公开(公告)号：US5021308A

公开(公告)日：1991-06-04

申请号：US467358

申请日：1990-01-23

申请人： Michel Armand ,  Michel Gauthier ,  Daniel Muller

发明人： Michel Armand ,  Michel Gauthier ,  Daniel Muller

IPC分类号： H01M6/16

CPC分类号： H01M6/166 ,  H01G11/56 ,  Y02E60/13

摘要： An electrochemical cell with an electrolyte of an ionically conductive material comprised of a salt diluted in a liquid solvent. The salt is represented by one of the following formulas: ##STR1##

摘要翻译： 具有离子导电材料的电解质的电化学电池由在液体溶剂中稀释的盐组成。 盐由下式表示：M [RFSO 2 NSO 2 R'F]; M [RFSO2NCOR'F]; [RFCONCOR'F];

公开(公告)号：US4683181A

公开(公告)日：1987-07-28

申请号：US726622

申请日：1985-04-24

申请人： Michel Armand ,  Jean-Michel Chabagno ,  Philippe Ricoux ,  Guy Vassort ,  Michel Gauthier ,  Fernand Brochu ,  Philippe Rigaud

发明人： Michel Armand ,  Jean-Michel Chabagno ,  Philippe Ricoux ,  Guy Vassort ,  Michel Gauthier ,  Fernand Brochu ,  Philippe Rigaud

IPC分类号： H01M4/58 ,  H01M10/052 ,  H01M10/36 ,  H01M10/40

CPC分类号： H01M10/052 ,  H01M4/581 ,  H01M4/5815

摘要： Electrochemical generator, the electrolyte of which is made of a macromolecular material comprising a salt in solution and of which the positive electrode is a composite electrode which comprises as active material a metallic compound adapted to be reduced by the cation of the salt in solution by generating during this reduction new species which can include the zero oxidation degree metal, said generator being able to operate reversibly at ambient temperature.

摘要翻译： 电化学发生器，其电解质由包含溶液中的盐的大分子材料制成，其中正电极是复合电极，其包含作为活性材料的金属化合物，其适于通过产生溶液中的盐的阳离子而被还原 在该还原期间，可以包括零氧化度金属的新物种，所述发生器能够在环境温度下可逆地操作。

公开(公告)号：US08668842B2

公开(公告)日：2014-03-11

申请号：US12972009

申请日：2010-12-17

申请人： Guoxian Liang ,  Jasmin Dufour ,  Michel Gauthier ,  Nathalie Ravet ,  Denis Geoffroy

发明人： Guoxian Liang ,  Jasmin Dufour ,  Michel Gauthier ,  Nathalie Ravet ,  Denis Geoffroy

IPC分类号： H01M4/88

CPC分类号： H01M4/0471 ,  C01B25/37 ,  C01B25/45 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/5825

摘要： A process for preparing an alkali metal oxyanion electrode material having a carbon coating deposited by a thermal treatment, said process comprising a thermal step under a humidified atmosphere of: (i) said alkali metal oxyanion electrode material having a carbon coating deposited by a thermal treatment; (ii) precursors of said alkali metal oxyanion electrode material and an organic precursor of carbon; or (iii) said alkali metal oxyanion electrode material and an organic precursor of carbon, wherein said thermal step is performed at a temperature in the range of about 300° C. to about 950° C.

摘要翻译： 一种制备具有通过热处理沉积的碳涂层的碱金属氧阴离子电极材料的方法，所述方法包括在湿润气氛下的热步骤：（i）所述碱金属氧阴离子电极材料具有通过热处理沉积的碳涂层 ; （ii）所述碱金属氧阴离子电极材料的前体和碳的有机前体; 或（iii）所述碱金属氧阴离子电极材料和碳的有机前体，其中所述热步骤在约300℃至约950℃的温度下进行。

公开(公告)号：US08114469B2

公开(公告)日：2012-02-14

申请号：US12149535

申请日：2008-05-02

申请人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

IPC分类号： B05D5/12

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： A process for synthesizing particles of an oxide corresponding to a formula selected from: Li4Ti5O12; Li(4-α)ZβTi5O12; and Li4ZαTi(5-β)O12, said process including the steps of: a) preparing an intimately dispersed ternary mixture of TiOx—LiZY-carbon, wherein x is a number between 1 and 2, z is 1 or 2, Y is a radical chosen from the group consisting of CO3, OH, O and TiO3 or a mixture thereof, and the carbon is a carbon powder selected from the group consisting of natural or artificial graphite, carbon black, Shawinigan black, Ketjen black and cokes; b) heating the dispersion at a temperature of between 400 and 1,000° C.; and c) if appropriate, adding a source of at least one metal Z to the ternary mixture, wherein the operating conditions are chosen in such a way as to yield a conversion of the initial products respectively into Li4Ti5O12, Li(4-α)ZαTi5O12, Li4ZβTi(5-β)O12.

