LONG-FIBER-REINFORCED RESIN COMPOSITION AND MOLDED ARTICLE THEREOF
    71.
    发明申请
    LONG-FIBER-REINFORCED RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 有权
    长纤维增强树脂组合物及其成型品

    公开(公告)号:US20110040022A1

    公开(公告)日:2011-02-17

    申请号:US12922348

    申请日:2009-03-19

    IPC分类号: C08L33/00

    摘要: A long-fiber-reinforced resin composition including the following component (A) and the component (B), the content of the component (A) being 50 to 90 wt % and the content of the component (B) being 10 to 50 wt %; and the content of reinforcing fiber contained in the component (A) being 20 to 60 wt % relative to the total amount of the fiber-reinforced resin composition:[Component (A)] a long-fiber-reinforced thermoplastic resin pellet including a thermoplastic resin, a modified polyolefin-based resin modified with an unsaturated carboxylic acid or its derivative and reinforcing fiber and satisfying the following (A-1) to (A-4): (A-1): the melt index of the thermoplastic resin (resin temperature: 230° C., load: 21.18N) is 100 to 250 g/10 min; (A-2): the relaxation time λ of the thermoplastic resin at an angular frequency ω=1 (rad/sec) calculated from the storage modulus G′ and the loss modulus G″ measured by means of a cone-and-plate rheometer is 0.1 (sec) or less; (A-3) the content of the reinforcing fiber is 40 to 70 wt %; and (A-4) the content of the modified polyolefin-based resin is 1 to 5 wt %; [Component (B)] a polyolefin-based resin satisfying the following (B-1) and (B-2): (B-1) the melt index of the polyolefin-based resin (resin temperature: 230° C., load: 21.18N) is 20 to 70 g/10 min; and (B-2) the relaxation time λ of the polyolefin-based resin at an angular frequency ω=1 (rad/sec) calculated from the storage modulus G′ and the loss modulus G″ measured by means of a cone-and-plate rheometer is 0.23 (sec) or less.

    摘要翻译: 包含以下组分(A)和组分(B)的长纤维增强树脂组合物,组分(A)的含量为50至90重量%,组分(B)的含量为10至50重量% %; 组分(A)中所含的增强纤维的含量相对于纤维增强树脂组合物的总量为20〜60重量%:[组分(A)]包含热塑性塑料的长纤维增强热塑性树脂颗粒 树脂,不饱和羧酸或其衍生物改性的改性聚烯烃系树脂及增强纤维,满足以下(A-1)〜(A-4):(A-1):热塑性树脂的熔融指数 树脂温度:230℃,负荷21.18N)为100〜250g / 10分钟; (A-2):以通过锥板流变仪测量的储能模量G'和损耗模量G“计算的角频率ω= 1(rad / sec)的热塑性树脂的弛豫时间λ 为0.1(秒)以下; (A-3)增强纤维的含量为40〜70重量%。 和(A-4)中,改性聚烯烃系树脂的含量为1〜5重量% [组分(B)]满足以下(B-1)和(B-2)的聚烯烃类树脂(B-1)聚烯烃系树脂的熔融指数(树脂温度:230℃,负荷 :21.18N)为20〜70g / 10min; 和(B-2)以从储能模量G'和损耗模量G“计算的角频率ω= 1(rad / sec)的聚烯烃类树脂的松弛时间λ, 板流变仪为0.23(秒)以下。

    Multilayered stretched hollow material
    73.
    发明申请
    Multilayered stretched hollow material 审中-公开
    多层拉伸中空材料

    公开(公告)号:US20090269528A1

    公开(公告)日:2009-10-29

    申请号:US12310671

    申请日:2007-09-04

    IPC分类号: B32B27/08

    摘要: The object of the present invention is to provide a multilayered stretched hollow material having excellent transparency and gas barrier properties. The multilayered stretched hollow material of the present invention is characterized in that it includes surface layers and an intermediate layer wherein the surface layers each contain a propylene polymer composition containing a propylene polymer (the weight thereof being A) and a modified propylene polymer grafted with an unsaturated carboxylic acid or a derivative thereof (the weight thereof being B) in a weight ratio of B/(A+B)≧0.15 and wherein the intermediate layer contains a modified ethylene/vinyl compound copolymer that has a melt flow rate (ASTM D 1238, 210° C., 2.16 kg load) of not less than 8 g/10 min and a crystallization temperature (Tc) of not less than 138° C. and further wherein the multilayered stretched hollow material satisfies C/(A+B+C)≧0.05 wherein C is the weight of the ethylene/vinyl compound copolymer.

    摘要翻译: 本发明的目的是提供具有优异透明性和阻气性的多层拉伸中空材料。 本发明的多层拉伸中空材料的特征在于它包括表面层和中间层,其中表面层各自含有丙烯聚合物组合物,其含有丙烯聚合物(其重量为A)和改性丙烯聚合物,其接枝有 不饱和羧酸或其衍生物(其重量为B)的重量比为B /(A + B)> = 0.15,其中中间层含有具有熔体流动速率的改性乙烯/乙烯基化合物共聚物(ASTM D1238,210℃,2.16kg负荷)不低于8g / 10min,结晶温度(Tc)不低于138℃,其中多层拉伸中空材料满足C /(A + B + C)> = 0.05,其中C是乙烯/乙烯基化合物共聚物的重量。

    Propylene Random Block Copolymer, Resin Composition Containing the Copolymer and Molded Article Made Thereof
    75.
    发明申请
    Propylene Random Block Copolymer, Resin Composition Containing the Copolymer and Molded Article Made Thereof 审中-公开
    丙烯无规嵌段共聚物,含有共聚物的树脂组合物及其制成的模制品

