Utilization of Ferric Ammonium Citrate for In Situ Remediation of Chlorinated Solvents
    62.
    发明申请
    Utilization of Ferric Ammonium Citrate for In Situ Remediation of Chlorinated Solvents 失效
    柠檬酸铁铵用于氯化溶剂的原位修复

    公开(公告)号:US20140030797A1

    公开(公告)日:2014-01-30

    申请号:US13557937

    申请日:2012-07-25

    申请人: Michael Scalzi

    发明人: Michael Scalzi

    摘要: Accelerated dechlorination of soil and water contaminated with chlorinated solvents in situ is achieved by delivering ferric ammonium citrate into the soils and/or water. The induction of ferric ammonium citrate into sulfate-rich reducing conditions initiates a combined abiotic and biotic mechanism for the dechlorination of subsurface contaminants. Initial and rapid removal of chlorinated solvents is achieved by way of reductive transformation, a mechanism utilizing the creation of an iron-bound soil mineral (pyrite) followed by stimulating conditions for enhanced biological natural attenuation.

    摘要翻译: 通过将柠檬酸铁铵输送到土壤和/或水中来实现对原位氯化溶剂污染的土壤和水的加速脱氯。 将柠檬酸铁铵诱导成富含硫酸盐的还原条件引发了组合的非生物和生物机制,用于地下污染物的脱氯。 氯化溶剂的初始和快速除去是通过还原转化实现的,这种机制利用铁结合土壤矿物(黄铁矿)的产生,然后刺激条件以增强生物天然衰减。

    ANTISOLVENT PROCESS FOR TREATING LIQUIDS THAT INCLUDE HIGH TOTAL DISSOLVED SOLIDS
    63.
    发明申请
    ANTISOLVENT PROCESS FOR TREATING LIQUIDS THAT INCLUDE HIGH TOTAL DISSOLVED SOLIDS 有权
    用于处理包含高达全部溶解固体的液体的抗微生物工艺

    公开(公告)号:US20130140234A1

    公开(公告)日:2013-06-06

    申请号:US13706943

    申请日:2012-12-06

    申请人: Ronald N. Drake

    发明人: Ronald N. Drake

    IPC分类号: C02F1/52 C02F1/02

    摘要: The present invention provides a low energy alternative to conventional thermal/evaporation processes for “zero liquid discharge” treatment of strong saline brines. The products of the process include a salt-free liquid and solid salt. In particular, an antisolvent can be mixed with liquids containing high total dissolved solids. The mixture can be chilled, whereby solid salt is precipitated and separated from the mixture at near ambient temperature leaving a mixed liquor. The antisolvent can be selected from a class of organic compounds that form solutions with salt brines that exhibit a critical solution temperature lower than a critical solution temperature of the salt brines alone. The mixed liquor can be heated to a temperature above its lower critical solution temperature to produce an antisolvent liquid phase for recycle to the process. Finally, a reduced salinity aqueous phase can be polished by reverse osmosis or other conventional technology to produce clean water for discharge or beneficial use.

    摘要翻译: 本发明提供了用于对强盐水的“零液体排放”处理的常规热/蒸发方法的低能量替代。 该方法的产物包括无盐液体和固体盐。 特别地,抗溶剂可与含有高总溶解固体的液体混合。 混合物可以冷却,由此在接近环境温度下沉淀固体盐并从混合物中分离出混合液体。 抗溶剂可以选自一类有机化合物,其形成具有低于单独的盐盐水的临界溶解温度的临界溶解温度的盐盐溶液。 混合液可以加热到高于其临界溶解温度的温度以产生用于再循环到该方法的反溶剂液相。 最后,减少的盐度水相可以通过反渗透或其它常规技术抛光,以产生用于排放或有益用途的清洁水。

    Flocculant for separating and flocculating oil and water
    64.
    发明授权
    Flocculant for separating and flocculating oil and water 有权
    絮凝剂用于分离和絮凝油和水

