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    Modified support materials for catalysts
    71.
    发明授权
    Modified support materials for catalysts 失效
    用于催化剂的改性载体材料

    公开(公告)号：US07518014B2

    公开(公告)日：2009-04-14

    申请号：US11285436

    申请日：2005-11-21

    申请人： Barbara Kimmich ,  Leslie E. Wade ,  Tao Wang ,  André Harmen Sijpkes ,  Roelandus Hendrikus Wilhelmus Moonen

    发明人： Barbara Kimmich ,  Leslie E. Wade ,  Tao Wang ,  André Harmen Sijpkes ,  Roelandus Hendrikus Wilhelmus Moonen

    IPC分类号： C07C67/00

    CPC分类号： B01J23/682 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J23/63 ,  B01J23/648 ,  B01J37/0207 ,  B01J37/16 ,  B01J2219/00745 ,  B01J2219/00747 ,  C07C67/055 ,  C40B30/08 ,  C40B40/18 ,  C07C69/01 ,  C07C69/15 ,  C07C69/24

    摘要： The present invention relates to a method of producing a catalyst or pre-catalyst suitable for assisting in the production of alkenyl alkanoates. The method includes contacting a modifier precursor to a support material to form a modified support material. One or more catalytic component precursors (palladium or gold) may be contacted to the modified support material. The atomic ratio of gold to palladium is preferably in the range of about 0.3 to about 0.90. The support materials with the catalytic component may then be reduced using a reducing environment. A composition for catalyzing the production of an alkenyl alkanoates including a modified support material with palladium and gold is also included within the invention. Catalysts of the present invention may be used to produce alkenyl alkanoates in general and vinyl acetate in particular and are useful to produce low EA/VA ratios while maintaining or improving CO2 selectivity.

    摘要翻译： 本发明涉及一种制备适于辅助生产链烷酸链烯酯的催化剂或预催化剂的方法。 该方法包括使改性剂前体与载体材料接触以形成改性的载体材料。 一种或多种催化组分前体（钯或金）可以与改性的载体材料接触。 金与钯的原子比优选在约0.3至约0.90的范围内。 然后可以使用还原环境来减少具有催化组分的载体材料。 用于催化生产含钯和金的改性载体材料的链烷酸酯的组合物也包括在本发明内。 本发明的催化剂通常可用于制备烯基链烷酸酯，特别是乙酸乙烯酯，并且可用于在保持或提高CO 2选择性的同时产生低的EA / VA比。

    Process for directly producing mixed linear alpha-alcohols having 1 to 18 carbon atoms from synthesis gas
    72.
    发明授权
    Process for directly producing mixed linear alpha-alcohols having 1 to 18 carbon atoms from synthesis gas 有权
    从合成气中直接生产具有1至18个碳原子的混合线型α-醇的方法

    公开(公告)号：US07468396B2

    公开(公告)日：2008-12-23

    申请号：US11890772

    申请日：2007-08-06

    申请人： Yunjie Ding ,  Hejun Zhu ,  Tao Wang ,  Guiping Jiao ,  Yuan Lv

    发明人： Yunjie Ding ,  Hejun Zhu ,  Tao Wang ,  Guiping Jiao ,  Yuan Lv

    IPC分类号： C07C27/00

    CPC分类号： C07C29/156 ,  C07C31/04 ,  C07C31/125

    摘要： The invention provide a process for producing directly mixed linear alpha-alcohols having 1 to 18 carbon atoms from synthesis gas comprising hydrogen and carbon monoxide, comprising the step of reacting hydrogen and carbon monoxide over a catalyst to produce mixed linear alpha-alcohols having 1 to 18 carbon atoms and hydrocarbons having 1 to 25 carbon atoms through Fischer-Tropsch process in one step in a reactor, wherein: the mole ratio of hydrogen to carbon monoxide is within the range of 1 to 3; the catalyst is an activated carbon supported cobalt based catalyst; the reactor is a fixed bed reactor, a slurry reactor or a fluid reactor; the reaction is carried out under specific conditions.

