公开(公告)号：US20080161477A1

公开(公告)日：2008-07-03

申请号：US11648287

申请日：2006-12-28

申请人： Richard W. Cruse ,  W. Michael York ,  Eric R. Pohl ,  Antonlo Chaves ,  Prashant Joshi

发明人： Richard W. Cruse ,  W. Michael York ,  Eric R. Pohl ,  Antonlo Chaves ,  Prashant Joshi

IPC分类号： C08G77/12 ,  C08G77/06 ,  C08L83/16

CPC分类号： C08K5/548 ,  C07F7/1804 ,  C08L21/00

摘要： This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.

摘要翻译： 本发明涉及新型含硫硅烷偶联剂和含有碳 - 碳双键的有机聚合物。 这些新型硅烷可以带有机和无机填料。 本发明还涉及由本文所述的弹性体组合物制成的制品，特别是轮胎。

公开(公告)号：US20080161463A1

公开(公告)日：2008-07-03

申请号：US11647903

申请日：2006-12-28

申请人： Richard W. Cruse ,  W. Michael York ,  Eric R. Pohl ,  Prashant Joshi

发明人： Richard W. Cruse ,  W. Michael York ,  Eric R. Pohl ,  Prashant Joshi

IPC分类号： C08K5/24 ,  C08F283/12 ,  C08G8/34 ,  C08L83/02 ,  C08J3/24

CPC分类号： C08K5/548 ,  C08K3/013 ,  C08K3/04 ,  C08K3/36 ,  C08K9/06 ,  C08L21/00

摘要： This invention relates to novel free-flowing filler compositions containing silated cyclic core polysulfide coupling agents, and to a rubber containing the filler composition.

摘要翻译： 本发明涉及含有硅烷化环状核多硫化物偶联剂的新型自由流动填料组合物和含有填料组合物的橡胶。

公开(公告)号：US07301042B2

公开(公告)日：2007-11-27

申请号：US10128804

申请日：2002-04-23

申请人： Richard W. Cruse

发明人： Richard W. Cruse

IPC分类号： C07F7/08

CPC分类号： C07F9/4012 ,  B60C1/00 ,  C07F7/0876 ,  C08K3/013 ,  C08K5/548 ,  C08L21/00

摘要： Rubber composition intended for the manufacture of tire casings which have improved hysteretic properties and scorch safety, based on at least one elastomer and silica by way of reinforcing filler enclosing a reinforcing additive consisting of the mixture and/or the product of in situ reaction of at least one functionalized polyorganosiloxane compound containing, per molecule, at least one functional siloxy unit capable of bonding chemically and/or physically to the surface hydroxyl sites of the silica particles and at least one functionalized organosilane compound containing, per molecule, at least one functional group capable of bonding chemically and/or physically to the polyorganosiloxane and/or the hydroxyl sites of the silica particles and at least one other functional group capable of bonding chemically and/or physically to the polymer chains.

摘要翻译： 用于制造具有改进的滞后性能和焦烧安全性的轮胎胎体的橡胶组合物，其基于至少一种弹性体和二氧化硅，通过增强填料，所述增强填料包封由混合物组成的增强添加剂和/或由 至少一种官能化聚有机硅氧烷化合物，每分子含有至少一个功能性甲硅烷氧基单元，其能够化学和/或物理地结合二氧化硅颗粒的表面羟基位点和至少一种官能化的有机硅烷化合物，每个分子含有至少一个官能团 能够化学和/或物理地结合二氧化硅颗粒的聚有机硅氧烷和/或羟基位点和能够化学和/或物理结合到聚合物链上的至少一个其它官能团。

公开(公告)号：US07138537B2

公开(公告)日：2006-11-21

申请号：US10405721

申请日：2003-04-02

申请人： Richard W. Cruse ,  Robert J. Pickwell

发明人： Richard W. Cruse ,  Robert J. Pickwell

IPC分类号： C07F7/04 ,  B60C1/00

CPC分类号： C08K5/548 ,  C08K5/5419 ,  C08K9/06 ,  C08L21/00

摘要： A composition of matter is disclosed that comprises at least one silane coupling agent for coupling an elastomer and a filler wherein said silane comprises at least one hydrolyzable group that, upon compounding said silane with said elastomer and filler, is released to yield a compound that improves downstream processability of the compounded composition or the properties of the final rubber product or both.

