Abstract:
A mesoporous mixed oxide catalyst that comprises silicon and at least one metal M that is selected from the group that consists of the elements of groups 4 and 5 of the periodic table and mixtures thereof, with the mass of metal M being between 0.1 and 20% of the mixed oxide mass.
Abstract:
The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise selectively catalytically reductive (SCR-active) mixed oxide consisting of cerium oxide, zirconium oxide, rare earth sesquioxide and niobium oxide and optionally tungsten oxide. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, mixed magnesium/aluminum oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
Abstract:
The present invention relates to a method of producing a catalyst or pre-catalyst suitable for assisting in the production of alkenyl alkanoates. The method includes contacting a modifier precursor to a support material to form a modified support material. One or more catalytic component precursors (palladium or gold) may be contacted to the modified support material. The atomic ratio of gold to palladium is preferably in the range of about 0.3 to about 0.90. The support materials with the catalytic component may then be reduced using a reducing environment. A composition for catalyzing the production of an alkenyl alkanoates including a modified support material with palladium and gold is also included within the invention. Catalysts of the present invention may be used to produce alkenyl alkanoates in general and vinyl acetate in particular and are useful to produce low EA/VA ratios while maintaining or improving CO2 selectivity.
Abstract:
A catalyst composition and its use for the selective oxidation of ethane to acetic acid and/or for the selective oxidation of ethylene to acetic acid. The composition includes in combination with oxygen the elements molybdenum, vanadium, niobium, gold in the absence of palladium according to the empirical formula MoaWbAucVdNbeZf, wherein Z is one or more elements selected from B, Al, Ga, In, Ge, Sn, Pb, Sb, Cu, Pt, Ag, Fe and Re, and a, b, c, d, e and f represent the gram atom ratios of the elements such that: 0
Abstract:
An exhaust gas system for an internal combustion engine includes a depth filter for removing soot from the exhaust gas. The depth filter includes a catalyst material, which promotes the oxidation of soot. An internal pore structure of the depth filter is provided with a catalyst material, which is liquid beyond a temperature of approximately no higher than 400° C. and more preferably no higher than approximately 350° C.
Abstract:
A multimetal oxide of the formula I Aga−bMbV2Ox*c H2O, I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04 , 3.09±0.04, 3.02±0.04 , 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.
Abstract translation:式I的多金属氧化物<?in-line-formula description =“In-line Formulas”end =“lead”?> Ag sub> B sub> > 2 i> i>在线公式描述=“在线公式”end =“tail”? 其中M是选自Li,Na,K,Rb,Cs,Tl,Mg,Ca,Sr,Ba,Cu,Zn,Cd,Pb,Cr,Au,Al,Fe,Co, Ni和/或Mo,a为0.3〜1.9,b为0〜0.5,条件是差(ab)≥0.1,c为0〜20,x为化合价和数量 具有式I中与氧不同的元素的结晶结构具有给出X射线粉末衍射图的晶体结构,其显示晶格间距d为15.23±0.6,12.16±0.4,10.68±0.3,3.41±0.04,3.09±0.04的反射 ,3.02±0.04,2.36±0.04和1.80±0.04。 还提供了预催化剂和由其制备的用于芳族烃的部分氧化的催化剂。
Abstract:
The present invention relates to a catalyst for removing aromatic halogenated compounds comprising dioxin, carbon monoxide and nitrogen oxide simultaneously and a method for preparing the catalyst, more particularly, a catalyst comprising 0.1 to 5% by weight of vanadium, 1 to 12% by weight of metals in 6A family and 0.1 to 10% by weight of Ag in titania carrier or, alternatively, a catalyst produced by impregnating said catalyst in 0.05 to 1M sulfuric acid solution to carry out acid treatment. The catalyst according to the present invention has improved efficiency for removing 1,2-dichlorobenzene as a reactant model of dioxin and carbon monoxide rather than existing catalysts and also, alternative efficiency for removing nitrogen oxide substantially equal to commonly known catalysts, so that the catalyst can effectively control various air pollutants contained in exhaust gas.
Abstract:
A device for the additive-free, catalytically induced oxidation of solid carbon particles and the decomposition of chemical compounds, which are generated by diesel engines and other combustion carbon particles. A device (100) for burning exhaust gas particles, comprising a converter chamber (50), in which at least one or a large number of porous structure catalyst carrier matrix profiles (120) are accommodated. The catalyst carrier matrix profiles are mounted in the converter chamber, wherein the converter chamber is provided with compartments, so that the space between the internal diameter of the catalyst profiles is connected to an inlet connection of the converter chamber, and the space around the external diameter of the catalyst profiles is connected to an outlet connection into the catalyst chamber. The profiles are mounted at the star-shaped gas passages and the compartments, so that gas particles can reach the outlet connection from the inlet connection only by passing through the walls of the structure of the porous profiles. To induce the activities of an additive-free catalytic oxidation at low exhaust gas temperatures, it may be advantageous to provide at least a third opening at the inlet of the device, through which liquid or gaseous media, e.g., NO2, O3 or H2O or auxiliary means are positioned in front of the porous structures. The porous structures are made of a catalytically active material in order to catalytically reduce the solid soot particles and chemical compounds in a exhaust gas stream, which pass through the device for burning exhaust gas particles, without additives or admixtures. The catalytically active material used is selected such that it has catalytic action at temperatures below 400null C., preferably below 350null C. and especially below 300null C. The low-temperature regeneration below 250null C. by the injection of H2O is preferred.
Abstract:
A photocatalytic functional film has a structure of a substrate, a barrier layer and a photocatalytic layer stacked one on another. The barrier layer is an amorphous TiO2 film, the photocatalyst layer comprises an amorphous TiO2 film, and particles of visible light responsive photocatalytic material formed on the surface of the amorphous TiO2 film. A method for producing a photocatalytic functional film includes: adding an alcohol solvent and an acid to a titanium precursor to obtain a TiO2 amorphous sol by dehydration and de-alcoholization reaction; applying and drying the TiO2 amorphous sol on a substrate to form a barrier layer; and applying and drying a composition formed by mixing particles of visible light responsive photocatalyst material with the TiO2 amorphous sol on the barrier layer, to form a photocatalyst layer.