公开(公告)号：US5053376A

公开(公告)日：1991-10-01

申请号：US532720

申请日：1990-06-04

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J27/051 ,  B01J37/20 ,  C10G47/12

CPC classification number: C10G47/12 ,  B01J27/051 ,  B01J37/20

Abstract: A method for preparing a sulfided molybdenum catalyst concentrate which method comprises: (a) forming a precursor catalyst concentrate by mixing together: (i) a hydrocarbonaceous oil comprising constituents boiling above about 1050.degree. F.; (ii) a metal compound, said metal being selected from the group consisting of Groups II, III, IV, V, VIB, VIIB, and VIII of the Periodic Table of the Elements, in an amount to provide from about 0.2 to 2 wt. % metal, based on said hydrocarbonaceous oil; and (iii) elemental sulfur in an amount such that the atomic ratio of sulfur to metal is from about 1/1 to 8/1; and (b) heating the mixture to an effective temperature to produce a catalyst concentrate.

Abstract translation: 一种制备硫化钼催化剂浓缩物的方法，该方法包括：（a）通过混合在一起形成前体催化剂浓缩物：（i）包含沸点高于约1050°F的组分的含烃油; （ii）金属化合物，所述金属选自元素周期表的第II，III，IV，V，VIB，VIIB和VIII族，其量为约0.2至2wt 。 基于所述烃油的％金属; 和（iii）元素硫，其量使得硫与金属的原子比为约1/1至8/1; 和（b）将混合物加热到有效温度以产生催化剂浓缩物。

公开(公告)号：US4882036A

公开(公告)日：1989-11-21

申请号：US291390

申请日：1988-12-27

Applicant: Clarence M. Eidt, Jr. ,  Clyde L. Aldrige ,  Roby Bearden, Jr.

Inventor： Clarence M. Eidt, Jr. ,  Clyde L. Aldrige ,  Roby Bearden, Jr.

IPC: C10B55/00 ,  C10G9/00 ,  C10G31/11 ,  C10G69/06

CPC classification number: C10G31/11 ,  C10B55/00 ,  C10G69/06 ,  C10G9/005

Abstract: A hydrocarbonaceous feed, such as petroleum vacuum distillation bottoms, is upgraded by a combination coking and catalytic slurry hydroconversion process wherein a bottoms fraction from coking is passed through a microfiltration system to remove coke fines, the filtrate passed to a slurry hydroconversion zone, and the bottoms fraction from the slurry hydroconversion zone is also passed through a microfiltration system to remove catalyst particles.

Abstract translation: 通过组合焦化和催化浆料加氢转化方法提高烃类进料，例如石油真空蒸馏塔底馏分，其中焦化的塔底馏分通过微量过滤系统以除去焦炭，滤液通过浆料加氢转化区， 来自浆料加氢转化区的塔底馏分也通过微量过滤系统以除去催化剂颗粒。

公开(公告)号：US4765882A

公开(公告)日：1988-08-23

申请号：US857358

申请日：1986-04-30

Applicant: Clyde L. Aldridge ,  William E. Lewis ,  Roby Bearden, Jr. ,  Francis X. Mayer

Inventor： Clyde L. Aldridge ,  William E. Lewis ,  Roby Bearden, Jr. ,  Francis X. Mayer

IPC: C10G49/12 ,  C10G65/10

CPC classification number: C10G49/12 ,  C10G65/10

Abstract: A slurry catalytic hydroconversion process comprising at least two hydroconversion zones is provided in which the heavy hydrocarbonaceous fresh oil feed is added to more than one hydroconversion zone. Additional portions of catalysts or catalyst precursors are also added to the first hydroconversion zone and to additional hydroconversion zones.

