PROCESS, METHOD, AND SYSTEM FOR REMOVING HEAVY METALS FROM FLUIDS
    61.
    发明申请
    PROCESS, METHOD, AND SYSTEM FOR REMOVING HEAVY METALS FROM FLUIDS 有权
    从流体中去除重金属的过程,方法和系统

    公开(公告)号:US20120125816A1

    公开(公告)日:2012-05-24

    申请号:US12950060

    申请日:2010-11-19

    IPC分类号: C10G33/00

    摘要: Trace element levels of heavy metals in crude oil are reduced by contacting the crude oil with an oxidizing agent, extracting heavy metals into a water phase for subsequent separation from the crude oil. The oxidizing agent is selected from the group of hydroperoxides, organic peroxides, inorganic peracids and salts thereof, organic peracids and salts thereof, and ozone. In one embodiment, the oxidizing agent converts heavy metals into the heavy metal cations in a water-oil emulsion, which can be subsequently separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, at least a complexing agent can be added to facilitate the removal by forming soluble heavy metal complexes in the water phase.

    摘要翻译: 通过使原油与氧化剂接触,原油中重金属的微量元素含量降低,将重金属萃取到水相中,随后与原油分离。 氧化剂选自氢过氧化物,有机过氧化物,无机过酸及其盐,有机过酸及其盐和臭氧。 在一个实施方案中,氧化剂将重金属转化为水 - 油乳液中的重金属阳离子,水乳液可以随后与原油分离,用于具有降低的重金属含量的处理过的原油。 在一个实施方案中,可以加入至少一种络合剂以通过在水相中形成可溶性重金属络合物来促进去除。

    Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides
    64.
    发明申请
    Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides 有权
    从碱金属硫化物和多硫化物中回收碱金属和硫的方法

    公开(公告)号:US20090134040A1

    公开(公告)日:2009-05-28

    申请号:US12277822

    申请日:2008-11-25

    IPC分类号: C25C1/00 C25B1/00 C25C7/00

    摘要: Alkali metals and sulfur may be recovered from alkali polysulfides in an electrolytic process that utilizes an electrolytic cell having an alkali ion conductive membrane. An anolyte solution includes an alkali polysulfide and a solvent that dissolves elemental sulfur. A catholyte solution includes alkali metal ions and a catholyte solvent. Applying an electric current oxidizes sulfur in the anolyte compartment, causes alkali metal ions to pass through the alkali ion conductive membrane to the catholyte compartment, and reduces the alkali metal ions in the catholyte compartment. Sulfur is recovered by removing and cooling a portion of the anolyte solution to precipitate solid phase sulfur. Operating the cell at low temperature causes elemental alkali metal to plate onto the cathode. The cathode may be removed to recover the alkali metal in batch mode or configured as a flexible band to continuously loop outside the catholyte compartment to remove the alkali metal.

    摘要翻译: 碱金属和硫可以在利用具有碱离子传导膜的电解池的电解方法中从碱性多硫化物中回收。 阳极电解液包括碱性多硫化物和溶解元素硫的溶剂。 阴极电解液包括碱金属离子和阴极电解质溶剂。 施加电流在阳极电解液室中氧化硫,导致碱金属离子通过碱金属离子导电膜到阴极电解液室,并减少阴极电解液室中的碱金属离子。 通过除去和冷却一部分阳极电解液以沉淀固相硫来回收硫。 在低温下操作电池会​​使元素碱金属镀在阴极上。 可以除去阴极以分批模式回收碱金属或者配置为柔性带,以连续地环绕阴极电解液室外部以除去碱金属。

    In transit desulfurization of widely available fuels
    65.
    发明授权
    In transit desulfurization of widely available fuels 有权
    广泛使用的燃料在运输过程中脱硫

