摘要:
There is provided a fluorine-containing copolymer having an aliphatic monocyclic structure in the polymer trunk chain which has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (Ma): -(M1)-(M2a)-(N)- (Ma) in which the structural unit M1 is a structural unit derived from an ethylenic monomer having 2 or 3 carbon atoms and at least one fluorine atom, the structural unit M2a is at least one structural unit which introduces an aliphatic monocyclic structure in the polymer trunk chain and is represented by the formula (a): wherein R1 is at least one hydrocarbon group selected from the group consisting of a divalent hydrocarbon group having 1 to 8 carbon atoms and constituting a ring which may be further substituted with a hydrocarbon group or a fluorine-containing alkyl group and a divalent hydrocarbon group having ether bond which has the sum of carbon atoms and oxygen atoms of 2 to 8, constitutes a ring and may be further substituted with a hydrocarbon group or a fluorine-containing alkyl group; R2 is an alkylene group which has 1 to 3 carbon atoms and constitutes a ring; R3 and R4 are the same or different and each is a divalent alkylene group which has 1 or 2 carbon atoms and constitutes a ring; n1, n2 and n3 are the same or different and each is 0 or 1, the structural unit N is a structural unit derived from a monomer copolymerizable with the monomers to introduce the structural units M1 and M2a, and the structural units M1, M2a and N are contained in amounts of from 1 to 99% by mole, from 1 to 99% by mole and from 0 to 98% by mole, respectively. The fluorine-containing polymer possesses excellent dry etching resistance and transparency in a vacuum ultraviolet region.
摘要:
This invention provides a cyclic ether copolymer such as a cyclic ether copolymer excellent in solubility in solvents and easy to form uniform thin films therefrom. The present invention relates to a cyclic ether copolymer obtained from a 1,3-dioxole ring structure-containing compound represented by the following general formula (I) and an ethylenically unsaturated monomer: (wherein R1 and R2 are the same or different and each represents F, H, Cl or a perfluoroalkyl group containing 1 to 5 carbon atoms and X1 and X2 are the same or different and each represents F, H, Cl or —OR3, and R3 represents a perfluoroalkyl group containing 1 to 5 carbon atoms, provided that at least one of R1 and R2 is F or a perfluoroalkyl group containing 1 to 5 carbon atoms), which compolymer has a glass transition point of 100 to 135° C. and an intrinsic viscosity of 0.01 to 0.4 dl/g as determined at 35° C. in perfluoro-2-butyltetrahydrofuran.
摘要:
There is provided a method of forming a thin film of vinylidene fluoride homopolymer having crystal form I which is applicable to various substrates in relatively easy way (coating conditions, application method, etc.), a process for preparing a vinylidene fluoride homopolymer having crystal form I efficiently at high purity, and novel vinylidene fluoride homopolymers which can give a thin film being excellent in ferroelectricity. The method of forming a thin film of vinylidene fluoride homopolymer comprises (i) a step for preparing a green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component by subjecting vinylidene fluoride to radical polymerization in the presence of a bromine compound or iodine compound having 1 to 20 carbon atoms which contains at least one moiety represented by —CRf1Rf2X1, wherein X1 is iodine atom or bromine atom; Rf1 and Rf2 are the same or different and each is selected from fluorine atom or perfluoroalkyl groups having 1 to 5 carbon atoms and (ii) a step for forming a thin film on a substrate surface by using vinylidene fluoride homopolymer which comprises crystal form I alone or as main component and is obtained from the green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component.
摘要:
There is provided a fluorine-containing optical material and a fluorine-containing copolymer which have excellent heat resistance and flexibility in addition to optical characteristics, particularly a material suitable as a clad material for heat resistant plastic optical fiber. The fluorine-containing optical material comprises from 15 to 62% by mole of a structural unit (a) derived from hexafluoroneopentyl methacrylate, from 12 to 70% by mole of a structural unit (b) derived from methyl methacrylate and from 1 to 40% by mole of a structural unit (c) which is derived from a fluorine-containing monomer and is copolymerizable therewith, and is used as various optical materials, and is useful particularly as a clad material for heat resistant optical fiber.
摘要:
According to the present invention, it is possible to provide a molding material, for example, a sealing material for semiconductor-related production apparatuses which comprises a fluorine-containing multi-segment polymer being excellent in mechanical properties (particularly at high temperature), abrasion resistance and transparency and ensuring reduced contamination and reduced gas permeation while maintaining inherent characteristics of a fluorine-containing elastomer such as flexibility, elasticity, sealing property, chemical resistance and heat resistance. A molding material comprising a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment and a non-elastomeric fluorine-containing polymer chain segment, in which the elastomeric fluorine-containing polymer chain segment imparts flexibility to the whole polymer and has perhaloolefin units as a recurring unit in an amount of not less than 95% by mole.
