利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

277 条记录 (耗时 0.054 秒)

    Method for producing N,N-substituted-3-aminopropan-1-ols
    61.
    发明授权
    Method for producing N,N-substituted-3-aminopropan-1-ols 有权
    制备N，N-取代-3-氨基丙-1-醇的方法

    公开(公告)号：US08536377B2

    公开(公告)日：2013-09-17

    申请号：US13127828

    申请日：2009-11-02

    申请人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Martin Ernst

    发明人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Martin Ernst

    IPC分类号： C07C213/00

    CPC分类号： C07C213/02 ,  C07C227/08 ,  Y02P20/582 ,  C07C215/08 ,  C07C229/12

    摘要： The present invention relates to a process for preparing N,N-substituted 3-aminopropan-1-ols by a) reacting secondary amine with acrolein at a temperature of (−50) to 100° C. and a pressure of 0.01 to 300 bar, and b) reacting the reaction mixture obtained in stage a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a pressure of 1 to 400 bar, wherein the molar ratio of secondary amine to acrolein in stage a) is 1:1 or more and the temperature in stage b) is in the range from (−50) to 70° C. In a preferred embodiment, acrolein which has been obtained from glycerol based on renewable raw materials is used. The invention further relates to the use of an N,N-dimethyl-3-aminopropan-1-ol (DMAPOL) based on renewable raw materials as a catalyst for polyurethane preparation, as a scrubbing fluid in gas scrubbing, in the electronics chemicals and electroplating sectors, as a feedstock in organic synthesis, and as an intermediate in the production of pharmaceuticals and crop protection compositions.

    摘要翻译： 本发明涉及一种通过以下步骤制备N，N-取代的3-氨基丙-1-醇的方法：a）在（-50）至100℃的温度和0.01至300巴的压力下使仲胺与丙烯醛反应 ，和b）在加氢催化剂存在下，在1至400巴的压力下，将a）中获得的反应混合物与氢气和氨反应，其中a）步中仲胺与丙烯醛的摩尔比为1:1 或更高，步骤b）中的温度在（-50）至70℃的范围内。在优选的实施方案中，使用了基于可再生原料从甘油获得的丙烯醛。 本发明还涉及使用基于可再生原料的N，N-二甲基-3-氨基丙-1-醇（DMAPOL）作为聚氨酯制备的催化剂，在电气化学品中用作气体洗涤中的洗涤液， 电镀部门，作为有机合成中的原料，以及作为药物和作物保护组合物生产中的中间体。

    Method for producing N,N-substituted-1,3-propandiamines
    62.
    发明授权
    Method for producing N,N-substituted-1,3-propandiamines 有权
    制备N，N-取代-1,3-丙二胺的方法

    公开(公告)号：US08461391B2

    公开(公告)日：2013-06-11

    申请号：US12991767

    申请日：2009-05-11

    申请人： Martin Ernst ,  Johann-Peter Melder ,  Christof Wilhelm Wigbers

    发明人： Martin Ernst ,  Johann-Peter Melder ,  Christof Wilhelm Wigbers

    IPC分类号： C07C209/60

    CPC分类号： C07C211/11 ,  C07C209/60 ,  Y02P20/582

    摘要： The present invention relates to a process for preparing N,N-substituted 1,3-propanediamine by a) reacting secondary amine with acrolein at a temperature of from (−50) to 100° C. and a pressure of from 0.01 to 300 bar, and b) reacting the reaction mixture obtained in stage a) with hydrogen and ammonia in the presence of a hydrogenation catalyst at a temperature of from 40 to 400° C. and a pressure of from 1 to 400 bar, wherein the molar ratio of secondary amine to acrolein in stage a) is 2:1 or more and the hydrogenation catalyst used in stage b) comprises cobalt. In a preferred embodiment, acrolein which has been obtained from glycerol based on renewable raw materials is used. The invention further relates to the use of N,N-dimethyl-1,3-propanediamine (DMAPA) based on renewable raw materials as a feedstock for lubricant soaps and other detergents, coagulants, polymers and comb polymers. In a further preferred embodiment, stage b) is performed in the presence of water.

