catalyst system which can be used to polymerize mono-1-olefins.
摘要翻译： 高表面氧化铝被预煅烧以形成γ-氧化铝。 在一个实施方案中，γ-氧化铝用含氟化合物的无水溶液处理。 在第二实施方案中，氧化铝在γ-氧化铝的孔中沉淀，然后用含氟化合物处理。 在第三个实施方案中，制备三氟化铝和氢氧化铝的共凝胶。 三种本发明的氟化氧化铝载体可以用过渡金属（优选铬）浸渍以形成可用于聚合单-1-烯烃的催化剂体系。
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公开(公告)号：US5095160A
公开(公告)日：1992-03-10
申请号：US719899
申请日：1991-06-24
申请人： Filippo Penella , Marvin M. Johnson
发明人： Filippo Penella , Marvin M. Johnson
IPC分类号： C07C2/00
CPC分类号： C07C2/00 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/04 , C07C2523/06 , C07C2523/755 , C07C2527/167
摘要： Benzene is converted to toluene in the presence of free hydrogen and a supported nickel metal catalyst.
摘要翻译： 在游离氢和负载的镍金属催化剂存在下，苯转化成甲苯。
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公开(公告)号：US4927795A
公开(公告)日：1990-05-22
申请号：US264293
申请日：1988-10-28
CPC分类号： C10G11/04 , B01J38/48 , Y10S502/521
摘要： This invention comprises improvements to processes for the catalytic cracking of hydrocarbon feedstocks. One such improvement to catalytic cracking processes provides compositions comprising metals passivating agents having an increased degree of stability. These compositions comprise aqueous suspensions of antimony by vinyl copolymers, aqueous suspensions of antimony oxide by diesters of phosphoric acid, or aqueous suspensions of antimony oxide by cellulose derivatives. Another improvement to catalytic cracking processes provides a process for reducing the viscosity of liquid suspensions of metals passivating agents without substantially reducing the stability of the liquid suspension by the utilization of at least two different particle ranges of metals passivating agents. A further improvement to catalytic cracking processes provides an efficient utilization of metals passivating agents by introducing the selected agent into the catalyst regeneration cycle of a catalytic cracking unit.
摘要翻译： 本发明包括对烃原料的催化裂化方法的改进。 催化裂化方法的一个这样的改进提供了包含具有增加的稳定性的金属钝化剂的组合物。 这些组合物包含乙烯基共聚物的锑水悬浮液，磷酸二酯的氧化锑水悬浮液，或纤维素衍生物的氧化锑水悬浮液。 催化裂化方法的另一改进提供了降低金属钝化剂的液体悬浮液的粘度的方法，而不会通过利用至少两种不同的金属钝化剂的不同颗粒范围来显着降低液体悬浮液的稳定性。 催化裂化方法的进一步改进通过将所选择的试剂引入催化裂化装置的催化剂再生循环来提供金属钝化剂的有效利用。
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公开(公告)号：US4711868A
公开(公告)日：1987-12-08
申请号：US866551
申请日：1986-05-23
申请人： Yen-Shin Shyr , Marvin M. Johnson
发明人： Yen-Shin Shyr , Marvin M. Johnson
摘要： A process for preparing silica-alumina compositions comprises mixing a first aqueous solution containing an aluminum salt (preferably KAl(SO.sub.4).sub.2) and an ammonium salt (preferably (NH.sub.4).sub.2 SO.sub.4) with a second solution containing an alkali metal silicate (preferably Na.sub.2 SiO.sub.3), wherein the mol ratio of the alkali metal silicate to the aluminum salt is in the range of from about 2:1 to about 20:1, and the concentration of the ammonium salt is chosen so as to afford coprecipitation of silica-alumina hydrogel (preferably at a pH of about 3-6). The thus coprecipitated silica-alumina hydrogel can be separated from the mixture of the two solutions, optionally washed, and calcined so as to prepare acidic silica-alumina suitable as cracking catalyst material.
摘要翻译： 制备二氧化硅 - 氧化铝组合物的方法包括将含有铝盐（优选KAl（SO 4）2）和铵盐（优选（NH 4）2 SO 4）的第一水溶液与含有碱金属硅酸盐（优选Na 2 SiO 3）的第二溶液混合， 其中碱金属硅酸盐与铝盐的摩尔比在约2:1至约20:1的范围内，并且选择铵盐的浓度以提供二氧化硅 - 氧化铝水凝胶的共沉淀（ 优选在约3-6的pH下）。 这样共沉淀的二氧化硅 - 氧化铝水凝胶可以从两种溶液的混合物中分离，任选地进行洗涤和煅烧，以制备适合作为裂化催化剂材料的酸性二氧化硅 - 氧化铝。
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