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    N,N-Dialkylamino diphenylamines and the use thereof in compositions for dyeing keratinic fibers
    81.
    发明授权
    N,N-Dialkylamino diphenylamines and the use thereof in compositions for dyeing keratinic fibers 失效
    N，N-二烷基氨基二苯胺及其在用于染色角蛋白纤维的组合物中的用途

    公开(公告)号：US4288622A

    公开(公告)日：1981-09-08

    申请号：US741495

    申请日：1976-11-12

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/40 ,  C07C91/42 ,  D06P1/32

    CPC分类号： A61K8/415 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/40

    摘要： Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, amino, lower alkyl amino wherein the alkyl moiety has 1-6 carbon atoms, acylamino, lower carbamylalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower hydroxyalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower carbalkoxy amino wherein the alkoxy moiety has 1-6 carbon atoms and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, acylamino and ureido;R.sub.5 and R.sub.8 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl having 1-6 carbon atoms and lower alkoxy having 1-6 carbon atoms; andR.sub.6 and R.sub.7 are lower alkyl having 1-6 carbon atoms, with the proviso that (a) when both R.sub.6 and R.sub.7 represent methyl (1) one of R.sub.1 and R.sub.4 must represent a member selected from the group consisting of amino, lower alkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower carbamylalkyl amino wherein the alkyl moiety has 1-6 carbon atoms, lower hydroxyalkyl amino wherein the alkyl moiety has 1-6 carbon atoms and ureido, or (2) one of R.sub.1 and R.sub.4 represent acylamino and R.sub.2 and R.sub.3 are not both hydrogen, and (b) that when both R.sub.6 and R.sub.7 represent ethyl, R.sub.2 and R.sub.3 are other than tertiobutyl.The said diphenylamine is employed in a dye composition for dyeing keratinic fibers.

    摘要翻译： 式IMA的二苯胺其中R 1和R 4各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，氨基，低级烷基氨基， 烷基部分具有1-6个碳原子，酰基氨基，低级氨基甲酰基烷基氨基，其中烷基部分具有1-6个碳原子，其中烷基部分具有1-6个碳原子的低级羟烷基氨基，低级烷氧基氨基，其中烷氧基部分具有1- 6个碳原子和脲基; R2和R3各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，酰氨基和脲基的成员; R5和R8各自独立地表示选自氢，卤素，具有1-6个碳原子的低级烷基和具有1-6个碳原子的低级烷氧基的成员; 并且R 6和R 7为具有1-6个碳原子的低级烷基，条件是（a）当R 6和R 7均表示甲基时，R 1和R 4中的一个必须表示选自氨基，低级烷基 氨基，其中烷基部分具有1-6个碳原子，其中烷基部分具有1-6个碳原子的低级氨基甲酰基烷基氨基，其中烷基部分具有1-6个碳原子的低级羟烷基氨基和脲基，或（2）R1和 R4代表酰基氨基，R2和R3不同时为氢，（b）当R6和R7都表示乙基时，R2和R3不是叔丁基。 所述二苯胺用于染色角蛋白纤维的染料组合物中。

    Indoanilines, process for producing the same and keratinic fiber dye composition containing the same
    84.
    发明授权
    Indoanilines, process for producing the same and keratinic fiber dye composition containing the same 失效
    联苯胺，其生产方法和含有它们的角质纤维染料组合物

    公开(公告)号：US4248591A

    公开(公告)日：1981-02-03

    申请号：US43892

    申请日：1979-05-30

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/26 ,  A61K7/13

    CPC分类号： A61Q5/10 ,  A61K8/413 ,  C07C275/26

    摘要： Indoaniline of the formula ##STR1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylmaino, hydroxy alkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye copositions for keratinic fibers, especially living human hair.

    摘要翻译： 式（I）的吲哚苯胺其中R1代表氢，卤素，烷基或烷氧基; R2和R3表示烷基; R 4，R 5和R 6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R5也可以表示氨基，烷基亚氨基，羟基烷基氨基或氨基甲酰基烷基氨基，上述烷基和烷氧基能够含有1至6个碳原子 和2〜7个碳原子的酰基，其中R5不代表氢，氯，甲基或甲氧基，当R5表示乙酰氨基时，R6不代表氢; 应当理解，上述化合物可以以由式（I）表示的互变异构体形式存在。 吲哚苯胺有效地用于角蛋白纤维，特别是活人的头发的染料组合物中。

    4,4'-Disubstituted diphenylamines and the use thereof in dye composition for keratinic fibers
    85.
    发明授权
    4,4'-Disubstituted diphenylamines and the use thereof in dye composition for keratinic fibers 失效
    4,4'-二取代二苯胺及其在角质纤维染料组合物中的应用

    公开(公告)号：US4222958A

    公开(公告)日：1980-09-16

    申请号：US797807

    申请日：1977-05-17

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C07C275/40 ,  C07C127/19 ,  C07C91/40 ,  C07C103/127

    CPC分类号： A61K8/415 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/40 ,  Y10S424/01 ,  Y10S424/02

    摘要： Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, amino, lower alkyl amino, acylamino, lower carbamylalkyl amino, lower hydroxyalkyl amino, lower carbalkoxy amino and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, acylamino and ureido;R.sub.5 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy;R.sub.6 represents a member selected from the group consisting of lower hydroxyalkyl, lower amino alkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamylalkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower mono alkyl lower amino alkyl and lower dialkyl lower amino alkyl; andR.sub.7 represents a member selected from the group consisting of lower alkyl, lower hydroxyalkyl, lower aminoalkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamyl alkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower monoalkyl lower amino alkyl and lower dialkyl lower amino alkyl, each of said alkyl and alkoxy moieties containing 1-6 carbon atoms and each of said acyl moieties representing R--CO-- wherein R is selected from the group consisting of an aliphatic and aromatic group.The said diphenylamine is usefully employed in a dye composition for dyeing keratinic fibers.