    摘要翻译： 本发明涉及一种通过以下步骤制备N，N-取代的1,3-丙二胺的方法：a）在（-50）至100℃的温度和0.01至300巴的压力下使仲胺与丙烯醛反应 和b）在加氢催化剂存在下，在40〜400℃，压力为1〜400巴下，使a）中获得的反应混合物与氢气和氨反应，其中摩尔比 阶段a）中的仲胺与丙烯醛的比例为2:1或更高，而阶段b）中使用的氢化催化剂包括钴。 在优选的实施方式中，使用从基于可再生原料的甘油获得的丙烯醛。 本发明还涉及基于可再生原料的N，N-二甲基-1,3-丙二胺（DMAPA）作为润滑剂皂和其它洗涤剂，凝结剂，聚合物和梳状聚合物的原料的用途。 在另一优选实施方案中，步骤b）在水的存在下进行。

    PROCESS FOR PREPARING A CYCLIC TERTIARY AMINE
    66.
    发明申请
    PROCESS FOR PREPARING A CYCLIC TERTIARY AMINE 有权
    制备循环胺的方法

    公开(公告)号：US20120095221A1

    公开(公告)日：2012-04-19

    申请号：US13273784

    申请日：2011-10-14

    申请人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Bernd Stein ,  Harald Meißner

    发明人： Christof Wilhelm Wigbers ,  Johann-Peter Melder ,  Bernd Stein ,  Harald Meißner

    IPC分类号： C07D295/03

    CPC分类号： C07D295/03 ,  C07D295/023

    摘要： A process for preparing a cyclic tertiary amine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, and the radical R2 is a linear or branched C2-C16-alkyl, C5-C7-cycloalkyl or C7-C20-aralkyl, in which (i) an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) and aminoethylethanolamine of the formula IIa where R1 is as defined above or hydrogen (H), in which case R1═R2 in the amine I, is reacted with a primary or secondary alcohol R2OH (III) at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst in a reactor.

    摘要翻译： 其中A是C 4 - 亚烷基，C 5 - 亚烷基或 - （CH 2）2 -B-（CH 2）2 - 基团，其中B是氧（O））的式I的环状叔胺的方法， 或N-R 1基团，并且R 1是C 1 -C 5 - 烷基，芳基或C 5 -C 7 - 环烷基，并且基团R 2是直链或支链C 2 -C 16 - 烷基，C 5 -C 7 - 环烷基或C 7 -C 20 - 芳烷基， 其中（i）由式IIa的其中R1如上所定义的氢原子（H）的1,4-氨基丁醇，1,5-氨基戊醇，氨基二甘醇（ADG）和氨基乙基乙醇胺组成的组中的氨基醇II，其中 在胺I中的情况R1 = R2在初级醇或仲醇R 2 OH（III）中，在含有铜的非均相催化剂的存在下，在液相中在150-270℃的温度下反应 反应堆。

    USE OF LINEAR TRIETHYLENTETRAMINE AS CURING AGENT FOR EPOXY RESINS
    69.
    发明申请
    USE OF LINEAR TRIETHYLENTETRAMINE AS CURING AGENT FOR EPOXY RESINS 审中-公开
    线性三乙烯胺作为环氧树脂固化剂的使用

    公开(公告)号：US20110218270A1

    公开(公告)日：2011-09-08

    申请号：US13039109

    申请日：2011-03-02

    申请人： DOMINIC SUTER ,  Manfred Kinscherff ,  Kirsten Dahmen ,  Hendrik Heising ,  Achim Kaffee ,  Johann-Peter Melder ,  Boris Buschhaus ,  Kevin Huyghe ,  Gunther van Cauwenberge

    发明人： DOMINIC SUTER ,  Manfred Kinscherff ,  Kirsten Dahmen ,  Hendrik Heising ,  Achim Kaffee ,  Johann-Peter Melder ,  Boris Buschhaus ,  Kevin Huyghe ,  Gunther van Cauwenberge

    IPC分类号： C08L63/00 ,  C08G69/34 ,  C09K3/00

    CPC分类号： C08G59/502 ,  C08G69/34 ,  C08L63/00 ,  C09K3/00

    摘要： The present invention relates to an amine composition comprising linear triethylene-tetramine and one or more amine compounds selected from the group consisting of tertiary amines derived from the condensation of ethylenediamine and methyl-substituted compounds derived from linear triethylenetetramine as well as a method of production for said composition.The present invention also relates to the use of linear triethylenetetramine or an amine composition according to the invention as amine curing agents.The present invention also relates to amine curing agent compositions comprising linear triethylenetetramine as well as to curable compositions comprising linear triethylenetetramine and to a method for producing said curable compositions.Additionally, the present invention relates to a cured epoxy resin comprising linear triethylenetetramine, especially a reinforced composite, and a method for producing said cured epoxy resins.Furthermore, the present invention relates to reactive polyamide resins obtainable from linear triethylenediamine and dimer fatty acids.