    摘要翻译： 本发明提供一种从包含氢气和一氧化碳的合成气生产具有1至18个碳原子的直接混合的直链α-醇的方法，包括在催化剂上使氢气和一氧化碳反应生成混合的线性α-醇，其具有1至 18个碳原子和碳原子数为1〜25的烃通过费 - 托法在一个反应​​器中进行，其中：氢与一氧化碳的摩尔比在1〜3的范围内; 催化剂是活性炭负载的钴基催化剂; 反应器是固定床反应器，淤浆反应器或流体反应器; 反应在特定条件下进行。

    PROCESS FOR DIRECTLY PRODUCING MIXED LINEAR ALPHA-ALCOHOLS HAVING 1 TO 18 CARBON ATOMS FROM SYNTHESIS GAS
    73.
    发明申请
    PROCESS FOR DIRECTLY PRODUCING MIXED LINEAR ALPHA-ALCOHOLS HAVING 1 TO 18 CARBON ATOMS FROM SYNTHESIS GAS 有权
    从合成气体直接生产具有1至18个碳原子的混合线性醇的方法

    公开(公告)号：US20080293835A1

    公开(公告)日：2008-11-27

    申请号：US11890772

    申请日：2007-08-06

    申请人： Yunjie Ding ,  Hejun Zhu ,  Tao Wang ,  Guiping Jiao ,  Yuan Lv

    发明人： Yunjie Ding ,  Hejun Zhu ,  Tao Wang ,  Guiping Jiao ,  Yuan Lv

    IPC分类号： C07C27/06

    CPC分类号： C07C29/156 ,  C07C31/04 ,  C07C31/125

    摘要： The invention provide a process for producing directly mixed linear alpha-alcohols having 1 to 18 carbon atoms from synthesis gas comprising hydrogen and carbon monoxide, comprising the step of reacting hydrogen and carbon monoxide over a catalyst to produce mixed linear alpha-alcohols having 1 to 18 carbon atoms and hydrocarbons having 1 to 25 carbon atoms through Fischer-Tropsch process in one step in a reactor, wherein: the mole ratio of hydrogen to carbon monoxide is within the range of 1 to 3; the catalyst is an activated carbon supported cobalt based catalyst; the reactor is a fixed bed reactor, a slurry reactor or a fluid reactor; the reaction is carried out under specific conditions.

    摘要翻译： 本发明提供一种从包含氢气和一氧化碳的合成气生产具有1至18个碳原子的直接混合的直链α-醇的方法，包括在催化剂上使氢气和一氧化碳反应生成混合的线性α-醇，其具有1至 18个碳原子和碳原子数为1〜25的烃通过费 - 托法在一个反应​​器中进行，其中：氢与一氧化碳的摩尔比在1〜3的范围内; 催化剂是活性炭负载的钴基催化剂; 反应器是固定床反应器，淤浆反应器或流体反应器; 反应在特定条件下进行。

    Mobile vehicle inspection system
    79.
    发明申请
    Mobile vehicle inspection system 有权
    移动车辆检查系统

    公开(公告)号：US20080089469A1

    公开(公告)日：2008-04-17

    申请号：US11974458

    申请日：2007-10-12

    申请人： Zhiqiang Chen ,  Kejun Kang ,  Haifeng Hu ,  Yuanjing Li ,  Hua Peng ,  Chuanxiang Tang ,  Shangmin Sun ,  Yinong Liu ,  Jianmin Li ,  Junli Li ,  Li Zhang ,  Yaohong Liu ,  Nan Jiang ,  Zhongrong Yang ,  Tao Wang

    发明人： Zhiqiang Chen ,  Kejun Kang ,  Haifeng Hu ,  Yuanjing Li ,  Hua Peng ,  Chuanxiang Tang ,  Shangmin Sun ,  Yinong Liu ,  Jianmin Li ,  Junli Li ,  Li Zhang ,  Yaohong Liu ,  Nan Jiang ,  Zhongrong Yang ,  Tao Wang

