Membrane electrode assembly and method for hydrogen evolution by electrolysis

    公开(公告)号:US11549188B2

    公开(公告)日:2023-01-10

    申请号:US17243303

    申请日:2021-04-28

    Abstract: A membrane electrode assembly includes a first electrode, a second electrode, and an anion exchange membrane disposed between the first electrode and the second electrode. The first electrode includes a first metal mesh, a first catalyst layer wrapping the first metal mesh, a second metal mesh, and a second catalyst layer wrapping the second metal mesh. The first metal mesh is disposed between the anion exchange membrane and the second metal mesh. The second metal mesh is thicker than the first metal mesh, and the first catalyst layer is thicker than the second catalyst layer. The second catalyst layer is iron, cobalt, manganese, zinc, niobium, molybdenum, ruthenium, platinum, gold, or aluminum. The second catalyst layer is crystalline.

    METHOD FOR ELECTROCHEMICAL EXTRACTION OF URANIUM FROM SEAWATER USING OXYGEN VACANCY (OV)-CONTAINING METAL OXIDE

    公开(公告)号:US20220090271A1

    公开(公告)日:2022-03-24

    申请号:US17433613

    申请日:2020-12-11

    Abstract: A method for electrochemical extraction of uranium from seawater using an oxygen vacancy (OV)-containing metal oxide includes the following steps: adding glycerin to a solution of indium nitrate in isopropanol, transferring a resulting mixture to a reactor, and conducting reaction to obtain a spherical indium hydroxide solid; dissolving the solid in deionized water, transferring a resulting solution to the reactor, and conducting reaction to obtain a flaky indium hydroxide solid; calcining the solid to obtain calcined OV-containing In2O3-x; adding the In2O3-x; to ethanol, and adding a membrane solution; coating a resulting solution uniformly on carbon paper, and naturally drying the carbon paper; clamping dried carbon paper with a gold electrode for being used as a working electrode for a three-electrode system; and adding simulated seawater to an electrolytic cell, placing the three-electrode system in the simulated seawater, and stirring the simulated seawater for electrolysis to extract uranium from the seawater.

    TWO-PHASE SOLUTIONS FOR ELECTROCHEMICALLY GENERATING CHEMICAL PRODUCTS

    公开(公告)号:US20250043437A1

    公开(公告)日:2025-02-06

    申请号:US18365962

    申请日:2023-08-04

    Abstract: Some aspects of the present disclosure are generally directed to systems for electrochemically generating compounds, for example, for generating hydrogen peroxide or other applications. In some cases, the systems may include electrodes containing a substrate comprising non-woven fibers comprising carbon, PTFE particles on the substrate, and/or an active material, for example, carbon particles, on the substrate and/or the PTFE. In some embodiments, the systems may generate and/or flow a two-phase solution over and/or through at least a portion of an electrode. Some systems using the electrode structures and/or two-phase solution may promote the formation of three-phase boundaries, and thus may facilitate the electrocatalytic generation of certain compounds at the three-phase boundaries. Still other aspects are directed to methods of making and/or using the systems, or the like.

    ELECTRODE AND WATER ELECTROLYSIS APPARATUS

    公开(公告)号:US20250034728A1

    公开(公告)日:2025-01-30

    申请号:US18715196

    申请日:2022-08-25

    Abstract: An electrode includes a metal porous-body sheet formed of a metal porous body having a skeleton, the skeleton having a three-dimensional network structure, and a metallic support body having a plate shape and disposed on one main surface of the metal porous-body sheet. The one main surface has a plurality of machined holes each formed perpendicularly to the one main surface, and at least some of the plurality of machined holes are disposed at equal intervals. The metallic support body has a plurality of through holes extending through two surfaces of the metallic support body, and at least some of the plurality of through holes are disposed at equal intervals. A center of each of the some of the plurality of machined holes and a center of each of the some of the plurality of through holes are shifted from each other in one direction in plan view.

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