    摘要翻译： 其中R 1和R 4各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，氨基，低级烷基氨基，酰氨基，低级氨基甲酰基烷基氨基，低级羟烷基氨基，低级烷氧基 氨基和脲基; R2和R3各自独立地表示选自氢，卤素，低级烷基，低级烷氧基，酰氨基和脲基的成员; R5表示选自氢，卤素，低级烷基和低级烷氧基的成员; R6代表选自低级羟烷基，低级氨基烷基，低级酰氨基烷基，下甲磺酰氨基烷基，低级氨基甲酰基烷基，低级磺基烷基，低级哌啶子基烷基，低级吗啉代烷基，低级单烷基低级氨基烷基和低级二烷基低级氨基烷基的成员。 并且R 7表示选自低级烷基，低级羟烷基，低级氨基烷基，低级酰氨基烷基，下甲磺酰氨基烷基，低级氨基甲酰基烷基，低级磺基烷基，低级哌啶子基烷基，低级吗啉代烷基，低级单烷基低级氨基烷基和低级二烷基低级 氨基烷基，所述烷基和烷氧基部分各自含有1-6个碳原子，并且每个所述酰基部分代表R-CO-，其中R选自脂族和芳族基团。 所述二苯胺可用于染色角质纤维的染料组合物中。

    Dye composition containing oxidation dye and diphenylamine
    86.
    发明授权
    Dye composition containing oxidation dye and diphenylamine 失效
    含有氧化染料和二苯胺的染料组合物

    公开(公告)号：US4200432A

    公开(公告)日：1980-04-29

    申请号：US853813

    申请日：1977-11-21

    申请人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    发明人： Gregoire Kalopissis ,  Andree Bugaut ,  Francoise Estradier

    IPC分类号： A61K8/41 ,  A61Q5/10 ,  C09B53/02 ,  A61K7/13

    CPC分类号： C09B53/02 ,  A61K8/413 ,  A61Q5/10

    摘要： A hair dye composition comprising at least one oxidation dye and at least one diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, acylamino or ureido;R.sub.2 and R.sub.3 each independently represent hydrogen, halogen, lower alkyl having 1-6 carbon atoms, lower alkoxy having 1-6 carbon atoms, amino, N-alkylamino wherein the alkyl has 1-6 carbon atoms, N-hydroxyalkylamino wherein the alkyl has 1-6 carbon atoms, acylamino, N-carbamylalkylamino wherein the alkyl has 1-6 carbon atoms or ureido;R.sub.5 represents hydrogen, halogen, lower alkyl having 1-6 carbon atoms or lower alkoxy having 1-6 carbon atoms;R.sub.6, R.sub.7 and R.sub.8, each independently represent hydrogen, halogen, lower alkyl having 1-6 carbon atoms or lower alkoxy having 1-6 carbon atoms;Y represents hydroxy or amino; andZ represents hydroxy or ##STR2## wherein R.sub.9 and R.sub.10 each independently represents hydrogen, lower alkyl containing 1-6 carbon atoms, hydroxyalkyl containing 1-6 carbon atoms, carbamyl alkyl wherein the alkyl has 1-6 carbon atoms, amino alkyl wherein the alkyl has 1-6 carbon atoms, monoalkylamino alkyl wherein each alkyl has 1-6 carbon atoms, dialkylamino alkyl wherein each alkyl has 1-6 carbon atoms, acylaminoalkyl wherein the alkyl has 1-6 carbon atoms, alkylsulfonamido alkyl wherein each alkyl has 1-6 carbon atoms, arylsulfonamidoalkyl wherein the alkyl has 1-6 carbon atoms, sulfoalkyl wherein the alkyl has 1-6 carbon atoms, piperidinoalkyl wherein the alkyl has 1-6 carbon atoms or morpholinoalkyl wherein the alkyl has 1-6 carbon atoms; ora salt thereof.

    摘要翻译： 一种染发剂组合物，其包含至少一种氧化染料和至少一种下式的二苯胺：其中R 1和R 4各自独立地表示氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基， 酰氨基或脲基; R2和R3各自独立地表示氢，卤素，具有1-6个碳原子的低级烷基，具有1-6个碳原子的低级烷氧基，氨基，其中烷基具有1-6个碳原子的N-烷基氨基，其中烷基具有 1-6个碳原子，酰氨基，N-氨基甲酰基烷基氨基，其中烷基具有1-6个碳原子或脲基; R5表示氢，卤素，具有1-6个碳原子的低级烷基或具有1-6个碳原子的低级烷氧基; R6，R7和R8各自独立地表示氢，卤素，具有1-6个碳原子的低级烷基或具有1-6个碳原子的低级烷氧基; Y表示羟基或氨基; 并且Z表示羟基或者其中R9和R10各自独立地表示氢，含有1-6个碳原子的低级烷基，含有1-6个碳原子的羟基烷基，其中烷基具有1-6个碳原子的氨基甲酰基烷基，其中 烷基具有1-6个碳原子，其中每个烷基具有1-6个碳原子的一烷基氨基烷基，其中每个烷基具有1-6个碳原子的二烷基氨基烷基，其中烷基具有1-6个碳原子的酰氨基烷基，烷基亚磺酰氨基烷基，其中每个烷基具有1个 -6个碳原子，其中烷基具有1-6个碳原子的芳基亚磺酰氨基烷基，其中烷基具有1-6个碳原子的磺基烷基，其中烷基具有1-6个碳原子的哌啶子基烷基或其中烷基具有1-6个碳原子的吗啉代烷基; 或其盐。