Additives with a reduced tendency to emulsify, which improve the lubricating action of highly desulphurised fuel oils
    61.
    发明授权
    Additives with a reduced tendency to emulsify, which improve the lubricating action of highly desulphurised fuel oils 失效
    具有降低乳化倾向的添加剂,其改善高度脱硫的燃料油的润滑作用

    公开(公告)号:US07431745B2

    公开(公告)日:2008-10-07

    申请号:US10484971

    申请日:2002-07-09

    IPC分类号: C10L1/18

    CPC分类号: C10L10/08 C10L1/191

    摘要: The present invention relates to an additive for improving the lubrication capacity of fuel oils with a maximum sulfur content of 0.035 wt. %. The additive contains at least one ester of a bivalent or polyvalent alcohol and a mixture of unsaturated and optionally saturated fatty acids, whose carbon chain lengths are between 8 and 30 carbon atoms, the aforementioned esters having an OH value of less than 200 mg KOH/g ester and an iodine value greater than 100 g l/100 g ester. The invention also relates to fuel oils with a maximum sulfur content of 0.035 wt. %, which contain the inventive additives. The novel additives exhibit less tendency to emulsify than the additives of the prior art.

    摘要翻译: 本发明涉及一种用于改善最大硫含量为0.035重量%的燃料油的润滑能力的添加剂。 %。 添加剂含有至少一种二价或多价醇的酯和碳链长度为8至30个碳原子的不饱和脂肪酸和任选的饱和脂肪酸的混合物,上述酯的OH值小于200mg KOH / g酯和碘值大于100g / 100g的酯。 本发明还涉及最大硫含量为0.035重量%的燃料油。 %,其含有本发明的添加剂。 与现有技术的添加剂相比,新型添加剂显示出较少的乳化倾向。

    Additives for crude oils
    64.
    发明申请
    Additives for crude oils 失效
    原油添加剂

    公开(公告)号:US20070221539A1

    公开(公告)日:2007-09-27

    申请号:US11525881

    申请日:2006-09-22

    IPC分类号: C10G71/00

    摘要: The invention thus provides crude oils and products which have been produced therefrom and comprise distillation residues, comprising at least one alkylphenol-aldehyde resin having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radical or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2, the use of the alkylphenol-aldehyde resin for splitting emulsions of water and crude oils or products derived therefrom, the use of the alkylphenol-aldehyde resin for improving the cold flowability of crude oils and products derived therefrom, and the use of the alkylphenol-aldehyde resin as an asphaltene dispersant in crude oils and products derived therefrom.

    摘要翻译: 因此,本发明提供由其制备的原油和产品,其包含蒸馏残余物,其包含至少一种具有下式重复结构单元的烷基酚醛树脂:其中R 1是支链烷基或链烯基 具有10至40个碳原子并具有至少一个羧基,羧酸酯和/或酯基团的基团,R 2是氢或R 1,R 3, / SUP>是氢或式的烷氧基<?in-line-formula description =“In-line Formulas”end =“lead”→>(AO) ?in-line-formula description =“In-line Formulas”end =“tail”?> A是C 4 - 亚烷基,m是 1至100,R 4是氢,C 1至C 11 - 烷基或羧基,R 11, 5是C 1 -C 20 - 烷基或 - 烯基,或6或OC(O)-R 6,R 6为C 1 -C 20 - 烷基或 - 烯基,n为1至100,并且 k为1或2,使用烷基苯酚醛树脂来分解水和原油或其衍生产物的乳液,使用烷基苯酚醛树脂来改善原油及其衍生产物的冷流动性,以及 在原油中使用烷基酚醛树脂作为沥青质分散剂和由其衍生的产品。

    Mineral oils which comprise detergent additives and have improved cold flowability
    65.
    发明申请
    Mineral oils which comprise detergent additives and have improved cold flowability 有权
    矿物油,其包含洗涤剂添加剂并具有改善的冷流动性

    公开(公告)号:US20070149417A1

    公开(公告)日:2007-06-28

    申请号:US11644228

    申请日:2006-12-22

    IPC分类号: C10M145/14

    摘要: The invention provides for the use of at least one oil-soluble polyoxyalkylene compound, this polyoxyalkylene compound being an oil-soluble ester, ether or ether/ester of alkoxylated polyols having at least three repeat alkoxy units derived from alkylene oxides having from 2 to 5 carbon atoms per OH group of the polyol which bears at least two aliphatic hydrocarbon radicals having from 12 to 30 carbon atoms for improving the response behavior of mineral oil cold flow improvers in middle distillates which comprise at least one ashless, nitrogen-containing detergent additive which is an oil-soluble amphiphilic compound which comprises at least one alkyl or alkenyl radical which is bonded to a polar group, the alkyl or alkenyl radical comprising from 10 to 500 carbon atoms and the polar group comprising 2 or more nitrogen atoms.