摘要翻译： 一种合成相应于下式的氧化物颗粒的方法：Li 4 Ti 5 O 12; Li（4-α）Z＆bgr; Ti5O12; 所述方法包括以下步骤：a）制备紧密分散的TiOx-LiZY-碳的三元混合物，其中x是1和2之间的数，z是1或2，Y是 选自CO 3，OH，O和TiO 3或其混合物的基团，碳是选自天然或人造石墨，炭黑，Shawinigan黑，Ketjen黑和焦炭的碳粉末; b）在400-1000℃的温度下加热分散体; 并且c）如果合适，向三元混合物中加入至少一种金属Z的源，其中选择操作条件以分别将初始产物分别转化为Li 4 Ti 5 O 12，Li（4-α）ZαTi5 O 12 ，Li4Z＆bgr; Ti（5-＆bgr））O12。

公开(公告)号：US07993621B2

公开(公告)日：2011-08-09

申请号：US11790020

申请日：2007-04-23

申请人： Karim Zaghib ,  Michel Gauthier ,  Gabrielle Nadeau ,  Abdelbast Guerfi ,  Monique Massé ,  Fernand Brochu ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Gabrielle Nadeau ,  Abdelbast Guerfi ,  Monique Massé ,  Fernand Brochu ,  Michel Armand

IPC分类号： C01B31/04

CPC分类号： H01M4/583 ,  C01B32/215 ,  H01M4/133 ,  H01M10/0525

摘要： The present invention relates to the physical or chemical specific purification of natural mineral graphite. This purification is preferably applied to the surface of natural graphite in order to allow the formation of a passivation film during the first electrical discharge or the insertion of lithium in the graphite when the latter is used in a lithium-ion cell. The grinding to a small size before purification allows the optimization of the distribution of the particles, resulting in a more uniform electrode. This grinding is carried out in the presence of the natural impurities of the graphite that play the role of a micro-abrasive and result in a hardness of the graphite that increases its mechanical properties.

摘要翻译： 本发明涉及天然矿物石墨的物理或化学特异性纯化。 优选将该纯化施加到天然石墨的表面，以便在锂离子电池中使用时，在石墨中的第一次放电或锂的插入期间允许形成钝化膜。 在纯化之前研磨至小尺寸允许优化颗粒的分布，导致更均匀的电极。 这种研磨是在发生微磨料作用的石墨的天然杂质的存在下进行的，并导致石墨的硬度增加其机械性能。

公开(公告)号：US20100065787A1

公开(公告)日：2010-03-18

申请号：US12558195

申请日：2009-09-11

申请人： Michel ARMAND ,  Michel Gauthier ,  Jean-Francois Magnan ,  Nathalie Ravet

发明人： Michel ARMAND ,  Michel Gauthier ,  Jean-Francois Magnan ,  Nathalie Ravet

IPC分类号： H01B1/24 ,  H01B1/08

CPC分类号： H01G9/155 ,  C01B17/96 ,  C01B25/37 ,  C01B25/45 ,  C01B33/20 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/50 ,  C01P2004/80 ,  H01M4/136 ,  H01M4/366 ,  H01M4/485 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/625 ,  H01M10/052 ,  H01M10/0525 ,  Y02E60/13 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/30

摘要： A method for the synthesis of compounds of the formula C—LixM1−yM′y(XO4)n, where C represents carbon cross-linked with the compound LixM1−yM′y(XO4)n, in which x, y and n are numbers such as 0≦x≦2, 0≦y≦0.6, and 1≦n≦1.5, M is a transition metal or a mixture of transition metals from the first period of the periodic table, M′ is an element with fixed valency selected among Mg2+, Ca2+, Al3+, Zn2+ or a combination of these same elements and X is chosen among S, P and Si, by bringing into equilibrium, in the required proportions, the mixture of precursors, with a gaseous atmosphere, the synthesis taking place by reaction and bringing into equilibrium, in the required proportions, the mixture of the precursors, the procedure including at least one pyrolysis step of the carbon source compound.

