公开(公告)号：US5166265A

公开(公告)日：1992-11-24

申请号：US486697

申请日：1990-03-01

Applicant: Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

Inventor： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

IPC: C08G59/00 ,  C08G59/18 ,  C08G59/20 ,  C08G59/40 ,  C08G59/62 ,  C08G59/68 ,  C08G59/70 ,  C08L63/00 ,  C09D163/00 ,  C09D201/04

CPC classification number: C08L63/00 ,  C09D201/04

Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.

Abstract translation: 公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

公开(公告)号：US5043366A

公开(公告)日：1991-08-27

申请号：US481056

申请日：1990-02-16

Applicant: Osamu Isozaki

Inventor： Osamu Isozaki

IPC: C08F8/44

CPC classification number: C08F8/44

Abstract: A self-curing aqueous resin dispersion obtained by neutralizing a resin having at least one alicyclic epoxy group and at least two carboxyl groups in the molecule, with a base and dispersing the neutralized resin in water.

公开(公告)号：US5008328A

公开(公告)日：1991-04-16

申请号：US313367

申请日：1989-02-21

Applicant: Noboru Nakai ,  Osamu Isozaki

Inventor： Noboru Nakai ,  Osamu Isozaki

IPC: C08G77/14 ,  C08G77/22 ,  C08G77/28 ,  C08G77/388 ,  C09D183/04 ,  C09D183/06 ,  C09D183/08

CPC classification number: C09D183/08 ,  C08G77/388 ,  C09D183/06

Abstract: This invention provides an aqueous organosilicon resin coating composition comprising:(I) an aqueous organosilicon resin which is a condensation product and which contains a quaternary ammonium base, the condensation product being prepared from (i) an organosilicon compound represented by the formulaR.sup.1.sub.a Si(OR.sup.2).sub.4-a (A) wherein R.sup.1 is hydrocarbon group having 1 to 12 carbon atoms, R.sup.2 is hydrocarbon group having 1 to 8 carbon atoms and a is 0, 1 or 2, and/or a low condensate thereof and (ii) an organosilicon compound represented by the formula ##STR1## wherein R.sup.3 is hydrogen atom or methyl group, R.sup.4 is bivalent hydrocarbon group having 1 to 8 carbon atoms and R.sup.2 is as defined above, and/or a low condensate thereof and,(II) an aqueous medium.

Abstract translation: 本发明提供一种水性有机硅树脂涂料组合物，其包含：（I）水性有机硅氧烷树脂，其为缩合产物并且含有季铵碱，所述缩合产物由（i）由式R 1a a（OR 2）表示的有机硅化合物 ）4-a（A）其中R 1是具有1至12个碳原子的烃基，R 2是具有1至8个碳原子的烃基，a是0,1或2，和/或其低缩合物和（ii） 由式（B）表示的有机硅化合物，其中R 3为氢原子或甲基，R 4为碳原子数为1〜8的二价烃基，R 2如上所定义，和/或低级缩合物，（II） ）水性介质。

公开(公告)号：US4923930A

公开(公告)日：1990-05-08

申请号：US272959

申请日：1988-11-18

Applicant: Naozumi Iwasawa ,  Osamu Isozaki

Inventor： Naozumi Iwasawa ,  Osamu Isozaki

IPC: C08F2/06 ,  C08F2/44 ,  C08F283/00 ,  C08F283/02 ,  C08K5/00

CPC classification number: C08F283/02 ,  C08F283/006 ,  C08K5/0091

Abstract: This invention provides a curable resin obtained by polymerizing at least one of an alkoxysiloxane-containing vinyl monomer and a polysiloxane macromonomer with an oxirane-containing vinyl monomer in the presence of a polymerization initiator and a resin having in the molecule a carboxyl group and/or an alicyclic hydrocarbon ring having one or two hydrogen atoms bonded to at least one carbon atom forming the alicyclic hydrocarbon ring; and a resin composition curable at a low temperature comprising the curable resin as defined above and a chelate compound.

