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71.发明授权公开(公告)号：US07344635B2
公开(公告)日：2008-03-18
申请号：US10503807
申请日：2003-01-22
IPC分类号： C10G45/02
CPC分类号： C10G69/123 , C10G29/205
摘要： Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.
摘要翻译： 用于裂化或蒸汽裂解烃的流出物的脱硫方法，更具体地，例如用于催化裂解的汽油，其包括通过这些化合物的烷基化除去噻吩化合物，然后蒸馏，所述烷基 - 噻吩化合物的加氢裂化， 然后从加氢裂化区获得的流出物的加氢脱硫。 在优选的实施方案中，该方法包括用于将裂化或蒸汽裂解流出物分离成三个馏分的初步阶段，并且建议仅向最初存在于重质碱性含氮化合物中的低碱性含氮化合物的中间馏分 待烷基化的废水。
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公开(公告)号：US07235703B2
公开(公告)日：2007-06-26
申请号：US11107794
申请日：2005-04-18
CPC分类号： B01J31/04 , B01J29/06 , B01J31/143 , B01J31/2208 , B01J2231/20 , B01J2531/847 , C07C2/30 , C07C2531/04 , C07C2531/14
摘要： An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminium trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要翻译： 用于低聚，特别是二烯化的单烯烃的改进的催化组合物包括由以下三种组分以任何顺序接触而得到的产物：a）至少一种二价镍化合物; b）至少一种烃基二卤化物，任选地富含三卤化铝; 和c）至少一种有机布朗斯台德酸; 催化组合物在使用其进行低聚反应之前在溶剂中预调节。
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公开(公告)号：US07208440B2
公开(公告)日：2007-04-24
申请号：US10962569
申请日：2004-10-13
IPC分类号： B01J20/34 , B01J38/56 , C07C2/02 , C07C2/64 , C07C15/067
CPC分类号： C10G29/205 , B01J27/182 , B01J37/08 , C10G2400/30
摘要： The invention relates to a method for pretreatment of a solid catalyst that is obtained by a reaction between an inorganic binder and phosphoric acid, whereby said method comprises a stage in which said catalyst is brought into contact with a mixture of hydrocarbons under swelling conditions of the catalyst up to a predetermined volume increase, with no significant volume constraint on said catalyst. The invention also relates to an operating process of said catalyst in an alkylation or oligomerization reactor.
摘要翻译： 本发明涉及一种通过无机粘合剂和磷酸之间的反应获得的固体催化剂的预处理方法，其中所述方法包括在所述催化剂的溶胀条件下使所述催化剂与烃混合物接触的阶段 催化剂达到预定体积增加，对所述催化剂没有明显的体积限制。 本发明还涉及所述催化剂在烷基化或低聚反应器中的操作过程。
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74.发明授权Process for the valorization of a charge of hydrocarbons and for reducing the vapor pressure of said charge 有权用于使碳氢化合物加压并且用于降低所述电荷的蒸汽压力的方法公开(公告)号：US07161052B2
公开(公告)日：2007-01-09
申请号：US10653426
申请日：2003-09-03
CPC分类号： C10G29/205 , C10G50/00
摘要： A process is described for the valorization of a charge of hydrocarbons and for reducing the vapour pressure of said charge, comprising three steps: a step a) consisting of separating said charge of hydrocarbons into a fraction (O1) comprising essentially compounds containing 5 carbon atoms, including at least 2% by weight of pentenes, a step b) consisting of placing said fraction (O1) in contact with a cut of hydrocarbons (O2) at least partly comprising hydrocarbons having a number of carbon atoms between 6 and 10, including at least 2% by weight of olefins, and a step c) consisting of separating the effluents originating from step b) into a gasoline cut (α) the upper distillation point of which is less than 100° C. and a kerosene cut (β) having a distillation range between 100° C. and 300° C.
