公开(公告)号：US07815697B2

公开(公告)日：2010-10-19

申请号：US11009885

申请日：2004-12-10

申请人： Matthias Krull ,  Bettina Siggelkow ,  Martina Hess

发明人： Matthias Krull ,  Bettina Siggelkow ,  Martina Hess

IPC分类号： C10L1/196 ,  C10L1/234

CPC分类号： C10L1/1955 ,  C10L1/143 ,  C10L1/146 ,  C10L1/19 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364

摘要： The invention provides a fuel oil composition comprising a fuel oil of mineral origin and a fuel oil of vegetable and/or animal origin and as a cold additive, the constituents, at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic and vinyl ester having a C1-C18 alkyl radical and at least one comb polymer containing structural units composed of at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety.

摘要翻译： 本发明提供一种燃料油组合物，其包含矿物来源的燃料油和植物和/或动物来源的燃料油和作为冷添加剂的组分，至少一种由乙烯和至少8-21摩尔％的共聚物组成的共聚物 一种具有C1-C18烷基的丙烯酸和乙烯基酯和至少一种梳状聚合物，其含有至少一种烯烃作为单体的结构单元，所述单体在所述烯属双键上带有至少一个C 8 -C 18烷基，以及至少一个 烯键式不饱和二羧酸作为单体2，其具有通过酰胺和/或酰亚胺部分键合的至少一个C 8 -C 16烷基。

公开(公告)号：US07815696B2

公开(公告)日：2010-10-19

申请号：US11391643

申请日：2006-03-28

申请人： Matthias Krull

发明人： Matthias Krull

IPC分类号： C10L1/18

CPC分类号： C10L10/08 ,  C10L1/143 ,  C10L1/1835 ,  C10L1/19 ,  C10L1/1905 ,  C10L1/191 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364 ,  C10M169/04 ,  C10M169/044 ,  C10M2205/022 ,  C10M2207/282 ,  C10M2209/101 ,  C10N2220/024 ,  C10N2220/026 ,  C10N2230/06 ,  C10N2230/10 ,  C10N2230/43

摘要： The present invention provides an additive for improving the lubricity of fuel oils having a maximum sulfur content of 0.035% by weight. The additive comprises A) at least one partial ester composed of a di- or polyhydric alcohol and unsaturated and optionally also saturated fatty acids whose carbon chain lengths are between 8 and 30 carbon atoms, at least 60% of the fatty acid radicals containing at least one double bond, and B) at least one alkylphenol-aldehyde resin, obtainable by the condensation of (i) at least one alkylphenol having at least one C6-C24-alkyl or C6-C24-alkenyl radical and (ii) at least one aldehyde or ketone, to a degree of condensation of between 2 and 50 alkylphenol units.

摘要翻译： 本发明提供一种添加剂，其用于改善最大硫含量为0.035重量％的燃料油的润滑性。 该添加剂包括A）至少一种由二元或多元醇组成的偏酯和碳链长度在8至30个碳原子之间的不饱和和任选的饱和脂肪酸，至少含有60％至少含有脂肪酸基团 一个双键，和B）至少一种烷基酚醛树脂，可通过（i）至少一种具有至少一个C 6 -C 24 - 烷基或C 6 -C 24 - 链烯基的烷基酚和（ii）至少一种 醛或酮，至2至50个烷基酚单元的缩合度。

公开(公告)号：US07776111B2

公开(公告)日：2010-08-17

申请号：US11185387

申请日：2005-07-20

申请人： Matthias Krull ,  Carsten Cohrs ,  Hildegard Freundl ,  Stefan Lorenz

发明人： Matthias Krull ,  Carsten Cohrs ,  Hildegard Freundl ,  Stefan Lorenz

IPC分类号： C08K5/41

CPC分类号： C10L1/143 ,  C10L1/1641 ,  C10L1/195 ,  C10L1/1955 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/198 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/2437 ,  C10L10/14

摘要： The invention provides compositions comprising at least one alkylphenol-aldehyde resin (constituent I) and, based on the alkylphenol resin, from 0.005 to 10% by weight of at least one oil-soluble organic ammonium sulfonate (constituent II).