Abstract translation: 本发明提供一种固化树脂，其通过在聚合引发剂和分子内具有羧基和/或其分子的树脂的存在下将含烷氧基硅氧烷的乙烯基单体和聚硅氧烷大分子单体中的至少一种与含环氧乙烷的乙烯基单体聚合而获得， 具有一个或两个氢原子与形成脂环烃环的至少一个碳原子键合的脂环烃环; 以及包含上述固化性树脂的低温可固化的树脂组合物和螯合化合物。

公开(公告)号：US4772672A

公开(公告)日：1988-09-20

申请号：US47392

申请日：1987-05-08

Applicant: Osamu Isozaki ,  Noboru Nakai

Inventor： Osamu Isozaki ,  Noboru Nakai

IPC: C08F4/06 ,  C08F230/08 ,  C08K5/00 ,  C08F4/52 ,  C08F24/00

CPC classification number: C08K5/0091 ,  C08F230/08

Abstract: The present invention provides a curable composition characterized in that the composition comprises a copolymer comprising as monomer components an oxirane-containing vinyl monomer and a specific alkoxysilane-containing vinyl monomer, and as a crosslinking curing agent at least one of an aluminum chelate compound and a zirconium chelate compound having neither of hydroxyl and alkoxyl directly combined with zirconium. The invention also provides a curing method characterized in that the composition is cured at a temperature of up to 100.degree. C. in the presence of water.

Abstract translation: 本发明提供一种可固化组合物，其特征在于该组合物包含含有环氧乙烷的乙烯基单体和含特定烷氧基硅烷的乙烯基单体作为单体成分的共聚物，作为交联固化剂，可以使用铝螯合物和 没有羟基和烷氧基直接与锆结合的锆螯合物。 本发明还提供一种固化方法，其特征在于该组合物在水存在下在高达100℃的温度下固化。

公开(公告)号：US4385097A

公开(公告)日：1983-05-24

申请号：US956996

申请日：1978-10-31

Applicant: Osamu Isozaki ,  Shun-ichi Kodama

Inventor： Osamu Isozaki ,  Shun-ichi Kodama

IPC: C08G59/70 ,  C08K5/00 ,  C09D5/00 ,  C09D5/02 ,  C09D5/08 ,  C09D133/14 ,  C09D175/04 ,  C09D201/02 ,  C09D201/06 ,  B32B15/08 ,  C08K5/04 ,  C08K5/17

CPC classification number: C09D175/04 ,  C08G59/70 ,  C08K5/0091 ,  C08K5/05 ,  C08K5/07 ,  C08K5/09 ,  C08K5/17 ,  C09D133/14 ,  C09D201/02 ,  C09D5/08 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31696

Abstract: An anticorrosive coating composition comprising (i) an aqueous medium, and dispersed therein, (ii) a water-soluble, film-forming and crosslinkable resin having a hydroxyl group and a proton-free onium salt radical and (iii) a chelate compound of titanium or zirconium.

Abstract translation: 一种防腐涂料组合物，其包含（i）水性介质并分散在其中，（ii）具有羟基和不质子鎓鎓盐基团的水溶性成膜和可交联树脂，和（iii）螯合化合物 钛或锆。

公开(公告)号：US4224357A

公开(公告)日：1980-09-23

申请号：US846797

申请日：1977-10-31

Applicant: Hiroshi Iwai ,  Hajime Sukejima ,  Osamu Isozaki

Inventor： Hiroshi Iwai ,  Hajime Sukejima ,  Osamu Isozaki

IPC: B05D3/06 ,  B05D3/02

CPC classification number: B05D3/06 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31605 ,  Y10T428/31681 ,  Y10T428/31696 ,  Y10T428/31699

Abstract: A method and a composition for forming electron beam curing high build coating film which method comprises the steps of preparing a specified coating composition, applying it to the surface of a substrate to be coated, and curing the coating film with the irradiation of electron beams or ultraviolet rays. The coating composition of the invention comprises a polymerizable resin (I) as the main vehicle component which is cured by the irradiation of electron beams or ultraviolet rays and has at least two polymerizable unsaturated double bonds and at least one hydroxyl group in its molecule, and a polyisocyanate compound (II). Further, a resin (III) having active unsaturated groups can be added to the above coating composition so as to improve the pot life of the composition.

Abstract translation: 一种形成电子束固化高效涂膜的方法和组合物，该方法包括以下步骤：制备指定的涂料组合物，将其施加到待涂布的基材的表面上，并用电子束的照射固化涂膜; 紫外线。 本发明的涂料组合物包含作为主要载体成分的可聚合树脂（I），其通过电子束或紫外线的照射固化并且在其分子中具有至少两个可聚合不饱和双键和至少一个羟基，以及 多异氰酸酯化合物（II）。 此外，可以向上述涂料组合物中加入具有活性不饱和基团的树脂（III），以提高组合物的适用期。