    IPC分类号： G01N23/00 ,  G21K1/00

    CPC分类号： G01V5/0016

    摘要： A mobile vehicle inspection system includes a moving device; a driving device for driving the moving device to move during scanning inspection; a radiation source disposed on the moving device for emitting a ray; a rotary table pivotally disposed on the moving device; an upright post installed on the rotary table at a lower end of the upright post; traverse detector beam having an end connected with an upper end of the upright post; the upright detector beam having an upper end connected with the other end of the traverse detector beam, and extending downwards from the other end of the traverse detector beam so that the upright post, the traverse detector beam and the upright detector beam constitute a frame of a substantial inverted “U” shape, a ray emitted from the radiation source so as to inspect a vehicle to be inspected which passes through the inverted-“U”-shaped frame.

    摘要翻译： 移动车辆检查系统包括移动装置; 用于在扫描检查期间驱动移动装置移动的驱动装置; 设置在所述移动装置上用于发射射线的辐射源; 枢转地设置在所述移动装置上的旋转台; 在立柱的下端安装在旋转台上的立柱; 横向检测器梁的一端与直立柱的上端连接; 直立检测器梁具有与横动检测器梁的另一端连接的上端，并且从横移检测器梁的另一端向下延伸，使得立柱，横移检测器梁和竖直检测器梁构成 大体上倒置的“U”形，从辐射源发出的射线，以检查通过倒置“U”形框架的被检查车辆。

    Synthesis of 3-(5-nitrocyclohex-1-enyl) acrylic acid and esters thereof
    80.
    发明申请
    Synthesis of 3-(5-nitrocyclohex-1-enyl) acrylic acid and esters thereof 失效
    3-（5-硝基环己-1-烯基）丙烯酸及其酯的合成

    公开(公告)号：US20080009651A1

    公开(公告)日：2008-01-10

    申请号：US11824246

    申请日：2007-06-29

    申请人： Tiruvettipuram Thiruvengadam ,  Tao Wang ,  John Chiu ,  Jing Liao

    发明人： Tiruvettipuram Thiruvengadam ,  Tao Wang ,  John Chiu ,  Jing Liao

    IPC分类号： C07C61/35 ,  C07C201/06

    CPC分类号： C07C251/44 ,  C07C201/06 ,  C07C249/08 ,  C07C2601/16 ,  C07C205/56 ,  C07C251/42

    摘要： This application discloses provides a process for the introduction of nitro-group functionality into a compound which contains also a site of unsaturation and/or oxygen functionality by direct (one step) oxidation of an oxime functional group mediated by a molybdenum VI/VII peroxo complex, the process comprising: (a) providing a substrate of Formula I containing an oxime functional group;  wherein R1 and R2 are selected independently from linear, branched or cyclic alkyl and linear, branched or cyclic alkenyl groups, optionally substituted, with the proviso that at least one of R1 or R2 contains a carbon/carbon double bond; and (b) contacting said substrate of Formula I with a molybdenum oxidation complex, thereby oxidizing said oxime functional group to a nitro functional group to yield the structure of Formula III. Where R1 and R2 are as defined above.

    摘要翻译： 本申请公开提供了一种通过由钼VI / VII过氧配合物介导的肟官能团的直接（一步）氧化将硝基官能团引入到还含有不饱和位和/或氧官能团位点的化合物的方法 该方法包括：（a）提供含有肟官能团的式I的底物; 其中R 1和R 2独立地选自直链，支链或环状的烷基和直链，支链或环状烯基，任选被取代，条件是至少一个 R 1或R 2 2含有碳/碳双键; 和（b）使式I的底物与钼氧化络合物接触，从而将所述肟官能团氧化为硝基官能团，得到式III的结构。 其中R 1和R 2如上定义。