摘要翻译： 本发明提供包含至少一种烷基酚醛树脂（组分I）和基于烷基酚树脂0.005至10重量％的至少一种油溶性有机磺酸铵（组分II）的组合物。

公开(公告)号：US07431745B2

公开(公告)日：2008-10-07

申请号：US10484971

申请日：2002-07-09

申请人： Matthias Krull ,  Markus Kupetz

发明人： Matthias Krull ,  Markus Kupetz

IPC分类号： C10L1/18

CPC分类号： C10L10/08 ,  C10L1/191

摘要： The present invention relates to an additive for improving the lubrication capacity of fuel oils with a maximum sulfur content of 0.035 wt. %. The additive contains at least one ester of a bivalent or polyvalent alcohol and a mixture of unsaturated and optionally saturated fatty acids, whose carbon chain lengths are between 8 and 30 carbon atoms, the aforementioned esters having an OH value of less than 200 mg KOH/g ester and an iodine value greater than 100 g l/100 g ester. The invention also relates to fuel oils with a maximum sulfur content of 0.035 wt. %, which contain the inventive additives. The novel additives exhibit less tendency to emulsify than the additives of the prior art.

摘要翻译： 本发明涉及一种用于改善最大硫含量为0.035重量％的燃料油的润滑能力的添加剂。 ％。 添加剂含有至少一种二价或多价醇的酯和碳链长度为8至30个碳原子的不饱和脂肪酸和任选的饱和脂肪酸的混合物，上述酯的OH值小于200mg KOH / g酯和碘值大于100g / 100g的酯。 本发明还涉及最大硫含量为0.035重量％的燃料油。 ％，其含有本发明的添加剂。 与现有技术的添加剂相比，新型添加剂显示出较少的乳化倾向。

公开(公告)号：US07347881B2

公开(公告)日：2008-03-25

申请号：US10495558

申请日：2002-11-02

申请人： Matthias Krull ,  Martina Hess

发明人： Matthias Krull ,  Martina Hess

IPC分类号： C10L1/18

CPC分类号： C10L1/143 ,  C10L1/1616 ,  C10L1/191 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1983 ,  C10L1/1985 ,  C10L1/1986 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/224 ,  C10L1/2364

摘要： A middle distillate having a maximum um sulfur content of 0.05% by weight and containing fatty acid esters of alkoxylated polyols having at least 3 OH groups (A) and also at least one cold flow improver (B). The cold flow improver includes at least one copolymer of ethylene and one or more ethylenically unsaturated carboxylic esters having an ethylene portion of from 60 to 90 mol %.

摘要翻译： 中间馏分，其最大硫含量为0.05重量％，并且含有具有至少3个OH基团（A）的烷氧基​​化多元醇的脂肪酸酯和至少一种冷流改进剂（B）。 冷流改进剂包括乙烯和一种或多种乙烯部分为60至90摩尔％的烯属不饱和羧酸酯的至少一种共聚物。

公开(公告)号：US20070221539A1

公开(公告)日：2007-09-27

申请号：US11525881

申请日：2006-09-22

申请人： Carsten Cohrs ,  Matthias Krull ,  Michael Feustel ,  Heidi Rausch

发明人： Carsten Cohrs ,  Matthias Krull ,  Michael Feustel ,  Heidi Rausch

IPC分类号： C10G71/00

CPC分类号： C10L1/1985 ,  B01D17/047 ,  C09K8/524 ,  C10L1/1981 ,  C10L10/16 ,  C10L10/18 ,  C10M2209/101 ,  C10N2230/04 ,  C10N2230/08 ,  C10N2230/24

摘要： The invention thus provides crude oils and products which have been produced therefrom and comprise distillation residues, comprising at least one alkylphenol-aldehyde resin having a repeat structural unit of the formula where R1 is a branched alkyl or alkenyl radical which has from 10 to 40 carbon atoms and bears at least one carboxyl, carboxylate and/or ester group, R2 is hydrogen or R1 R3 is hydrogen or an alkoxy group of the formula -(A-O)m—H, A is a C2- to C4-alkylene group, m is from 1 to 100, R4 is hydrogen, a C1- to C11-alkyl radical or a carboxyl group, R5 is C1-C200-alkyl or -alkenyl, O—R6 or O—C(O)—R6, R6 is C1-C200-alkyl or -alkenyl, n is from 1 to 100 and k is 1 or 2, the use of the alkylphenol-aldehyde resin for splitting emulsions of water and crude oils or products derived therefrom, the use of the alkylphenol-aldehyde resin for improving the cold flowability of crude oils and products derived therefrom, and the use of the alkylphenol-aldehyde resin as an asphaltene dispersant in crude oils and products derived therefrom.