摘要翻译： 用于合成式C-LixM1-yM'y（XO4）n的化合物的方法，其中C表示与化合物LixM1-yM'y（XO4）n交联的碳，其中x，y和n为 M是过渡金属或来自周期表第一周期的过渡金属的混合物，M'是具有固定化合价的元素，其中R 1，R 2， 选择Mg2 +，Ca2 +，Al3 +，Zn2 +或这些相同元素的组合，X选自S，P和Si，通过以所需比例将前体混合物与气体气氛并入， 通过反应并以所需比例使所述前体的混合物达到平衡，所述方法包括碳源化合物的至少一个热解步骤。

公开(公告)号：US20090305132A1

公开(公告)日：2009-12-10

申请号：US11919925

申请日：2006-05-05

申请人： Michel Gauthier ,  Christophe Michot

发明人： Michel Gauthier ,  Christophe Michot

IPC分类号： H01M4/48 ,  H01M4/60 ,  H01M4/62 ,  H01M10/26 ,  B05D5/12 ,  H01B1/24

CPC分类号： H01M4/485 ,  H01M4/04 ,  H01M4/13 ,  H01M4/131 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5805 ,  H01M4/5815 ,  H01M4/582 ,  H01M4/5825 ,  H01M4/622 ,  H01M4/625 ,  H01M10/0525

摘要： The invention relates to an electrode material and a composite electrode including same. The electrode material consists of particles or particulate aggregates of a complex LiiMmM′m′ZzOoNnFf oxide, wherein M is at least one transition metal, M′ is at least one metal other than a transition metal, Z is at least one non-metal, coefficients i, m, m′, z, o, n and f are selected in such a way that the complex oxide is electrically neutral, with i=0, m>0, z=0, m′=0, o>0, n=0 and f=0. At least part of the complex oxide particle or particulate aggregate surface is coated with a carbon layer bound by chemical bonds and/or physical bonds to the carbon. The complex oxide has formula; the carbon has covalently bonded functional groups GF.

摘要翻译： 本发明涉及电极材料和包括它的复合电极。 电极材料由复合LiMnM'M'ZzOoNnFf氧化物的颗粒或颗粒聚集体组成，其中M是至少一种过渡金属，M'是除过渡金属之外的至少一种金属，Z是至少一种非金属， 选择系数i，m，m'，z，o，n和f，使得复合氧化物是电中性的，其中i = 0，m> 0，z = 0，m'= 0，o> 0 ，n = 0，f = 0。 复合氧化物颗粒或颗粒聚集体表面的至少一部分涂覆有与碳结合的化学键和/或物理键结合的碳层。 复合氧化物具有配方; 碳具有共价键合的官能团GF。

公开(公告)号：US20090280410A1

公开(公告)日：2009-11-12

申请号：US12373945

申请日：2007-07-17

申请人： Karim Zaguib ,  Martin Dontigny ,  Michel Petitclerc ,  Michel Gauthier

发明人： Karim Zaguib ,  Martin Dontigny ,  Michel Petitclerc ,  Michel Gauthier

IPC分类号： H01M4/38 ,  H01M4/58 ,  B05D5/12

CPC分类号： H01M4/0402 ,  C23C4/11 ,  C23C8/10 ,  C23C28/00 ,  C23C28/321 ,  C23C28/322 ,  C23C28/324 ,  C23C28/34 ,  C23C28/345 ,  H01M4/0407 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/625 ,  H01M4/661 ,  H01M10/052 ,  H01M10/0565

摘要： A method for preparing a multilayer material based on active lithium, by depositing a film of active lithium on a protective layer at a sufficient speed so that substantially no oxidation of the lithium occurs, and/or during a sufficient time for the adhesion of the lithium to develop after contact with the protective layer. The multilayer material, when incorporated in an electrochemical battery as an anode, has excellent impedance stability and no formation of dendrites during the cycling. Batteries where the anode is the multilayer material are particularly efficient in terms of their coulomb efficiency.