    公开(公告)号:US07618540B2

    公开(公告)日:2009-11-17

    申请号:US12316616

    申请日:2008-12-15

    申请人: Kiyoharu Fujino

    发明人: Kiyoharu Fujino

    摘要: A flocculant for separating and flocculating oily components and water components is provided so that no sludge is produced when the oily components and the water components contained in the emulsion having a high COD value; and the throughput of the active sludge is not decreased in the secondary treatment of the active sludge. A flocculant for separating and flocculing oily components and water components contained in oil-in-water type or water-in-oil type emulsion, comprises a unit (i), and at least one of units (ii) and (iii) represented by the following formulas: (i) —(C(R1R2)C(R3X))—, (ii) —(C(R4R5)C(R6Y))—, (iii) —(C(R7R8)C(R9Z))—; wherein X is a group having —SO3M, M is hydrogen or a metal element, Y is a group having a quaternary nitrogen atom, Z is an electrophilic group, each R1 to R9 is hydrogen or an alkyl group, and a ratio per molecule of these units (i):(ii):(iii) is (1 to 100):(1 to 100):(1 to 100).

    摘要翻译: 提供了用于分离和絮凝油性组分和水组分的絮凝剂,使得当含有高COD值的乳液中的油性组分和水组分时,不会产生污泥; 在活性污泥的二次处理中活性污泥的生产量不降低。 包含在水包油型或油包水型乳液中的用于分离和絮凝油性成分和水成分的絮凝剂包括单元(i)和至少一种由(ⅰ)和(ⅲ)表示的单元 (ⅰ) - (C(R 1 R 2)C(R 3 X)) - ,(ⅱ) - (C(R 4 R 5)C(R 6 Y)) - ,(ⅲ) - (C(R 7 R 8) - ; 其中X是具有-SO 3 M,M是氢或金属元素的基团,Y是具有季氮原子的基团,Z是亲电子基团,每个R 1至R 9是氢或烷基,并且每分子的比例 这些单元(i):(ii):(iii)是(1〜100):(1〜100):( 1〜100)。

    Flocculant for separating and flocculating oil and water
    65.
    发明申请
    Flocculant for separating and flocculating oil and water 有权
    絮凝剂用于分离和絮凝油和水

    公开(公告)号:US20090105355A1

    公开(公告)日:2009-04-23

    申请号:US12316616

    申请日:2008-12-15

    申请人: Kiyoharu Fujino

    发明人: Kiyoharu Fujino

    IPC分类号: C08F230/04 B01D17/05

    摘要: A flocculant for separating and flocculating oily components and water components is provided so that no sludge is produced when the oily components and the water components contained in the emulsion having a high COD value; and the throughput of the active sludge is not decreased in the secondary treatment of the active sludge. A flocculant for separating and flocculating oily components and water components contained in oil-in-water type or water-in-oil type emulsion, comprises a unit (i), and at least one of units (ii) and (iii) represented by the following formulas: (i) —(C(R1R2)C(R3X))—, (ii) —(C(R4R5)C(R6Y))—, (iii) —(C(R7R8)C(R9Z))—; wherein X is a group having —SO3M, M is hydrogen or a metal element, Y is a group having a quaternary nitrogen atom, Z is an electrophilic group, each R1 to R9 is hydrogen or an alkyl group, and a ratio per molecule of these units (i):(ii):(iii) is (1 to 100):(1 to 100):(1 to 100).