    公开(公告)号:US07523724B2

    公开(公告)日:2009-04-28

    申请号:US11733718

    申请日:2007-04-10

    IPC分类号: F02B43/00 F02B63/00

    摘要: A method of and system for reducing engine environmental atmospheric pollution emissions from a vehicle having a combustion engine utilizing hydrocarbon fuel for at least one of propulsion and auxiliary electrical power is disclosed. The method basically includes providing an unprocessed bulk fuel storage container and a clean processed fuel tank on the vehicle, supplying the engine for propulsion with fuel from the unprocessed fuel storage container when the vehicle is beyond a predetermined distance from an area having environmental restrictions passing a portion of unprocessed fuel through a desulphurization process to fill a clean fuel storage container while the vehicle is in motion and supplying the combustion engine for one of propulsion and auxiliary electrical power from clean fuel in the processed fuel storage container when the vehicle is within an area having environmental restrictions.

    摘要翻译: 公开了一种用于减少来自具有利用烃燃料的内燃机的车辆的发动机环境大气污染排放的方法和系统,所述燃料发动机用于推进和辅助电力中的至少一个。 该方法基本上包括在车辆上提供未经处理的大容量燃料储存容器和清洁处理的燃料箱,当车辆距离具有环境限制的区域超过预定距离时,向来自未加工的燃料储存容器的燃料供应用于推进的发动机 未处理的燃料的一部分通过脱硫过程在车辆运动时填充清洁的燃料存储容器,并且当车辆在区域内时,从处理的燃料存储容器中的清洁燃料提供用于推进和辅助电力中的一种的内燃机 有环境限制。

    CO-HYDROPROCESSING OF FISCHER-TROPSCH PRODUCTS AND CRUDE OIL FRACTIONS
    66.
    发明申请
    CO-HYDROPROCESSING OF FISCHER-TROPSCH PRODUCTS AND CRUDE OIL FRACTIONS 有权
    FISCHER-TROPSCH产品和原油分离器的CO-HYDROPROCESSING

    公开(公告)号:US20020169220A1

    公开(公告)日:2002-11-14

    申请号:US09854201

    申请日:2001-05-11

    IPC分类号: C07C027/06

    摘要: An integrated process for producing a hydrocarbon stream, preferably including predominantly C5-20 normal and iso-paraffins, is disclosed. The process involves isolating a C4null stream and, optionally a C5null stream (nullnatural gas condensatenull) from a natural gas source. The C4null stream is converted to syngas, and the syngas used in a hydrocarbon synthesis process, for example, Fischer-Tropsch synthesis. In one embodiment, one or more fractions from the hydrocarbon synthesis are blended with one or more crude oil derived fractions, and, optionally, the natural gas condensate, such that the overall sulfur content of the blend is less than about 200 ppm. If necessary, the crude oil fractions and/or natural gas condensate can be treated to lower the sulfur content so that the blend has an acceptable sulfur level. The fraction from the hydrocarbon synthesis may include, for example, C5-20 hydrocarbons, C20null hydrocarbons, or C5null hydrocarbons. In this embodiment, the hydroprocessing catalysts are noble metal-containing catalysts, which tend to be sensitive to sulfur concentrations above about 200 ppm. The catalysts preferably have high selectivity for C5null products, such that a significant C4null fraction is not formed. In another embodiment, one or more fractions from the hydrocarbon synthesis are blended with one or more crude oil derived fractions, and, optionally, the natural gas condensate, such that the overall sulfur content of the blend is more than about 200 ppm. The fraction from the hydrocarbon synthesis may include, for example, C5-20 hydrocarbons, C20null hydrocarbons, or C5null hydrocarbons. In this embodiment, conventional sulfur-tolerant hydroprocessing catalysts can be used.