    公开(公告)号:US20090069523A1

    公开(公告)日:2009-03-12

    申请号:US12225689

    申请日:2007-03-27

    IPC分类号: C08F210/00

    摘要: The invention provides a propylene random block copolymer (A) that has a melt flow rate from 0.1 to 100 g/10 min and a melting point from 100 to 155° C. and includes 90 to 60% by weight of a portion insoluble (Dinsol) in n-decane at room temperature and 10 to 40% by weight of a portion soluble (Dsol) in n-decane at room temperature, wherein the Dinsol satisfies the following requirements (1) through (3) and the Dsol satisfies the following requirements (4) through (6). The invention further provides molded articles such as sheets, films, injection molded articles, hollow molded articles, injection blow molded articles and fibers, which are formed of the propylene random block copolymer (A) or a propylene resin composition containing the propylene random block copolymer (A). (1) The molecular weight distribution (Mw/Mn) obtained by GPC of the Dinsol is from 1.0 to 3.5, (2) the content of skeletons derived from ethylene in the Dinsol is from 0.5 to 13% by mole, (3) the total amount of 2,1- and 1,3-propylene units in the Dinsol is 0.2% by mole or less, (4) the molecular weight distribution (Mw/Mn) obtained by GPC of the Dsol is from 1.0 to 3.5, (5) the intrinsic viscosity [η] in decalin at 135° C. of the Dsol is from 1.5 to 4 dl/g and (6) the content of skeletons derived from ethylene in the Dsol is from 15 to 35% by mole.

    摘要翻译: 本发明提供一种丙烯无规嵌段共聚物(A),其熔体流动速率为0.1-100g / 10min,熔点为100-155℃,包括90-60wt%的不溶物(Dinsol )和室温下正癸烷中可溶解部分(Dsol)的10〜40重量%,其中,D insol为(1)〜(3),Dsol满足下述式 要求(4)至(6)。 本发明还提供了由丙烯无规嵌段共聚物(A)形成的成型制品,例如片材,薄膜,注塑制品,中空成型制品,注塑吹塑制品和纤维,或含丙烯无规嵌段共聚物 (一个)。 (1)由Dinsol得到的分子量分布(Mw / Mn)为1.0〜3.5,(2)由Dinsol得到的乙烯的骨架含量为0.5〜13摩尔%,(3) D insol中的2,1-和1,3-丙烯单元的总量为0.2摩尔%以下,(4)通过Dsol的GPC得到的分子量分布(Mw / Mn)为1.0〜3.5( 5)Dsol的135℃萘烷中的特性粘度η为1.5〜4dl / g,(6)Dsol中衍生自乙烯的骨架含量为15〜35摩尔%。

    PROPYLENE POLYMER COMPOSITION AND SHAPED ARTICLE

    公开(公告)号:US20220380585A1

    公开(公告)日:2022-12-01

    申请号:US17632467

    申请日:2020-08-07

    摘要: A propylene polymer composition includes a propylene homopolymer (A) having an intrinsic viscosity [η] measured in a tetralin solvent at 135° C. in the range of 7 to 12 dl/g, a propylene polymer (B) having an intrinsic viscosity [η] in the range of not less than 0.21 dl/g and less than 0.54 dl/g, and having a proportion of a component eluted at a temperature of not more than −20° C. in TREF in the range of not more than 3.5 mass %, and a propylene polymer (C) having an intrinsic viscosity [η] in the range of not less than 0.54 dl/g and less than 2.6 dl/g, wherein the content of (A) is 0.5 to 47.5 mass %, the content of (B) is 5 to 95 mass % and the content of (C) is 2.5 to 85.5 mass %, based on the total of (A), (B) and (C).

    POLYPROPYLENE RESIN COMPOSITION AND MOLDED ARTICLE COMPRISING THE SAME

    公开(公告)号:US20220289956A1

    公开(公告)日:2022-09-15

    申请号:US17638530

    申请日:2020-09-10

    IPC分类号: C08L23/12 C08L23/16 C08J9/10

    摘要: A polypropylene resin composition including components (A) to (D) in prescribed amounts, limiting the amount of a polypropylene component having a molecular weight of 106.5 or more to less than 0.05 wt % can provide a propylene resin composition that includes an impact polypropylene and a high flow homopolypropylene and is particularly preferable for foam molding, and a molded article comprising the composition (A) Impact polypropylene that includes 5 wt % or more and 20 wt % or less of a propylene-ethylene copolymer having an intrinsic viscosity [η] of 1.5 dl/g or more and 3.8 dl/g or less and having an MFR (230° C., 2.16 kg) of 30 g/10 min to 200 g/10 min, (B) high flow homopolypropylene having MFR (230° C., 2.16 kg) of 200 g/10 min to 1000 g/10 min, (C) ethylene elastomer having an MFR (190° C., 2.16 kg) of 0.5 g/10 min to 40 g/10 min, and (D) inorganic filler.

    Polypropylene-based resin composition and molded article

    公开(公告)号:US11359082B2

    公开(公告)日:2022-06-14

    申请号:US16486796

    申请日:2018-02-22

    摘要: Disclosed are: a polypropylene-based resin composition comprising 100 parts by mass of polypropylene-based resin (A) (provided that, when the polypropylene-based resin includes other resins and/or inorganic filler, the total amount of the polypropylene-based resin and other resins and/or inorganic filler is taken as 100 parts by mass), 0.80 to 5.0 parts by mass of on or more types of aluminum flakes (B) having an average particle size of 5 to 90 μm, and 0.005 to 0.06 parts by mass of carbon black (C); and a molded article obtained by injection-molding this polypropylene-based resin composition. The polypropylene-based resin composition and the molded article obtained from this are excellent in a flip-flop metallic feeling, a heavy luxury feeling, light resistance and a feeling of luminance.