    摘要翻译: 提供了用于分离和絮凝油性组分和水组分的絮凝剂,使得当含有高COD值的乳液中的油性组分和水组分时,不会产生污泥; 在活性污泥的二次处理中活性污泥的生产量不降低。 一种用于分离和絮凝油包水型或油包水型乳液中含有的油性组分和水组分的絮凝剂,包含单元(i)和至少一种由(ⅱ)和(ⅲ)表示的单元 (ⅰ) - (C(R 1 R 2)C(R 3 X)) - ,(ⅱ) - (C(R 4 R 5)C(R 6 Y)) - ,(ⅲ) - (C(R 7 R 8) - ; 其中X是具有-SO 3 M,M是氢或金属元素的基团,Y是具有季氮原子的基团,Z是亲电子基团,每个R 1至R 9是氢或烷基,并且每分子的比例 这些单元(i):(ii):(iii)是(1〜100):(1〜100):( 1〜100)。

    Novel biological floculants and production methods
    67.
    发明申请
    Novel biological floculants and production methods 审中-公开
    新型生物絮凝剂和生产方法

    公开(公告)号:US20040219651A1

    公开(公告)日:2004-11-04

    申请号:US10762429

    申请日:2004-01-21

    IPC分类号: C12P001/04 C12N001/20

    摘要: The present invention relates to a novel flocculant comprising bacteria of the Bacillus genus cultivated in a culture medium comprising soybean protein, glucose, molasses, and yeast. Alternatively, the flocculant comprises soybean protein. The present invention also relates to methods of making the flocculant, including fermentation method for mass production, and methods of using the flocculant in water treatment.

    摘要翻译: 本发明涉及包含在包含大豆蛋白,葡萄糖,糖蜜和酵母的培养基中培养的芽孢杆菌属细菌的新型絮凝剂。 或者,絮凝剂包括大豆蛋白。 本发明还涉及制备絮凝剂的方法,包括大规模生产的发酵方法,以及在水处理中使用絮凝剂的方法。

    Organic ammonium salts for the removal of water soluble organics in
produced water
    68.
    发明授权
    Organic ammonium salts for the removal of water soluble organics in produced water 失效
    有机铵盐,用于除去生产水中的水溶性有机物

    公开(公告)号:US6159379A

    公开(公告)日:2000-12-12

    申请号:US305235

    申请日:1999-05-04

    IPC分类号: C02F1/52 C02F1/58

    摘要: A method has been discovered for removing organics, such as water soluble organics (WSO), from fluids containing water, such as oil process water, by contacting the fluid with an effective amount of an organic ammonium salt. No added acid is necessary, although in some embodiments, weak acids such as glycolic acid, can be used to give synergistic improvement in organic removal. Suitable organic ammonium salts have the formula:R.sup.1 R.sup.2 R.sup.3 N.sup.+ H X.sup.-where R.sup.1 is a saturated or unsaturated alkyl group or an aryl group, or saturated or unsaturated alkyl group or an aryl group substituted with a heteroatom selected from the group consisting of N, O, S, P and halogen; R.sup.2, and R.sup.3 are independently H or a saturated or unsaturated alkyl group or an aryl group, or saturated or unsaturated alkyl group or an aryl group substituted with a heteroatom selected from the group consisting of N, O, S, P and halogen; and X is a halogen atom or an anion of a protic acid.

    摘要翻译: 已经发现通过使流体与有效量的有机铵盐接触,从含有水的流体例如油加工水中除去有机物如水溶性有机物(WSO)的方法。 不需要添加酸,尽管在一些实施方案中,弱酸例如乙醇酸可用于在有机物去除方面提供协同改进。 合适的有机铵盐具有下式:R 1 R 2 R 3 N + H X - 其中R 1是饱和或不饱和的烷基或芳基,或饱和或不饱和的烷基或被选自N,O ,S,P和卤素; R2和R3独立地为H或饱和或不饱和的烷基或芳基,或饱和或不饱和的烷基或被选自N,O,S,P和卤素的杂原子取代的芳基; X是卤素原子或质子酸的阴离子。

    Process for treating photographic processing waste solution
    69.
    发明授权
    Process for treating photographic processing waste solution 失效
    处理照相处理废液的方法