摘要翻译： 因此，本发明提供由其制备的原油和产品，其包含蒸馏残余物，其包含至少一种具有下式重复结构单元的烷基酚醛树脂：其中R 1是支链烷基或链烯基 具有10至40个碳原子并具有至少一个羧基，羧酸酯和/或酯基团的基团，R 2是氢或R 1，R 3， / SUP>是氢或式的烷氧基<？in-line-formula description =“In-line Formulas”end =“lead”→>（AO） ？in-line-formula description =“In-line Formulas”end =“tail”？> A是C 4 - 亚烷基，m是 1至100，R 4是氢，C 1至C 11 - 烷基或羧基，R 11， 5是C 1 -C 20 - 烷基或 - 烯基，或6或OC（O）-R 6，R 6为C 1 -C 20 - 烷基或 - 烯基，n为1至100，并且 k为1或2，使用烷基苯酚醛树脂来分解水和原油或其衍生产物的乳液，使用烷基苯酚醛树脂来改善原油及其衍生产物的冷流动性，以及 在原油中使用烷基酚醛树脂作为沥青质分散剂和由其衍生的产品。

公开(公告)号：US20060020065A1

公开(公告)日：2006-01-26

申请号：US11185387

申请日：2005-07-20

申请人： Matthias Krull ,  Carsten Cohrs ,  Hildegard Freundl ,  Stefan Lorenz

发明人： Matthias Krull ,  Carsten Cohrs ,  Hildegard Freundl ,  Stefan Lorenz

IPC分类号： C08K5/41

CPC分类号： C10L1/143 ,  C10L1/1641 ,  C10L1/195 ,  C10L1/1955 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/198 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/2437 ,  C10L10/14

摘要： The invention provides compositions comprising at least one alkylphenol-aldehyde resin (constituent I) and, based on the alkylphenol resin, from 0.005 to 10% by weight of at least one oil-soluble organic ammonium sulfonate (constituent II).

摘要翻译： 本发明提供包含至少一种烷基酚醛树脂（组分I）和基于烷基酚树脂0.005至10重量％的至少一种油溶性有机磺酸铵（组分II）的组合物。

公开(公告)号：US20050126072A1

公开(公告)日：2005-06-16

申请号：US11009885

申请日：2004-12-10

申请人： Matthias Krull ,  Bettina Siggelkow ,  Martina Hess

发明人： Matthias Krull ,  Bettina Siggelkow ,  Martina Hess

IPC分类号： C10L1/192 ,  C10L1/02 ,  C10L1/04 ,  C10L1/14 ,  C10L1/18 ,  C10L1/195 ,  C10L1/196 ,  C10L1/197 ,  C10L1/22 ,  C10L1/224 ,  C10L1/236 ,  C10L10/14 ,  C10L5/00

CPC分类号： C10L1/1955 ,  C10L1/143 ,  C10L1/146 ,  C10L1/19 ,  C10L1/1963 ,  C10L1/1973 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364

摘要： The invention provides a fuel oil composition F) comprising F1) a fuel oil of mineral origin and F2) a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol% of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units composed of B1) at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety, where the sum Q Q = ∑ i ⁢ w 1 ⁢   ⁢ i · n 1 ⁢ i + ∑ j ⁢ w 2 ⁢ j · n 2 ⁢ j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the amide and/or imide groups of monomer 2 on the other is from 21.0 to 28.0, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radical of the amide and/or imide groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2.

公开(公告)号：US06364918B1

公开(公告)日：2002-04-02

申请号：US09594950

申请日：2000-06-09

申请人： Matthias Krull ,  Waltraud Nagel

发明人： Matthias Krull ,  Waltraud Nagel

IPC分类号： C10L118

CPC分类号： C10L10/08 ,  C08F8/14 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/2364 ,  C10L1/2366

摘要： Oil-soluble copolymers having an OH number of from 10 to 250 and a molecular weight of from 1000 to 100,000 g/mol, obtained from the reaction of a copolymer precursor which comprises structural units of A) from 5 to 95 mol-% of an olefinically unsaturated carboxylic acid or a derivative of such an acid, B) from 5 to 95 mol-% of an olefinically unsaturated compound having at least one hydrocarbon radical containing at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of C1-C6-alkyl (meth)acrylates, C1-C6-alkyl vinyl esters and C2-C6-olefins, with a reagent, which must carry at least one OH group and which, apart from this OH group, has at least one further functional group which is capable of reacting with the carboxylic acid or the derivative of a carboxylic acid as in component A), where the residual acid number is set to a value below 50 mg of KOH/g of copolymer by addition of the reagent.

