摘要:
Novel composite pigments containing both organic and inorganic portions have been produced.These pigments consist of an inorganic binary titanium dioxide/aluminum hydrate component, in a percent quantity comprised between 70% and 95% by weight, the remaining organic component amounting to between 5% and 30% by weight, consisting of an organic dye selected from the group consisting of azoic and quinophtalonic compounds, containing in their structure at least one carboxylic and/or sulphonic, substantially salified, acid function.The pigments are obtained according to a co-precipitation process, under substantially alkaline controlled pH conditions, of the acid organic dye together with the aluminum hydroxide (hydrated aluminum), by acidification of a solution and/or an aqueous dispersion of the acid organic dye in sodium aluminate, in the presence of titanium dioxide, at from 40.degree. C. to about 80.degree. C., and by a subsequent lacquering by treatment with an aqueous solution of an alkaline-earth metal salt (Ca, Mg, Ba, Sr) or of a Mn, Zn salt.The above-mentioned pigments are insoluble in water and in common organic solvents. They possess, moreover, a good dyeing power, an excellent stability under heat, a good fastness to light, a good fastness to bases and acids, to migration in plastic materials and stability to over varnishing in the stove, etc. Lastly, they may be obtained with different degrees of covering power.Thus, the pigments find a preferential application in varnishing products, air-drying and stove-baked enamels, in the pigmentation of plastic materials, in inks and in the beprinting of fabrics, etc., by means of conventional applicational methods.
摘要:
A process for producing monoazo or disazo pigments, which process comprises:(a) adding to a solution of a diazonium and/or tetrazonium salt of an aromatic or heterocyclic amine a solution or suspension containing 0.1-50% by weight of the theoretically required total weight of one or more coupling components, and(b) using the product from step (a) as an additive in the production of a monoazo pigment, a disazo pigment or a mixture of monoazo and disazo pigments.Compared with products produced by conventional methods, the pigments produced in the manner described above have a greater coloring strength, improved transparency, improved flow properties, and a higher degree of dispersibility.
摘要:
Fibrous materials of any kind is finished with an organic compound having fiber-finishing properties and containing one or several groups of the formula ##STR1## in which X is sulfonyl or carbonyl and A represents hydrogen or one equivalent of a mono-, bi- or trivalent metal or an ammonium group, is applied onto the fibrous material in the form of an aqueous or organo-aqueous solution or dispersion, and the fibrous material thus treated is then subjected, if necessary, to a heat treatment for the fixation of this organic compound onto the fibrous material. Organic fiber-finishing compounds containing the above-mentioned group may be for example dyestuffs, optical brighteners or compounds increasing the crease resistance.
摘要:
A process for producing monoazo or disazo pigments, which process comprises:(a) adding to a solution of a diazonium and/or tetrazonium salt of an aromatic or heterocyclic amine a solution or suspension containing 0.1-50% by weight of the theoretically required total weight of one or more coupling components, and(b) using the product from step (a) as an additive in the production of a monoazo pigment, a disazo pigment or a mixture of monoazo and disazo pigments.Compared with products produced by conventional methods, the pigments produced in the manner described above have a greater coloring strength, improved transparency, improved flow properties, and a higher degree of dispersibility.
摘要:
Novel azo dye-providing compounds and photographic elements containing such compounds are described. The present compounds contain a carrier moiety which, as a function of oxidation under alkaline conditions, provides a substance having a mobility different than that of the starting compound.
摘要:
Dye formulations for dyeing and printing cellulose and cellulosic textile material which in addition to conventional components contain a dye of the general formula (I): ##STR1## in which D is the radical of a diazo component;R is hydrogen, C.sub.1 to C.sub.7 alkyl, phenyl or phenyl bearing methyl as a substituent;X is cyano, carbamoyl or substituted carbamoyl;R.sup.1 is hydrogen or an aliphatic, cycloaliphatic, araliphatic or aromatic radical;R.sup.2 is hydrogen or an aliphatic, cycloaliphatic or araliphatic radical;R.sup.3 and R.sup.4 independently of one another have the same meanings as R.sup.1 and R.sup.2 ; andR.sup.1 --n--r.sup.2 and R.sup.3 --N--R.sup.4 independently of one another are saturated heterocyclic radicals.
摘要:
In a cholesteric guest-host liquid crystal composition having a positive dielectric anisotropy and consisting of a nematic host component with a dye incorporated as a guest component therein and an optically active (cholesteric) component, the improvement consisting of a substantially stable and water insoluble azo dye guest component having a pleochroic ratio a.sub.1 /a.sub.2 of at least 6.5 and an absorption maximum in the range of from 350 to 700 nm, said azo dye being a compound of the formula (1)X -- A -- N .dbd. N -- B -- Y (I)wherein A is selected from the group consisting of 1,4-phenylene, 2-hydroxy-1,4-naphthylene and 2-hydroxy-8-amino-1,4-naphthylene; B is selected from the group consisting of 1,4-phenylene, 1,5-naphthylene and 5-substituted benzothiazo-(1,3)-2-yl; X is selected from the group consisting of nitro, nitrile, dimethylamino, di(hydroxyethyl)-amino, phenyl and straight chain C.sub.1 -C.sub.10 alkyl, and Y is a monovalent organic radical that does not promote water solubility in the dye molecule.
摘要:
A process for forming a dye image on a receiving element by diffusion transfer from a photosensitive element is disclosed wherein the exposed photosensitive element is processed with an alkaline solution in the presence of a particular dye developer having at least one azo radical.
摘要:
The invention relates to a process which comprises reacting a compound of formula I, ##STR1## in which A.sub.1 is a radical which does not compete with the activity of the ##STR2## OR A TAUTOMER THEREOF, WITH A COMPOUND OF FORMULA II,a.sub.2 -- ch.sub.2 -- cn iiin which A.sub.2 is a radical which does not compete with the activity of the --CH.sub.2 CN group of the compound of formula II but provides the vicinal methylene group with sufficient acidity to react with the .dbd.NH group of the compound of formula I,and with sulphur,To obtain a compound of formula III, ##STR3## in which A.sub.1 and A.sub.2 are as defined above, which compounds of formula III are useful as intermediates for the production of dyestuffs.
摘要:
A hair dye preparation contains diamino-nitrobenzene compounds as a direct hair dye or contains diamino-nitrobenzene compounds as coupling components in combination with developing components for oxidation dyestuffs. A process for dyeing human hair comprises applying one of these preparations to the hair.