Process for the preparation of urethanes
    73.
    发明授权
    Process for the preparation of urethanes 失效
    制备聚氨酯的方法

    公开(公告)号:US4594441A

    公开(公告)日:1986-06-10

    申请号:US610063

    申请日:1984-05-14

    CPC分类号: C07C271/06

    摘要: A process for the preparation of urethanes. Urethanes having the general formula R.sub.1 (NHCOOR.sub.2).sub.n are reacted with an alcohol at a temperature of 120.degree. to 400.degree. C. in amounts such that, for every mol of the urethane, at least one mol of the alcohol is present. R.sub.1 is a radical obtained by removing the isocyanate groups from an n-functional organic isocyanate, which isocyanate has a boiling point greater than 100.degree. C. at atmospheric pressure. R.sub.2 is a radical obtained by removing the hydroxyl group from a monohydric alcohol which has a boiling point greater than 140.degree. C. at atmospheric pressure.

    摘要翻译: 制备聚氨酯的方法。 具有通式R 1(NHCOOR 2)n的聚氨酯与醇在120-400℃的温度下反应,其量使得对于每一摩尔的氨基甲酸酯,存在至少一摩尔的醇。 R1是通过从大气压下异氰酸酯的沸点大于100℃的正官能的有机异氰酸酯除去异氰酸酯基得到的基团。 R2是在大气压下从沸点高于140℃的一元醇中除去羟基得到的基团。

    Pesticidal substituted 4-heterocyclyloximino-pyrazolin-5-ones,
compositions and use
    76.
    发明授权
    Pesticidal substituted 4-heterocyclyloximino-pyrazolin-5-ones, compositions and use 失效
    杀虫剂取代的4-杂环基肟基 - 吡唑啉-5-酮,组合物和用途

    公开(公告)号:US4968687A

    公开(公告)日:1990-11-06

    申请号:US403266

    申请日:1989-09-05

    CPC分类号: C07D403/12 A01N43/56

    摘要: Fungicidal substituted 4-heterocyclyloximinopyrazolin-5-ones of the formula ##STR1## in which R.sup.1 and R.sup.2 independently of one another in each case represent hydrogen, alkyl, alkenyl, alkinyl, cyanoalkyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl, alkoxycarbonyl, hydroxycarbonylalkyl, alkoxycarbonylalkyl, aminocarbonylalkyl, alkylaminocarbonylalkyl or dialkylaminocarbonylalkyl, or represent in each case unsubstituted or in each case substituted oxiranylalkyl, aralkyl, heterocyclyl or aryl andHet represents an unsubstituted or substituted heterocycle.

    摘要翻译: R 1和R 2各自独立地代表氢,烷基,烯基,炔基,氰基烷基,羟基烷基,烷氧基烷基,烷硫基烷基,烷氧基羰基,羟基羰基烷基的式(Ⅰ)的杀真菌剂取代的4-杂环基亚氨基吡唑啉-5-酮 ,烷氧基羰基烷基,氨基羰基烷基,烷基氨基羰基烷基或二烷基氨基羰基烷基,或在每种情况下表示未取代的或在每种情况下取​​代的环氧烷基烷基,芳烷基,杂环基或芳基,Het表示未取代或取代的杂环。

    Process for the production of microcellular moldings from diisocyanate
and compounds containing groups obtained by reacting amino groups with
carbon dioxide
    77.
    发明授权
    Process for the production of microcellular moldings from diisocyanate and compounds containing groups obtained by reacting amino groups with carbon dioxide 失效
    用于从二异氰酸酯生产微孔成型体的方法和含氨基与二氧化碳反应得到的化合物

