摘要:
A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(═O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.
摘要:
A crosslinked polysulfide-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: [(CaH2a-)mG1(-CbH2bSx—)n−m]o[CcH2c-G2-CdH2dSy—]p[R]q wherein G1 is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—]n[R2SiO—]r group of valence n; G2 is a saturated, divalent cyclic aliphatic group of valence 2 containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—]n[R2SiO—]r group of valence n; each R independently is a selected from the group consisting of a hydrogen atom, monovalent hydrocarbon of up to 20 carbon atoms and a halogen atom; each occurrence of subscripts a, b, c, d, m, n, o, p, q, x and y independently is an integer wherein a is 2 to 6; b is 2 to 6; c is 1 to 6; d is 1 to 6; m is 1 or 2; n is 3 to 5; o is a positive integer, p is 0 or a positive integer; q is a positive integer; r is an integer of from 0 to 3; x is 1 to 10 and y is 1 to 10, with the provisos that, (i) at least one x is 2 to 10; (ii) the ratio of p to o is less than 1 to 5; and q is equal to the sum of unfilled valences of the (CaH2a-)mG1(-CbH2bSx—)n−m and CcH2c-G2-CdH2dSy— groups.
摘要翻译:可用作填充的硫可硫化弹性体组合物的交联剂的交联的含多硫醚的脂环族化合物由以下通式表示:[(CaH2a)mG1(-CbH2bSx-)nm] o [CcH2c-G2-CdH2dSy-] p [R] q,其中G1是含有5至12个碳原子并且任选地含有至少一个卤素或饱和单环硅氧烷[RSiO - ] n [R 2 SiO] - 基的价数n的饱和单环脂族基团n; G 2是含有5至12个碳原子并且任选地含有至少一个卤素或饱和单环硅氧烷[RSiO - ] n [R 2 SiO] - 基的价数n的饱和二价环状脂肪族基团; 每个R独立地选自氢原子,至多20个碳原子的一价烃和卤素原子; 每个出现的下标a,b,c,d,m,n,o,p,q,x和y独立地是其中a是2至6的整数; b为2〜6; c为1〜6; d为1〜6; m为1或2; n为3〜5; o是正整数,p是0或正整数; q是正整数; r为0〜3的整数; x为1至10且y为1至10,条件是(i)至少一个x为2至10; (ii)p与o之比小于1至5; 且q等于(CaH2a)mG1(-CbH2bSx-)n-m和CcH2c-G2-CdH2dSy-基团的未饱和化合价的总和。
摘要:
A tire composition with a Shore A hardness, according to DIN 53 505 and ASTM D2240, of not less than 40 and not greater than 95 and a glass-transition temperature Tg (E″max), according to DIN 53 513 with a specified temperature sweep of −80° C. to +80° C. and a specified compression of 10+0.2% at 10 Hz, not less than −80° C. and not greater than 0° C., with improved abrasion performance, in particular for pneumatic tires, has the following composition: at least one vulcanizable diene rubber selected from natural rubbers, synthetic polyisoprene rubbers, polyisobutylene rubbers, polybutadiene rubbers (BR), and random styrene-butadiene rubbers; from 35 to 300 phr of at least one active filler selected from carbon blacks, silicas, silicon based fillers, and metal oxides, of which at least 10 phr must be carbon blacks, silicas, or some combination thereof; from 0 to 250 phr of other or further additives; from 0.1·10−3 to 42·10−3 mhr (mol per hundred parts of rubber) of a vulcanizing agent which crosslinks with a functionality>4; and from 0.1 to 10 phr of at least one vulcanization accelerator.
摘要:
A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(═O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.
摘要:
The invention relates to a rubber mixture, in particular for vehicle air-inflated tires, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: at least one polar or non-polar rubber and at least one bright and/or dark filler and at least one softener, wherein the softener is free of polycyclic aromatics according to Directive 76/769/EEC, and wherein the carbon source for the softener comes from non-fossil sources, and other additives.
摘要:
The vulcanizable rubber mixture according to this invention is used for rubber products in particular vehicle tires and vehicle tire treads, but also technical rubber products like belts on conveyor systems, technical hoses, vibration dampers and impact dampers, or wire coatings. All these products benefit from the improved processability that is achieved with the invention in that the mixture comprises a polymer represented by the formula F1-A-F2, or a mixture of F1-A-F2 with an astral or radial coupling product of F1-A-units, coupled by a multivalent coupling agent; wherein F1 represents a terminal functionalization of the polymeric chain, F2 represents a terminal functionalization different from F1; and A represents the polymeric chain of a polymer formed by the copolymerization between one or more conjugated dienes with one or more aromatic vinyl monomers.
摘要:
A tire composition is provided that may include a sulfur-functional linear polyorganosiloxane and an unsaturated elastomer. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group, which includes a thiocarbamate, a dithiocarbamate, or a derivative or analog of thiocarbamate or dithiocarbamate. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in tire compositions.
摘要:
A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(═O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.
摘要:
The invention relates to a rubber mixture, in particular for pneumatic vehicle tires, bands, and belts. The rubber mixture is characterized by the following composition: at least one diene rubber and—at least one precipitated silicic acid having a CTAB surface area greater than or equal to 150 m2/g and a BET surface area greater than or equal to 150 m2/g and a DBP number between 180 and 350 g/100 g and a full width at half maximum, which is standardized to the location of the reflection, of the reflection of less than or equal to 0.95 and a homogeneity ratio d 25% to d 75% of 1.00 to 1.80 and a relative width Ypressed in the compressed state of less than or equal to 2.8 (g nm)/ml and a fineness index F.V.pressed in the compressed state between 100 and 140, and further additives.
摘要:
A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(═O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RsiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.