Abstract translation: 提供了包含至少两个加氢转化区的淤浆催化加氢转化方法，其中将重质烃类新鲜油进料加入多于一个加氢转化区。 催化剂或催化剂前体的另外部分也加入到第一加氢转化区和另外的加氢转化区。

公开(公告)号：US4637871A

公开(公告)日：1987-01-20

申请号：US785994

申请日：1985-10-10

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: C10G47/26 ,  C10G47/02

CPC classification number: C10G47/26

Abstract: Slurry hydroconversion processes utilizing an aqueous solution of phosphomolybdic acid as catalyst precursor, which is subsequently converted to a solid molybdenum-containing catalyst, are improved when the catalyst precursor aqueous solution comprises a specified concentration of molybdenum derived from the phosphomolybdic acid. The improved hydroconversion processes and the improved method of preparing the catalyst are provided.

Abstract translation: 当催化剂前体水溶液包含来自磷钼酸的规定浓度的钼时，利用磷钼酸水溶液作为催化剂前体的随后转化成固体含钼催化剂的浆料加氢转化方法得到改善。 提供了改进的加氢转化方法和改进的制备催化剂的方法。

公开(公告)号：US4569752A

公开(公告)日：1986-02-11

申请号：US676864

申请日：1984-11-30

Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

IPC: C10G69/06 ,  C10G69/00 ,  C10G69/10

CPC classification number: C10G69/06

Abstract: A carbonaceous feed, such as a heavy hydrocarbonaceous oil or coal, and mixtures thereof, is upgraded by a combination coking and catalytic slurry hydroconversion process in which a catalyst precursor is added to the feed of the hydroconversion zone as a catalyst precursor concentrate prepared from a virgin hydrocarbonaceous oil and a thermally decomposable or oil dispersible metal compound.

Abstract translation: 通过组合焦化和催化浆料加氢转化方法提高碳质原料如重烃类油或煤及其混合物，其中将催化剂前体加入到加氢转化区的进料中，作为催化剂前体浓缩物，其由 原始含烃油和可热分解或油分散的金属化合物。

公开(公告)号：US4548700A

公开(公告)日：1985-10-22

申请号：US561475

申请日：1983-12-14

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: C10G1/08 ,  C10G47/24 ,  C10G47/26 ,  C01G31/00 ,  C01G39/00

CPC classification number: C10G47/26 ,  C10G1/086 ,  C10G47/24

Abstract: A slurry hydroconversion process is provided in which a carbonaceous chargestock such as a hydrocarbonaceous oil or coal comprising a catalyst containing vanadium or molybdenum or mixtures thereof, is converted to a hydroconverted oil product. A heavy oil portion comprising metal-containing solids is separated from the oil product and partially gasified to produce a carbon-free metal-containing ash which is extracted with oxalic acid. The resulting metal-containing oxalic acid extract is recycled to the hydroconversion zone as catalyst precursor.

Abstract translation: 提供了一种浆料加氢转化方法，其中将包含含有钒或钼或其混合物的催化剂的含碳物质如含烃油或煤转化为加氢转化的油产物。 将包含含金属固体的重油部分与油产物分离并部分气化以产生用草酸萃取的无碳金属灰。 所得含金属的草酸提取物作为催化剂前体再循环至加氢转化区。

公开(公告)号：US4348270A

公开(公告)日：1982-09-07

申请号：US246448

申请日：1981-03-23

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge ,  Lloyd A. Pine

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge ,  Lloyd A. Pine

IPC: B01J23/745 ,  B01J27/04 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  C10G1/08 ,  C10G49/12 ,  C10G1/06 ,  C10G11/02 ,  C10G45/04 ,  C10G47/12

CPC classification number: B01J27/04 ,  B01J23/745 ,  B01J37/0215 ,  B01J37/086 ,  B01J37/16 ,  C10G1/086 ,  C10G49/12

Abstract: A catalyst is provided which comprises a composition comprising a catalytic metal component, carbon and hydrogen deposited on a low surface area aluminum alloy powder support prepared by atomizing the metal alloy. Hydrocarbon treating and conversion processes utilizing the catalyst are also provided. The catalyst is particularly suitable for slurry processes.