摘要翻译： 公开了一种物质组合物，其包含用于偶联弹性体和填料的至少一种硅烷偶联剂，其中所述硅烷包含至少一种可水解基团，其在将所述硅烷与所述弹性体和填料混合后，释放以产生改进的化合物 复合组合物的下游加工性或最终橡胶制品的性能或两者兼有。

公开(公告)号：US06414061B1

公开(公告)日：2002-07-02

申请号：US09284841

申请日：1999-04-21

申请人： Richard W. Cruse ,  Robert J. Pickwell ,  Keith J. Weller ,  Eric R. Pohl

发明人： Richard W. Cruse ,  Robert J. Pickwell ,  Keith J. Weller ,  Eric R. Pohl

IPC分类号： C08K55419

CPC分类号： C07F9/4075 ,  C07F7/1804 ,  C07F9/1651 ,  C08J3/203 ,  C08J2321/00 ,  C08K3/013 ,  C08K3/36 ,  C08K5/0025 ,  C08K5/5406 ,  C08K5/548 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L2666/08

摘要： This invention describes novel blocked mercaptosilanes wherein the hydrogen atom of the mercaptan functionality has been substituted. The invention includes methods of preparation for the blocked mercaptosilicon compounds as well as their use in filled rubbers. The blocked mercaptosilanes described are unique in that they allow the mixing of fillers with organic polymers to proceed while remaining inert toward coupling to the polymer. The coupling reactions of these blocked mercaptosilicon compounds are triggered by addition of an appropriate deblocking agent.

摘要翻译： 本发明描述了其中硫醇官能团的氢原子已经被取代的新的封端巯基硅烷。 本发明包括制备封端巯基硅化合物的方法及其在填充橡胶中的用途。 所述封端的巯基硅烷是独特的，因为它们允许填料与有机聚合物的混合进行，同时保持惰性以与聚合物偶联。 这些封端巯基硅化合物的偶联反应是通过加入适当的去封闭剂来触发的。

公开(公告)号：US06204339B1

公开(公告)日：2001-03-20

申请号：US09245454

申请日：1999-02-05

申请人： Bruce A. Waldman ,  Misty Weiyu Huang ,  Richard W. Cruse

发明人： Bruce A. Waldman ,  Misty Weiyu Huang ,  Richard W. Cruse

IPC分类号： C08C1926

CPC分类号： C07F9/4075 ,  C07F7/1804 ,  C07F9/1651 ,  C08J3/203 ,  C08J2321/00 ,  C08K3/013 ,  C08K3/36 ,  C08K5/0025 ,  C08K5/5406 ,  C08K5/548 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L2666/08

摘要： This invention describes the use of blocked mercaptosilanes wherein the hydrogen atom of the mercaptan functionality has been substituted to manufacture coating, adhesive, sealant and elastomeric compositions. The blocked mercaptosilanes described are unique in that they allow the application of elastomers to substrates to proceed while remaining inert toward coupling to the catalyst. The coupling reactions of these blocked mercaptosilicon compounds are triggered by exposure to an appropriate deblocking agent.