摘要翻译： 描述了一种用于增加烃类和降低所述电荷的蒸气压的方法，包括三个步骤：步骤a）由将所述烃分离成基本上含有5个碳原子的化合物的馏分（O1）组成的步骤 ，包括至少2重量％的戊烯，步骤b）将所述馏分（O1）与至少部分包含6至10个碳原子的烃的馏分（O 2）接触，包括 至少2重量％的烯烃，以及步骤c），其通过将来自步骤b）的流出物分离成上馏分小于100℃的汽油馏分（α）和煤油切割（β ），其蒸馏范围为100℃至300℃。
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公开(公告)号：US20050192471A1
公开(公告)日：2005-09-01
申请号：US11107794
申请日：2005-04-18
CPC分类号： B01J31/04 , B01J29/06 , B01J31/143 , B01J31/2208 , B01J2231/20 , B01J2531/847 , C07C2/30 , C07C2531/04 , C07C2531/14
摘要： An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminium trihalide; and c) at least one organic Bronsted acid; the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.
摘要翻译： 用于低聚，特别是二烯化的单烯烃的改进的催化组合物包括由以下三种组分以任何顺序接触而得到的产物：a）至少一种二价镍化合物; b）至少一种烃基二卤化物，任选地富含三卤化铝; 和c）至少一种有机布朗斯台德酸; 催化组合物在使用其进行低聚反应之前在溶剂中预调节。
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公开(公告)号：US06281402B1
公开(公告)日：2001-08-28
申请号：US09208585
申请日：1998-12-10
申请人： Vincent Coupard , François Hugues , Dominique Commereuc , Béatrice Fischer , Pierre Boucot , Alain Forestiere
发明人： Vincent Coupard , François Hugues , Dominique Commereuc , Béatrice Fischer , Pierre Boucot , Alain Forestiere
IPC分类号： C07C604
CPC分类号： C07C6/04 , C07C2521/04 , C07C2523/36 , Y02P20/584
摘要： The present invention relates to a process for continuous metathesis or disproportionation of olefins, comprising at least 2 phases, a reaction phase a) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst and a regeneration phase b) carried out in a zone comprising at least one reactor containing at least one fixed bed of catalyst, characterized in that at least one reactor passes from one phase to the other in alternation. In FIG. 1, the feed containing olefins traverses reactor R1 in riser mode. The feed to be treated containing olefins is introduced into reactor R1 via line 1a. In this reactor, the olefins contained in the feed undergo metathesis or disproportionation, then the effluent leaves the circuit via line 11. Simultaneously, reactor R2 is placed in catalyst regeneration phase, the different regeneration gases are introduced into reactor R2 via line 2b and leave this reactor via line 2c. Passage from the operating phase of a reactor to the catalyst regeneration phase thereof is carried out as follows: the reactor for which the catalyst is to be regenerated is isolated from the remainder of the apparatus, the hydrocarbons contained in the reactor are evacuated, then the reactor is purged. Said reactor is then connected to a regeneration loop and undergoes regeneration of its catalyst, and at the end of the regeneration phase, the reactor and the regeneration loop are purged.
摘要翻译： 本发明涉及一种烯烃的连续复分解或歧化方法，包括至少两相，在包含至少一个含有至少一个催化剂固定床和再生阶段的反应器的区域中进行的反应相a） 在包含至少一个包含至少一个催化剂固定床的反应器的区域中进行，其特征在于至少一个反应器交替地从一个相转移到另一个相。 在图 如图1所示，含有烯烃的进料以提升管方式穿过反应器R1。 待处理含烯烃的进料通过管线1a引入反应器R1。 在该反应器中，进料中所含的烯烃经过复分解或歧化，然后流出物通过管线11离开回路。同时，将反应器R2置于催化剂再生阶段，不同的再生气体通过管线2b引入反应器R2，并留下 该反应器经由管线2c。 从反应器的操作阶段到催化剂再生阶段的通过如下进行：将待再生催化剂的反应器与装置的其余部分分离，将反应器中包含的烃抽真空，然后 反应器被清除。 然后将所述反应器连接到再生回路并经历其催化剂的再生，并且在再生阶段结束时，将反应器和再生回路清除。
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公开(公告)号：US06235956B1
公开(公告)日：2001-05-22
申请号：US09217584
申请日：1998-12-22
IPC分类号： C07C232
CPC分类号： C07C43/303 , C07D307/12 , C07F7/003
摘要： An acetal, wherein the acetal is 2,2-di(tetrahydrofurfuryloxy)propane as well as processed for producing the acetal and methods of using the acetal.