摘要翻译： 由共聚物前体的反应获得的羟值为10至250，分子量为1000至100,000g / mol的油溶性共聚物，该共聚物前体包含结构单元A）5至95摩尔％的烯属 不饱和羧酸或这种酸的衍生物，B）5至95摩尔％的具有至少一个含有至少6个碳原子的烃基的烯属不饱和化合物，如果需要，C）0至40摩尔 - 选自由（甲基）丙烯酸C 1 -C 6烷基酯，C 1 -C 6烷基乙烯基酯和C 2 -C 6 - 烯烃组成的组中的另外的结构单元的％与必须携带至少一个OH基团的试剂的％ 除了OH基之外，还有至少一个能够与羧酸或羧酸衍生物反应的另外的官能团，如组分A），其中残余酸值设定为低于50mg的值 KOH / g共聚物。

公开(公告)号：US09221938B2

公开(公告)日：2015-12-29

申请号：US13977326

申请日：2011-12-08

申请人： Matthias Krull ,  Roman Morschhaeuser ,  Hans Juergen Scholz ,  Jochen Stock

发明人： Matthias Krull ,  Roman Morschhaeuser ,  Hans Juergen Scholz ,  Jochen Stock

IPC分类号： C08F8/14 ,  C08F216/06 ,  B01J19/12 ,  C08F8/00 ,  H05B6/80

CPC分类号： C08F216/06 ,  B01J19/126 ,  B01J2219/0884 ,  B01J2219/0888 ,  B01J2219/0892 ,  B01J2219/1215 ,  B01J2219/1227 ,  B01J2219/1287 ,  C08F8/00 ,  C08F8/14 ,  C08F2810/20 ,  H05B6/806 ,  C08F16/06

摘要： The invention relates to polymers carrying ester/hydroxyl groups, containing repetitive structural units of formulae (I) and (II) in a block-wise, alternating or statistical sequence, wherein D represents a direct bond between the polymer backbone and the hydroxyl group, a C1- to C6-alkene group, a C5- to C12-arylene group, an oxyalkene group of formula —O—R2—, an ester group of formula —C(O)—O—R2— or an amide group of formula —C(O)—N(R3)R2—, E represents a hydrocarbon group having 1 to 50 C-atoms, R2 represents a C2- to C10-alkene group, R3 represents hydrogen or a C1- to C10-alkyl group, which can carry substituents, k represents a number between 1 and 1000, n represents a number from 0 to 4999, m represents a number from 1 to 5000, and n+m represents a number between 10 to 5000, under the proviso that a) the molar portion of the structural units (I); on the polymer is between 0 and 99.9 mol-%, and b) the molar portion of the structural units (II) on the polymer is between 0.1 and 100 mol-% of the repetitive units. The invention also relates to a method for the production of said polymers using microwaves.

摘要翻译： 本发明涉及含有分子式（I）和（II）的重复结构单元的酯/羟基的聚合物，其中D表示聚合物主链和羟基之间的直接键， C 1〜C 6烯基，C 5〜C 12亚芳基，式-O-R 2 - 的氧化烯基，式-C（O）-O-R 2 - 的酯基或式 -C（O）-N（R 3）R 2 - ，E表示1〜50个碳原子的烃基，R 2表示C 2〜C 10烯基，R 3表示氢或C 1至C 10烷基， 其可以携带取代基，k表示1至1000之间的数字，n表示0至4999的数，m表示1至5000的数，n + m表示10至5000之间的数字，条件是a） 结构单元（I）的摩尔部分; 在聚合物上的摩尔份数在0至99.9mol％之间，b）聚合物上的结构单元（II）的摩尔份数为重复单元的0.1至100mol％。 本发明还涉及使用微波生产所述聚合物的方法。