    公开(公告)号:US4499038A

    公开(公告)日:1985-02-12

    申请号:US549040

    申请日:1983-11-07

    摘要: The present invention is directed to a process for the production of polyurea-based microcellular moldings comprising reacting(a) at least one diisocyanate or polyisocyanate containing only aromatically bound isocyanate groups,(b) at least one compound containing at least two isocyanate-reactive groups, and(c) optionally the auxiliaries and additives known in polyurethane chemistry, in closed molds, components (a)-(c) being processed as a one-shot system by reaction injection molding, characterized in that component (b) comprises at least one polyether compound (b1) optionally in admixture with other isocyanate-reactive compounds and containing at least 3 aliphatically bonded ether groups and n-aliphatically bonded isocyanate-reactive groups, n standing for an integer or, statistically a fraction of from 2-4(i) at least (100:n) % of the isocyanate-reactive groups present in component (b1) being aliphatically bonded primary and/or secondary amino groups,(ii) at least 10 equivalent % of said amino groups being present in the form of ammonium carbamate groups having a functionality of two in the isocyanate addition reaction, of the type obtained by reacting aliphatically bonded, primary or secondary amino groups with carbon dioxide,(iii) the unmodified compounds containing at least 3 ether groups having a molecular weight of from 200 to 10,000 and(iv) at least 0,2 equivalent % of all isocyanate-reactive groups of the total component (b) being ammonium carbamate groups.The present invention also relates to said compounds (b) optionally in admixture with the auxiliaries and additives known in polyurethane chemistry.

    摘要翻译: 本发明涉及一种制备聚脲基微孔成型体的方法,其包括使(a)至少一种仅含芳香结合的异氰酸酯基团的二异氰酸酯或多异氰酸酯,(b)至少一种含有至少两个异氰酸酯反应性基团的化合物 ,和(c)任选地在聚氨酯化学中已知的助剂和添加剂,在封闭模具中,组分(a) - (c)通过反应注射成型作为一步法处理,其特征在于组分(b)至少包含 一种聚醚化合物(b1)任选地与其它异氰酸酯反应性化合物混合并且含有至少3个脂族键合的醚基团和n-脂肪键合的异氰酸酯反应性基团,n代表整数,或统计学上为2-4 i)组分(b1)中存在的至少(100:n)%的异氰酸酯 - 反应性基团是脂族键合的伯和/或仲氨基,(ii)至少10当量 所述氨基的%以异氰酸酯加成反应中官能度为2的氨基甲酸铵基团的形式存在,其通过脂族键合,伯或仲氨基与二氧化碳反应而获得的类型,(iii)未修饰的化合物含有 至少3个分子量为200至10,000的醚基和(iv)总组分(b)的所有异氰酸酯反应性基团的至少0.2当量%为氨基甲酸铵基团。 本发明还涉及所述化合物(b),任选地与聚氨酯化学中已知的助剂和添加剂混合。

    Herbicidally active substituted
6-halogeno-tert.-butyl-1,2,4-triazin-5-ones
    79.
    发明授权
    Herbicidally active substituted 6-halogeno-tert.-butyl-1,2,4-triazin-5-ones 失效
    除草活性的取代的6-卤代叔丁基-1,2,4-三嗪-5-酮

    公开(公告)号:US4386953A

    公开(公告)日:1983-06-07

    申请号:US299919

    申请日:1981-09-08

    CPC分类号: C07D253/075 A01N43/707

    摘要: A substituted 6-halogeno-tert.-butyl-1,2,4-triazin-5-one of the formula ##STR1## in which R.sup.1 is an amino or methyl group,R.sup.2 is an alkylmercapto, alkylamino or dialkylamino group,X is a halogen atom, andY and Z each independently is a hydrogen or halogen atom,which possesses selective herbicidal activity. A synthesis involving the novel intermediates ##STR2## in which X, Y and Z have the above-mentioned meaning andQ is CN, CONH.sub.2 or COOH,is also shown.

    摘要翻译: R 1为氨基或甲基的取代的6-卤代叔丁基-1,2,4-三嗪-5-酮,其中R 1为烷基巯基,烷基氨基或二烷基氨基,X为 卤素原子,Y和Z各自独立地为具有选择性除草活性的氢或卤素原子。 涉及其中X,Y和Z具有上述含义且Q为CN,CONH 2或COOH的新中间体“IMAGE”的合成也显示。