摘要翻译： 缩醛，其中缩醛是2,2-二（四氢呋喃氧基）丙烷，以及用于制备缩醛的方法和使用缩醛的方法。
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公开(公告)号：US6149879A
公开(公告)日：2000-11-21
申请号：US22842
申请日：1998-02-12
IPC分类号： B01D3/00 , B01D3/14 , B01D3/20 , B01J8/00 , B01J8/02 , C07C41/06 , C07C41/42 , B01J10/00 , C07C41/05
CPC分类号： B01D3/008 , B01D3/009 , B01D3/14 , B01D3/20 , B01J8/008 , B01J8/025 , B01J8/0278 , C07C41/06 , C07C41/42 , B01J2208/00814 , B01J2208/00884 , Y02P20/127
摘要： The invention relates to a modular device that comprises a reaction zone that includes a catalyst bed and a zone for separation by distillation, as well as independent circulation channels for liquid fluid and gaseous fluid.
摘要翻译： 本发明涉及一种模块化装置，其包括反应区，其包括催化剂床和用于通过蒸馏分离的区，以及用于液体流体和气态流体的独立循环通道。
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79.发明授权Process for the separation of alpha-olefins by distillation of an effluent comprising ethylene and 1-butene 失效通过蒸馏出包含乙烯和1-丁烯的流出物来分离α-烯烃的方法
公开(公告)号：US5853551A
公开(公告)日：1998-12-29
申请号：US720384
申请日：1996-07-23
CPC分类号： C07C7/05
摘要： The invention concerns a process for the separation of a mixture comprising ethylene, 1-butene, alpha-olefins containing at least 6 carbon atoms per molecule and possibly heavier hydrocarbon products, the ethylene content of the mixture being in the range 30% to 70% by weight, in which separation is effected in a distillation zone to obtain an overhead fraction comprising the major portion of the ethylene present in the mixture and between 0% and 100% by weight of the 1-butene present in the mixture, the process being characterized in that the zone is also supplied with supplemental 1-butene in an amount in the range 1 to 40 times the quantity (by weight) of 1-butene present in the mixture. In a preferred implementation of the process of the invention, the mixture originates form a homogenous liquid phase ethylene oligomerisation zone.
摘要翻译： 本发明涉及一种分离包含乙烯，1-丁烯，每分子含有至少6个碳原子的α-烯烃和可能较重烃产物的混合物的混合物的方法，该混合物的乙烯含量在30％至70％的范围内， ，其中在蒸馏区中进行分离以获得包含混合物中存在的乙烯的主要部分和0重量％至100重量％的混合物中存在的1-丁烯的塔顶馏分，该方法为 其特征在于，该区域还提供了在混合物中存在的1-丁烯的量（重量）的1至40倍的量的补充的1-丁烯。 在本发明方法的优选实施方案中，混合物起始形成均相液相乙烯齐聚区。
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公开(公告)号：US5744681A
公开(公告)日：1998-04-28
申请号：US620456
申请日：1996-03-22
摘要： A process for the alkylation of at least one isoparaffin by at least one olefin in the presence of at least one solid acidic catalyst, characterized in that the major portion of the olefin is initially brought into contact with the catalyst in a complexing zone to form an olefin-catalyst complex in the presence of the isoparaffin, and in that the suspension of the complex in the isoparaffin is then sent to at least one alkylation reaction zone.
摘要翻译： 一种在至少一种固体酸性催化剂存在下由至少一种烯烃烷基化至少一种异链烷烃的方法，其特征在于，所述烯烃的主要部分最初在络合区域中与所述催化剂接触以形成 烯烃 - 催化剂络合物在异链烷烃的存在下进行，然后将异构烷烃中的络合物的悬浮液送至至少一个烷基化反应区。
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