    摘要翻译： 本发明涉及包含直链三亚乙基四胺和一种或多种胺化合物的胺组合物，所述胺化合物选自由乙二胺缩合得到的叔胺和衍生自线性三亚乙基四胺的甲基取代的化合物，以及制备方法 所说的组合。 本发明还涉及线性三亚乙基四胺或根据本发明的胺组合物作为胺固化剂的用途。 本发明还涉及包含线性三亚乙基四胺的胺固化剂组合物以及包含线性三亚乙基四胺的可固化组合物以及制备所述可固化组合物的方法。 另外，本发明涉及包含直链三亚乙基四胺，特别是增强复合材料的固化环氧树脂，以及制备所述固化环氧树脂的方法。 此外，本发明涉及由直链三亚乙基二胺和二聚脂肪酸得到的反应性聚酰胺树脂。

    PROCESS FOR THE SYNTHESIS OF DMAPA
    70.
    发明申请
    PROCESS FOR THE SYNTHESIS OF DMAPA 有权
    合成DMAPA的方法

    公开(公告)号：US20100105952A1

    公开(公告)日：2010-04-29

    申请号：US12683015

    申请日：2010-01-06

    申请人： Martin Ernst ,  Steffen Oehlenschläger ,  Frank Kuhnke ,  Karl-Heinz Roß ,  Roland Deeg ,  Johann-Peter Melder

    发明人： Martin Ernst ,  Steffen Oehlenschläger ,  Frank Kuhnke ,  Karl-Heinz Roß ,  Roland Deeg ,  Johann-Peter Melder

    IPC分类号： C07C209/02 ,  B01J19/00

    CPC分类号： C07C209/48 ,  B01J2219/00006 ,  C07C253/30 ,  C07C211/11 ,  C07C255/24

    摘要： The present invention relates to a process for the industrial preparation of a diamine starting from a corresponding alkenyl nitrile comprising at least one C—C double bond, which comprises the steps (a) reaction of the alkenyl nitrile with a corresponding monoamine in a first reactor so that the monoamine adds exothermically onto the at least one double bond to form an aminoalkyl nitrile, with the monoamine and water being charged initially and the alkenyl nitrile being fed in; (b) evaporation of unreacted alkenyl nitrile and monoamine to increase the concentration of the aminoalkyl nitrile product in the bottoms of the first reactor; (c) transfer of the aminoalkyl nitrile bottom product from step (b) to a second reactor; (d) batchwise catalytic hydrogenation of the aminoalkyl nitrile transferred in step (c) to the diamine in the second reactor, with each batch being obtained by initially charging a catalyst suitable for the hydrogenation of nitriles to amines and also water, the desired diamine and a base, introducing hydrogen into the second reactor and feeding in the aminoalkyl nitrile transferred in step (c); and (e) isolation of the diamine and, if appropriate, repetition of the steps (a) to (e). The invention further relates to an apparatus for preparing these diamines and the use of the apparatuses. A preferred diamine is 3-dimethylaminopropylamine (DMAPA).

    摘要翻译： 本发明涉及从包含至少一个C-C双键的相应链烯基腈开始工业制备二胺的方法，其包括步骤（a）在第一反应器中烯基腈与相应的单胺反应 使得单胺在至少一个双键上放热添加以形成氨基烷基腈，最初加入单胺和水，并加入链烯基腈; （b）蒸发未反应的烯基腈和单胺以增加第一反应器底部氨基烷基腈产物的浓度; （c）将氨基烷基腈底部产物从步骤（b）转移至第二反应器; （d）将步骤（c）中转移的氨基烷基腈分批催化氢化为第二反应器中的二胺，每个批次通过首先将适合于将腈氢化成的催化剂加入到胺中而得到，并且还需要水，所需的二胺和 碱，将氢气引入第二反应器并进料步骤（c）中转移的氨基烷基腈; 和（e）分离二胺，如果合适，重复步骤（a）至（e）。 本发明还涉及一种用于制备这些二胺的装置和该装置的用途。 优选的二胺是3-二甲基氨基丙胺（DMAPA）。