    公开(公告)号:US5795485A

    公开(公告)日:1998-08-18

    申请号:US399658

    申请日:1995-03-07

    摘要: A process for treating a photographic processing waste solution which comprises: placing a polymer precipitate in a lower portion of a tank having a U-shaped treating space which comprises (i) a first partition, (ii) a second partition and (iii) an interconnecting partition for interconnecting the first partition and the second partition in the lower portion of a tank; introducing into the first partition a photographic processing waste solution containing a processing solution having fixing ability which has processed a silver halide photographic material; treating the photographic processing waste solution in the U-shaped treating space in the presence of a polymer having S atom which can coordinate with a metal; and removing the metal in said photographic processing waste solution.

    摘要翻译: 一种用于处理照相处理废液的方法,包括:将聚合物沉淀物放置在具有U形处理空间的罐的下部,所述罐的形状包括(i)第一隔板,(ii)第二隔板和(iii) 互连分隔件,用于将第一分隔件和第二隔板互相连接在罐的下部; 将具有处理卤化银照相材料的具有定影能力的处理溶液的照相处理废溶液引入第一隔板中; 在具有可与金属配合的S原子的聚合物的存在下处理U形处理空间中的照相处理废液; 并去除所述照相处理废液中的金属。

    Calcium alginate gel partially deficient in calcium ions for use in
binding metal cations
    70.
    发明授权
    Calcium alginate gel partially deficient in calcium ions for use in binding metal cations 失效
    藻酸钙凝胶部分缺乏钙离子用于结合金属阳离子

    公开(公告)号:US5385741A

    公开(公告)日:1995-01-31

    申请号:US940856

    申请日:1992-10-23

    摘要: An ionically gellable material is gelled with a metal cation and the metal cation content of the gel is reduced to provide the gel with binding sites not occupied by the metal cation so the gel can be used to bind and remove metal cations from solution. In a preferred embodiment, a calcium alginate gel in the form of beads is prepared, the calcium ion content of the gel is reduced to between 0.01 mg/g and 1.5 mg/g of moist gel by contacting the gel with an aqueous solution of acid such as lactic or tartaric acid having a pH of 1 to 3.5. The gel can be produced containing a microorganism such as yeast used for fermentation so metal ions can be removed while fermenting with the microorganism. In the bottle fermentation of wine to produce champagne, the gel containing yeast is added to the wine in the bottle. During fermentation, calcium and potassium ions are bound by the gel to reduce the precipitation of calcium tartrate and/or potassium bitartrate. Other uses of the gel include binding metal ions which can be other than calcium ions to provide metal ions for regulating enzymic activity or for recognizing, binding or purifying organic materials such as proteins or amino acids.

    摘要翻译: PCT No.PCT / FR92 / 00171 Sec。 371日期:1992年10月23日 102(e)日期1992年10月23日PCT提交1992年2月25日PCT公布。 第WO92 / 14544号公报 日期为1992年9月3日。离子可凝胶材料用金属阳离子凝胶化并且凝胶的金属阳离子含量被还原,以使凝胶具有未被金属阳离子占据的结合位点,因此凝胶可用于结合和去除 溶液中的金属阳离子。 在优选的实施方案中,制备珠粒形式的藻酸钙凝胶,通过使凝胶与酸的水溶液接触将凝胶的钙离子含量降低至0.01mg / g至1.5mg / g的湿凝胶 例如pH为1〜3.5的乳酸或酒石酸。 可以制造含有用于发酵的微生物如酵母的凝胶,因此可以在用微生物发酵的同时除去金属离子。 在葡萄酒瓶发酵生产香槟时,将含有酵母的凝胶加入瓶中的葡萄酒中。 在发酵期间,钙和钾离子被凝胶结合以减少酒石酸钙和/或酒石酸钾的沉淀。 凝胶的其它用途包括结合金属离子,其可以是不是钙离子以提供用于调节酶活性的金属离子或用于识别,结合或纯化有机材料如蛋白质或氨基酸的结合金属离子。