摘要:
The nickel powder is characterized in that the rate of the nickel particles whose particle size is not less than 1.2 time the average particle size as determined by the observation with an SEM is not more than 5% of the total number of nickel particles and that the rate of nickel particles whose particle size is not more than 0.8 time the average particle size is not more than 5% of the total number of nickel particles. The nickel powder is produced by bringing a slurry, containing nickel hydroxide, which is prepared by adding an aqueous solution of a nickel salt to an aqueous solution of an alkali metal hydroxide, into contact with a hydrazine reducing agent under the temperature conditions of not less than 55° C. to reduce the nickel hydroxide.
摘要:
A platform monitoring system includes a camera for capturing a situation on a platform. An image captured by the camera is transmitted from a light emitter on the ground side as an optical signal and also transmitted from a transmission antenna on the ground side as a radio wave signal. These signals are received by an optical receiver and a reception antenna, respectively, mounted in a leading end portion of a vehicle. When the vehicle is positioned in a region around a stopping position, an image carried by the optical signal is selectively displayed on a monitor disposed near an operator's seat in the vehicle. When the vehicle is positioned out of the region around the stopping position, an image carried by the radio wave signal is selectively displayed on the monitor near the operator's seat in the vehicle.
摘要:
The present invention relates to nickel powder characterized in that the rate of the nickel particles whose particle size is not less than 1.2 time the average particle size as determined by the observation with an SEM is not more than 5% of the total number of nickel particles, that the rate of nickel particles whose particle size is not more than 0.8 time the average particle size is not more than 5% of the total number of nickel particles and that the tap density of the nickel powder is not less than 2.5 g/cm3, as well as a conductive paste for use in making a multilayer ceramic capacitor. The nickel powder of the present invention has a narrow particle size distribution and an excellent packing ability in a conductive paste and is particularly suitably used for forming a thin and uniform inner electrode for a multilayer ceramic capacitor, without being accompanied by the formation of any crack and/or the generation of any delamination.
摘要翻译:本发明涉及镍粉,其特征在于,通过用SEM观察确定的粒径不小于平均粒径的1.2倍的镍粒子的速率不超过镍粒子总数的5% 粒径不大于平均粒径的0.8倍的镍粒子的速率不超过镍粒子总数的5%,并且镍粉的振实密度不小于2.5g / cm 3 ,以及用于制造多层陶瓷电容器的导电浆料。 本发明的镍粉末具有窄的粒度分布和在导电浆料中的优异的填充能力,特别适用于形成薄且均匀的多层陶瓷电容器的内部电极,而不伴随任何裂纹的形成 和/或产生任何分层。
摘要:
A method for preparing nickel fine powder is herein disclosed, which comprises the steps of mixing an aqueous sodium hydroxide solution comprising, on the basis of the total weight of the sodium hydroxide present in the aqueous solution, 75 to 85% by weight of liquid caustic soda as specified in JIS K 1203 and 25 to 15% by weight, in total, of at least one of sodium hydroxide as specified in JIS K 8576 and solid caustic soda as specified in JIS K 1202, with an aqueous solution of nickel sulfate to form nickel hydroxide, then reducing the resulting nickel hydroxide with hydrazine and recovering nickel fine powder produced. The nickel fine powder prepared by the method has an average particle size of the primary particles ranging from 0.1 to 0.9 .mu.m, a D.sub.90 value of not more than 2.1 .mu.m and a tap density of not less than 3.5 g/cc. The nickel fine powder has a low degree of aggregation, a narrow particle size distribution and a high tap density and therefore, the powder is quite suitably used as a material for producing an internal electrode for a laminated ceramic condenser.
摘要翻译:本文公开了一种制备镍微粉的方法,其包括以下步骤:将氢氧化钠水溶液混合,所述氢氧化钠水溶液基于存在于水溶液中的氢氧化钠的总重量为75至85重量%的液体苛性碱 按照JIS K 1203中规定的苏打水,以及JIS-8576中规定的氢氧化钠中的至少一种和JIS K 1202中规定的固体苛性钠中的至少一种的25〜15重量%的硫酸镍水溶液 形成氢氧化镍,然后用肼还原所得的氢氧化镍并回收生产的镍细粉。 通过该方法制备的镍微粉末,其一次粒子的平均粒径为0.1〜0.9μm,D90值不大于2.1μm,振实密度为3.5g / cc以上。 镍微粉末具有低聚集度,窄粒度分布和高振实密度,因此该粉末非常适合用作制备用于层压陶瓷冷凝器的内部电极的材料。
摘要:
A semiconductor device including a plurality of cells having an antenna protection element and a cell other than the antenna protection element; and a first dummy pattern and a second dummy pattern arranged in a layer above the plurality of cells. Further, the first dummy pattern overlaps with the antenna protection element, the second dummy pattern overlaps with the cell other than the antenna protection element, and a first layout rule of the first dummy pattern is different from a second layout rule of the second dummy pattern.