摘要翻译： 本发明描述了其中硫醇官能团的氢原子被取代以制造涂料，粘合剂，密封剂和弹性体组合物的封端巯基硅烷的用途。 所述的封端的巯基硅烷是独特的，因为它们允许将弹性体施加到基底上，同时保持惰性以与催化剂偶合。 这些封端的巯基硅化合物的偶联反应是通过暴露于适当的去块剂来触发的。

公开(公告)号：US20120130105A1

公开(公告)日：2012-05-24

申请号：US13302506

申请日：2011-11-22

申请人： Kenrick M. Lewis ,  Aaron M. Tondreau ,  Richard W. Cruse ,  Keith J. Weller ,  Johannes G.P. Delis ,  Susan A. Nye ,  Paul J. Chirik

发明人： Kenrick M. Lewis ,  Aaron M. Tondreau ,  Richard W. Cruse ,  Keith J. Weller ,  Johannes G.P. Delis ,  Susan A. Nye ,  Paul J. Chirik

IPC分类号： C07F7/08 ,  C07F7/18

CPC分类号： C07F15/025 ,  B01J31/1805

摘要： Disclosed herein is the selective synthesis of mono-hydrosilylated derivatives of polyunsaturated compounds, such as trivinylcyclohexane using non-precious metal based pyridinediimine and terpyridine complex as selective hydrosilylation catalysts.

摘要翻译： 本文公开了多不饱和化合物的单氢化硅烷化衍生物的选择性合成，例如使用非贵金属的吡啶二亚胺和三联吡啶络合物作为选择性氢化硅烷化催化剂的三乙烯基环己烷。

公开(公告)号：US08124206B2

公开(公告)日：2012-02-28

申请号：US12290368

申请日：2008-10-30

申请人： Richard W. Cruse ,  William Michael York ,  Carla Recker ,  Thomas Kramer ,  Katharina Herzog

发明人： Richard W. Cruse ,  William Michael York ,  Carla Recker ,  Thomas Kramer ,  Katharina Herzog

IPC分类号： B32B1/08 ,  C08L9/00 ,  C08F8/34 ,  C08F8/00 ,  C08F236/20

CPC分类号： C08K5/549 ,  C08K3/013 ,  C08K5/0025 ,  C08K5/06 ,  C08K5/09 ,  C08K5/13 ,  C08K5/42 ,  C08L7/00 ,  C08L9/02 ,  C08L9/06 ,  C08L23/22 ,  Y10T428/139 ,  C08L21/00 ,  C08L2666/06 ,  C08L2666/02

摘要： A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(═O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RsiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.

摘要翻译： 可用作填充硫可硫化弹性体组合物的交联剂的含硫脂环族化合物由通式表示：G [-CaH2a-S [C（= O）] bR] n其中G选自 含有5至12个碳原子并且任选地含有至少一个卤素的饱和单价脂族基团n和价数n的饱和单环硅氧烷[RsiO - ] n [R 2 SiO] - 基团; 其中每个R独立地为氢或至多20个碳原子的一价烃; 每个出现的下标a和b独立地是其中a是2至6并且b是0或1的整数; p是0至3的整数; n为3〜6的整数，条件是当b为0时，R为氢原子，当G为6个碳原子的非卤代饱和单环脂肪族基团时，n不能为3。

公开(公告)号：US20100317796A1

公开(公告)日：2010-12-16

申请号：US12767715

申请日：2010-04-26

申请人： Misty Huang ,  Richard W. Cruse ,  Benjamin Falk ,  Eric Pohl ,  Shiu-Chin Su ,  Jeries Nesheiwat ,  Philbert Ramdatt

发明人： Misty Huang ,  Richard W. Cruse ,  Benjamin Falk ,  Eric Pohl ,  Shiu-Chin Su ,  Jeries Nesheiwat ,  Philbert Ramdatt

IPC分类号： C08L83/00

CPC分类号： C08G18/837 ,  C07F7/18 ,  C08G2/10 ,  C08G18/10 ,  C08G18/289 ,  C08G18/48 ,  C08G18/718 ,  C08L101/10 ,  C09D175/08 ,  C09J175/04 ,  C09J175/08 ,  C09J201/10

摘要： A moisture-curable resin composition comprising (a) a moisture-curable polymer having at least one hydrolysable silyl group; (b) a reactive modifier; (c) a catalyst for catalyzing the reaction between the moisture-curable polymer (a) and reactive modifier (b) under curing conditions; and optionally, the composition can contain one or more conventional components, including pigments, fillers, curing catalysts, dyes, plasticizers, thickeners, coupling agents, extenders, volatile organic solvents, wetting a agents, tackifiers, crosslinking agents, thermoplastic polymers, ultraviolet stabilizers, and combination thereof. The moisture-curable resin composition is useful in the production of adhesives including hot melt adhesives, primers, sealants and coatings.