摘要翻译： 一种制备基于活性锂的多层材料的方法，通过以足够的速度在保护层上沉积活性锂膜，使得基本上不发生锂的氧化，和/或在锂的粘附足够的时间内 与保护层接触后开发。 多层材料当结合在电化学电池中作为阳极时，具有优异的阻抗稳定性，并且在循环期间不形成枝晶。 阳极是多层材料的电池在库仑效率方面特别有效。

公开(公告)号：US20080285211A1

公开(公告)日：2008-11-20

申请号：US12149535

申请日：2008-05-02

申请人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

发明人： Karim Zaghib ,  Michel Gauthier ,  Fernand Brochu ,  Abdelbast Guerfi ,  Monique Masse ,  Michel Armand

IPC分类号： H01M4/48 ,  H01G9/155 ,  H01G9/04 ,  C01G23/04

CPC分类号： H01M4/485 ,  B82Y30/00 ,  C01G23/003 ,  C01G23/005 ,  C01P2002/77 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/64 ,  C01P2006/40 ,  H01G9/155 ,  H01G11/04 ,  H01G11/46 ,  H01M4/02 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/136 ,  H01M4/366 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/623 ,  H01M4/625 ,  H01M4/661 ,  H01M4/745 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/004 ,  H01M2300/0082 ,  H01M2300/0085 ,  Y02E60/122 ,  Y02E60/13 ,  Y02P70/54 ,  Y10T428/2982

摘要： Synthesis process for new particles of Li4Ti5O12, Li(4-α)ZαTi5O12 or Li4ZβTi(5-β)O12, preferably having a spinel structure, wherein β is greater than 0 and less than or equal to 0.5 (preferably having a spinel structure), α representing a number greater than zero and less than or equal to 0.33, Z representing a source of at least one metal, preferably chosen from the group made up of Mg, Nb, Al, Zr, Ni, Co. These particles coated with a layer of carbon notably exhibit electrochemical properties that are particularly interesting as components of anodes and/or cathodes in electrochemical generators.

摘要翻译： Li 4 N 5 O 12的新颗粒的合成方法，Li（4-α）Z _{5 5 β优选具有尖晶石结构，其中β大于0且小于或等于0.5（优选具有尖晶石结构），α表示大于零的数 并且小于或等于0.33，Z代表至少一种金属的源，优选选自由Mg，Nb，Al，Zr，Ni，Co组成的组。涂覆有碳层的这些颗粒特别表现出电化学性质 这在电化学发生器中作为阳极和/或阴极的组分是特别有意义的。}

公开(公告)号：US07378194B2

公开(公告)日：2008-05-27

申请号：US10954487

申请日：2004-10-01

申请人： Christophe Michot ,  Michel Armand ,  Michel Gauthier ,  Nathalie Ravet

发明人： Christophe Michot ,  Michel Armand ,  Michel Gauthier ,  Nathalie Ravet

IPC分类号： H01M10/36 ,  H01M10/40 ,  C01B25/00 ,  C07F9/02 ,  C07C23/00

CPC分类号： C07C211/63 ,  C07C45/46 ,  C07C45/72 ,  C07C211/64 ,  C07C317/04 ,  C07C317/12 ,  C07C381/00 ,  C07D213/20 ,  C07D213/74 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D311/82 ,  C07D339/06 ,  C07F9/54 ,  H01G9/038 ,  H01G9/20 ,  H01G9/2004 ,  H01G11/62 ,  H01M4/13 ,  H01M4/505 ,  H01M4/525 ,  H01M4/58 ,  H01M4/5825 ,  H01M4/587 ,  H01M4/60 ,  H01M4/602 ,  H01M4/624 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M6/181 ,  H01M8/1048 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0566 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/36 ,  H01M2300/0022 ,  H01M2300/0082 ,  Y02E10/542 ,  Y02E60/122 ,  Y02E60/13

摘要： The invention concerns novel ionic compounds with low melting point whereof the onium type cation having at least a heteroatom such as N, O, S or P bearing the positive charge and whereof the anion includes, wholly or partially, at least an ion imidide such as (FX1O)N−(OX2F) wherein X1 and X2 are identical or different and comprise SO or PF, and their use as solvent in electrochemical devices. Said composition comprises a salt wherein the anionic charge is delocalised, and can be used, inter alia, as electrolyte.

摘要翻译： 本发明涉及具有低熔点的新型离子化合物，其中具有至少具有正电荷的N，O，S或P的杂原子的鎓型阳离子及其阴离子全部或部分至少包含一个离子酰亚胺，例如 （FX 1 O）N - （OX 2 F）其中X 1和X 2， / SUP>相同或不同，包含SO或PF，以及它们在电化学装置中作为溶剂的用途。 所述组合物包含盐，其中阴离子电荷是离域的，并且可以特别地用作电解质。