    摘要翻译: 公开了一种生产烃流的综合方法,优选主要包括C5-20正链烷烃和异链烷烃。 该方法包括从天然气源分离C4-流和任选的C5 +流(“天然气冷凝物”)。 C4-烃转化为合成气,合成气用于烃合成过程,例如费 - 托合成。 在一个实施方案中,来自烃合成的一种或多种馏分与一种或多种原油衍生馏分和任选的天然气冷凝物共混,使得共混物的总硫含量小于约200ppm。 如果需要,可以处理原油馏分和/或天然气冷凝物以降低硫含量,使得共混物具有可接受的硫含量。 来自烃合成的馏分可以包括例如C5-20烃,C20 +烃或C5 +烃。 在该实施方案中,加氢处理催化剂是含贵金属的催化剂,其倾向于对高于约200ppm的硫浓度敏感。 催化剂优选对C5 +产物具有高选择性,使得不形成显着的C4-馏分。 在另一个实施方案中,来自烃合成的一种或多种馏分与一种或多种原油衍生馏分和任选的天然气冷凝物共混,使得共混物的总硫含量大于约200ppm。 来自烃合成的馏分可以包括例如C5-20烃,C20 +烃或C5 +烃。 在该实施方案中,可以使用常规的耐硫加氢催化剂。

    Process for removal of organo-sulfur compounds from liquid hydrocarbons
    67.
    发明授权
    Process for removal of organo-sulfur compounds from liquid hydrocarbons 失效
    从液态烃中除去有机硫化合物的方法

    公开(公告)号:US5723039A

    公开(公告)日:1998-03-03

    申请号:US630758

    申请日:1996-04-11

    IPC分类号: C10G17/00 C10G27/00 C01G17/00

    CPC分类号: C10G27/00 C10G17/00

    摘要: A process for purifying a liquid hydrocarbon feedstock containing organo-sulfur compounds wherein an aqueous sulfuric acid solution containing ions of a transition metal, such as vanadium, chromium, manganese, cobalt, cerium or mixtures thereof, is subject to electrolysis to oxidize the metal ions to a higher oxidation state, the electrolyzed solution is emulsified with the feedstock to achieve oxidation of the organo-sulfur compounds to form water soluble sulfur compounds, gaseous products, resinous products; the spent aqueous acidic solution and the purified hydrocarbon product are separated and the spent aqueous solution is recycled via electrolysis.

    摘要翻译: 一种净化含有机硫化合物的液态烃原料的方法,其中含有过渡金属离子如钒,铬,锰,钴,铈或其混合物的硫酸水溶液经受电解以氧化金属离子 到较高的氧化态,电解溶液与原料乳化,实现有机硫化合物的氧化,形成水溶性硫化合物,气态产物,树脂产品; 分离废水中的酸性水溶液和纯化的烃产物,并通过电解再循环废水溶液。

    Process for converting acid sludge to asphalt
    68.
    发明授权
    Process for converting acid sludge to asphalt 失效
    将酸性污泥转化为沥青的方法

    公开(公告)号:US5573656A

    公开(公告)日:1996-11-12

    申请号:US198189

    申请日:1994-02-16

    申请人: Benjamin Santos

    发明人: Benjamin Santos

    摘要: A process for significantly decreasing the acid sludge settling time in waste oil recovery processes comprising the steps of heating used oil to a high temperature above 725 degrees Fahrenheit, cooling the heated oil, adding an oxidizing agent to the oil, allowing the acid sludge to settle within a period of approximately 24 to 72 hours, separating the acid-sludge-free oil from the acid sludge which settles out of solution as a result of addition of the oxidizing agent, and adding a polishing agent and separating the re-refined oil from the spent polishing agent. The spent polishing agent is recycled, and the acid sludge which settles out after oxidation is converted to either hard, oxidized asphalt or soft asphalt or asphalt products such as emulsions etc. The process produces a high quality re-refined oil rapidly and economically with no acid sludge disposal problem.

    摘要翻译: 一种在废油回收方法中显着降低酸性污泥沉淀时间的方法,包括将用过的油加热至高于725华氏度的高温,冷却加热的油,向油中加入氧化剂,使酸性污泥沉降 在大约24至72小时的时间内,从添加了氧化剂的结果中分离出沉淀在溶液中的酸性污泥的油,并加入抛光剂并将再精制的油从 抛光剂。 废抛光剂被循环使用,氧化后沉降的酸性污泥转化为硬质,氧化沥青或软沥青或沥青产品如乳液等。该方法快速,经济地生产高品质的再精炼油,无 酸性污泥处理问题。