摘要翻译： 一种湿气固化树脂组合物，其包含（a）具有至少一个可水解甲硅烷基的湿气固化性聚合物; （b）反应性改性剂; （c）在固化条件下催化可湿固化聚合物（a）和反应性改性剂（b）之间的反应的催化剂; 并且任选地，组合物可以包含一种或多种常规组分，包括颜料，填料，固化催化剂，染料，增塑剂，增稠剂，偶联剂，增量剂，挥发性有机溶剂，润湿剂，增粘剂，交联剂，热塑性聚合物，紫外线稳定剂 ，及其组合。 可湿固化树脂组合物可用于生产包括热熔粘合剂，底漆，密封剂和涂料的粘合剂。

公开(公告)号：US20100112258A1

公开(公告)日：2010-05-06

申请号：US12290367

申请日：2008-10-30

申请人： Richard W. Cruse ,  William Michael York ,  Carla Recker

发明人： Richard W. Cruse ,  William Michael York ,  Carla Recker

IPC分类号： C08L23/26 ,  C07C321/00 ,  C09K3/00 ,  B32B1/08

CPC分类号： C08G75/14 ,  Y10T428/139

摘要： A crosslinked polysulfide-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: [(CaH2a-)mG1(-CbH2bSx—)n−m]o[CcH2c-G2-CdH2dSy—]p[R]q wherein G1 is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—]n[R2SiO—]r group of valence n; G2 is a saturated, divalent cyclic aliphatic group of valence 2 containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—]n[R2SiO—]r group of valence n; each R independently is a selected from the group consisting of a hydrogen atom, monovalent hydrocarbon of up to 20 carbon atoms and a halogen atom; each occurrence of subscripts a, b, c, d, m, n, o, p, q, x and y independently is an integer wherein a is 2 to 6; b is 2 to 6; c is 1 to 6; d is 1 to 6; m is 1 or 2; n is 3 to 5; o is a positive integer, p is 0 or a positive integer; q is a positive integer; r is an integer of from 0 to 3; x is 1 to 10 and y is 1 to 10, with the provisos that, (i) at least one x is 2 to 10; (ii) the ratio of p to o is less than 1 to 5; and q is equal to the sum of unfilled valences of the (CaH2a-)mG1(-CbH2bSx—)n−m and CcH2c-G2-CdH2dSy— groups.

摘要翻译： 可用作填充的硫可硫化弹性体组合物的交联剂的交联的含多硫醚的脂环族化合物由以下通式表示：[（CaH2a）mG1（-CbH2bSx-）n-m] o [CcH2c-G2-CdH2dSy- ] p [R] q其中G1是含有5至12个碳原子并且任选地含有至少一个卤素或饱和单环硅氧烷[RSiO - ] n [R 2 SiO] - 基的化合价的饱和单价脂族基团n n; G 2是含有5至12个碳原子并且任选地含有至少一个卤素或饱和单环硅氧烷[RSiO - ] n [R 2 SiO] - 基的价数n的饱和二价环状脂肪族基团; 每个R独立地选自氢原子，至多20个碳原子的一价烃和卤素原子; 每个出现的下标a，b，c，d，m，n，o，p，q，x和y独立地是其中a是2至6的整数; b为2〜6; c为1〜6; d为1〜6; m为1或2; n为3〜5; o是正整数，p是0或正整数; q是正整数; r为0〜3的整数; x为1至10且y为1至10，条件是（i）至少一个x为2至10; （ii）p与o之比小于1至5; 且q等于（CaH2a）mG1（-CbH2bSx-）n-m和CcH2c-G2-CdH2dSy-基团的未饱和化合价的总和。