Abstract translation: 提供了一种催化剂，其包含一种组合物，其包含沉积在通过雾化金属合金制备的低表面积铝合金粉末载体上的催化金属成分，碳和氢。 还提供了利用催化剂的烃处理和转化方法。 催化剂特别适用于淤浆方法。

公开(公告)号：US4295995A

公开(公告)日：1981-10-20

申请号：US90415

申请日：1979-11-01

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02 ,  B01J23/84 ,  B01J23/85 ,  B01J27/04 ,  B01J31/12

CPC classification number: B01J37/086 ,  B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02

Abstract: A catalyst comprising a composition comprising a catalytic metal component, carbon and hydrogen deposited on a low surface area metal or metal alloy support is provided. Hydrocarbon treating and conversion processes utilizing the catalyst are also provided. The catalyst is particularly suitable for slurry processes.

Abstract translation: 提供了一种包含沉积在低表面积金属或金属合金载体上的催化金属成分，碳和氢的组合物的催化剂。 还提供了利用催化剂的烃处理和转化方法。 催化剂特别适用于淤浆方法。

公开(公告)号：US4169038A

公开(公告)日：1979-09-25

申请号：US889744

申请日：1978-03-24

Applicant: William J. Metrailer ,  Roby Bearden, Jr. ,  Clyde L. Aldridge

Inventor： William J. Metrailer ,  Roby Bearden, Jr. ,  Clyde L. Aldridge

IPC: C10B55/10 ,  C10G1/00 ,  C10G1/06 ,  C10G1/08 ,  C10G69/06 ,  C10J3/54 ,  C10G9/32

CPC classification number: C10J3/54 ,  C10B55/10 ,  C10G1/002 ,  C10G1/08 ,  C10G1/086 ,  C10G69/06 ,  C10J3/503 ,  C10J3/66 ,  C10J3/78 ,  C10J3/84 ,  C10J2300/0906 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/0976 ,  C10J2300/0986 ,  C10J2300/1807 ,  C10J2300/1884 ,  Y10S208/951

Abstract: A combination slurry hydroconversion, coking and coke gasification process is provided wherein solid fines having an average particle size of less than 10 microns in diameter or the ashes thereof recovered from a gaseous product derived from the coke gasification are used as a catalyst in the hydroconversion stage.

Abstract translation: 提供了一种组合浆料加氢转化，焦化和焦炭气化方法，其中直径小于10微米的固体细粉或其衍生自焦炭气化的气态产物回收的灰分在加氢转化阶段用作催化剂 。

公开(公告)号：US4123350A

公开(公告)日：1978-10-31

申请号：US713510

申请日：1976-08-11

Applicant: William C. Baird, Jr. ,  Roby Bearden, Jr. ,  Ralph L. Bollinger, Jr.

Inventor： William C. Baird, Jr. ,  Roby Bearden, Jr. ,  Ralph L. Bollinger, Jr.

IPC: C10G19/00 ,  C10G19/08 ,  C10G45/00 ,  C10G13/06 ,  B01J23/04 ,  B01J23/90

CPC classification number: C10G19/00 ,  C10G19/08 ,  C10G45/00 ,  Y10S423/12

Abstract: Sulfur-containing petroleum oil feedstocks which include heavy hydrocarbon constituents undergo simultaneous desulfurization and hydroconversion by contacting and reacting such feedstocks with sodamide in the presence of hydrogen and at elevated temperatures. The mixture of reaction products resulting from the above procedure is separated to give a sodium sulfur salt by-product, and a petroleum oil product which has been substantially desulfurized and demetallized, as well as being significantly improved as indicated by a reduced Conradson carbon content and an increased API gravity relative to the feedstock. Sodamide is regenerated from the sodium sulfur salt by-product and can be recycled for reaction with additional feedstock.