    摘要翻译: 本发明提供至少一种油溶性聚氧化烯化合物的用途,该聚氧化烯化合物是具有至少三个衍生自具有2至5个碳原子的氧化烯的重复烷氧基单元的油溶性酯,醚或醚/ 含有至少两个具有12至30个碳原子的脂族烃基的多元醇OH基团的碳原子,用于改善中间馏分中矿物油冷流改进剂在至少一种无灰含氮洗涤剂添加剂中的响应行为, 是一种油溶性两亲化合物,其包含至少一个与极性基团键合的烷基或烯基,所述烷基或烯基包含10至500个碳原子,极性基团包含2个或更多个氮原子。

    Mineral oils with improved conductivity and cold flowability
    66.
    发明申请
    Mineral oils with improved conductivity and cold flowability 有权
    具有改善导电性和冷流动性的矿物油

    公开(公告)号:US20070027041A1

    公开(公告)日:2007-02-01

    申请号:US11494951

    申请日:2006-07-28

    IPC分类号: C07C309/62 C09K15/08

    摘要: Mineral oil distillates having an aromatics content of less than 21% by weight, a water content of less than 150 ppm and a conductivity of at least 50 pS/m, and comprising from 0.1 to 200 ppm of at least one alkylphenol-aldehyde resin (constituent I) which includes a structural element of the formula in which R5 is C1-C200-alkyl or C2-C200-alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or C2-C200-alkenyl and n is from 2 to 100, and from 0.1 to 200 ppm of at least one polar oil-soluble nitrogen compound (constituent II), excluding those mineral oil distillates in which between 0.001 and 10 ppm of an oil-soluble, organic sulfonic acid-ammonium salt are present.

    摘要翻译: 芳族化合物含量小于21重量%,含水量小于150ppm,电导率至少为50pS / m的矿物油馏分,并且包含0.1至200ppm的至少一种烷基酚醛树脂( 组分I),其包括其中R 5为C 1 -C 20 - C 2-4 - 烷基或C 2 - 的下式的结构元件 或者C 0(O)-R 6,C 6 O 12,C 6 -C 12, >为C 1 -C 2 - 亚烷基或C 2 -C 20 - 烯基,n为2 至100ppm和0.1ppm至200ppm的至少一种极性油溶性氮化合物(组分II),不包括其中存在0.001至10ppm油溶性有机磺酸铵盐的那些矿物油馏分 。

    Fuel oils composed of middle distillates and oils of vegetable or animal origin and having improved cold flow properties

    公开(公告)号:US20050126072A1

    公开(公告)日:2005-06-16

    申请号:US11009885

    申请日:2004-12-10

    摘要: The invention provides a fuel oil composition F) comprising F1) a fuel oil of mineral origin and F2) a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol% of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units composed of B1) at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety, where the sum Q Q = ∑ i ⁢ w 1 ⁢   ⁢ i · n 1 ⁢ i + ∑ j ⁢ w 2 ⁢ j · n 2 ⁢ j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the amide and/or imide groups of monomer 2 on the other is from 21.0 to 28.0, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radical of the amide and/or imide groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2.

    Hydroxyl-containing copolymers, and their use for the preparation of fuel oils having improved lubricity
    70.
    发明授权
    Hydroxyl-containing copolymers, and their use for the preparation of fuel oils having improved lubricity 失效
    含羟基的共聚物及其用于制备具有改善的润滑性的燃料油的用途

    公开(公告)号:US06364918B1

    公开(公告)日:2002-04-02

    申请号:US09594950

    申请日:2000-06-09

    IPC分类号: C10L118

    摘要: Oil-soluble copolymers having an OH number of from 10 to 250 and a molecular weight of from 1000 to 100,000 g/mol, obtained from the reaction of a copolymer precursor which comprises structural units of A) from 5 to 95 mol-% of an olefinically unsaturated carboxylic acid or a derivative of such an acid, B) from 5 to 95 mol-% of an olefinically unsaturated compound having at least one hydrocarbon radical containing at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of C1-C6-alkyl (meth)acrylates, C1-C6-alkyl vinyl esters and C2-C6-olefins, with a reagent, which must carry at least one OH group and which, apart from this OH group, has at least one further functional group which is capable of reacting with the carboxylic acid or the derivative of a carboxylic acid as in component A), where the residual acid number is set to a value below 50 mg of KOH/g of copolymer by addition of the reagent.

    摘要翻译: 由共聚物前体的反应获得的羟值为10至250,分子量为1000至100,000g / mol的油溶性共聚物,该共聚物前体包含结构单元A)5至95摩尔%的烯属 不饱和羧酸或这种酸的衍生物,B)5至95摩尔%的具有至少一个含有至少6个碳原子的烃基的烯属不饱和化合物,如果需要,C)0至40摩尔 - 选自由(甲基)丙烯酸C 1 -C 6烷基酯,C 1 -C 6烷基乙烯基酯和C 2 -C 6 - 烯烃组成的组中的另外的结构单元的%与必须携带至少一个OH基团的试剂的% 除了OH基之外,还有至少一个能够与羧酸或羧酸衍生物反应的另外的官能团,如组分A),其中残余酸值设定为低于50mg的值 KOH / g共聚物。