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    Processes for the preparation of n-butyraldehyde, n-butanol and mixtures thereof
    81.
    发明授权
    Processes for the preparation of n-butyraldehyde, n-butanol and mixtures thereof 失效
    制备正丁醛，正丁醇及其混合物的方法

    公开(公告)号：US6166265A

    公开(公告)日：2000-12-26

    申请号：US381452

    申请日：1999-09-15

    申请人： Jurgen Kanand ,  Rocco Paciello ,  Michael Roper

    发明人： Jurgen Kanand ,  Rocco Paciello ,  Michael Roper

    IPC分类号： C07C27/06 ,  C07B61/00 ,  C07C29/132 ,  C07C31/12 ,  C07C41/06 ,  C07C41/32 ,  C07C41/54 ,  C07C45/51 ,  C07C47/02

    CPC分类号： C07C29/132 ,  C07C41/06 ,  C07C41/32 ,  C07C41/54 ,  C07C45/515 ,  C07C31/12 ,  C07C47/02 ,  C07C43/15 ,  C07C43/303

    摘要： Process for the preparation of n-butyraldehyde and/or n-butanol, whereina) 1,3-Butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of the formula IROH I, where R is C.sub.2 -C.sub.20 -alkyl or alkenyl which is unsubstituted or substituted by 1 or 2 C.sub.1 -C.sub.10 -alkoxy or hydroxyl groups, or is C.sub.6 -C.sub.10 -aryl, C.sub.7 -C.sub.11 -aralkyl or methyl, at elevated temperatures and superatmospheric pressure in the presence of a Bronsted acid or in the presence of a complex of an element of Group Ia, VIIA or VIIIA of the Periodic Table of Elements with phosphorus- or nitrogen-containing ligands to give a mixture of the adducts of the formulae II ##STR1## and III ##STR2## b) the adduct III is isomerized to the adduct II, c) the adduct II is converted into the acetal of the formula IV ##STR3## d) n-butyraldehyde and/or n-butanol are then produced from this acetal IV by reacting it, in the liquid phase, with hydrogen and water or water in the presence of a homogeneous or heterogeneous transition metal catalyst which differs from dicobaltoctacarbonyl or hydridocobalttetracarbonyl.

    摘要翻译： PCT No.PCT / EP98 / 01324 Sec。 371日期1999年9月15日 102（e）1999年9月15日PCT 1998年3月6日PCT PCT。 第WO98 / 41494号公报 日期1998年9月24日制备正丁醛和/或正丁醇的方法，其中a）1,3-丁二烯或含丁二烯的烃混合物与式IROHI的醇反应，其中R是C2- C 1 -C 10 - 芳基，C 7 -C 11 - 芳烷基或甲基未被取代或被1或2个C 1 -C 10 - 烷氧基或羟基取代的C 1 -C 20 - 烷基或烯基，在高温和超大气压的存在下， Br + E，uml + EE ed ed ed ed ed acid acid the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the the 式II和III b）加合物III异构化为加合物II，c）加合物II转化为式IV的缩醛d）然后由该缩醛IV由该缩醛IV制备正丁醛和/或正丁醇，通过使 在液相中，在均相或不均匀转变的存在下，用氢和水或水进行反应 金属催化剂不同于二羰基羰基或氢化钴四羰基。

    Preparation of alcohols and/or aldehydes
    83.
    发明授权
    Preparation of alcohols and/or aldehydes 失效
    醇和/或醛的制备

    公开(公告)号：US5919987A

    公开(公告)日：1999-07-06

    申请号：US716216

    申请日：1996-09-13

    申请人： Heinz-Josef Kneuper ,  Maik Aron ,  Frank-Michael Korgitzsch ,  Michael Nilles ,  Wolfgang Harder ,  Michael Roper ,  Rocco Paciello

    发明人： Heinz-Josef Kneuper ,  Maik Aron ,  Frank-Michael Korgitzsch ,  Michael Nilles ,  Wolfgang Harder ,  Michael Roper ,  Rocco Paciello

    IPC分类号： B01J23/46 ,  B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  C07C29/16 ,  C07C31/02 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/235 ,  C07C209/00 ,  C07C45/00

    CPC分类号： B01J31/20 ,  B01J31/4046 ,  C07C209/00 ,  C07C29/141 ,  C07C29/16 ,  C07C45/50 ,  C07C45/80 ,  C07C51/235 ,  B01J2231/321 ,  B01J23/464 ,  B01J2531/822 ,  B01J31/181 ,  B01J31/1815 ,  B01J31/1825 ,  B01J31/183 ,  Y02P20/584

    摘要： An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180.degree. C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180.degree. C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.

    摘要翻译： PCT No.PCT / EP95 / 00825 Sec。 371日期1996年9月13日 102（e）日期1996年9月13日PCT 1995年3月6日PCT公布。 WO95 / 25080 PCT公开 日期1995年9月21日通过在50至1000巴的压力和50至180℃的温度下通过烯烃反应物的催化加氢甲酰化来工业制备大于3个碳原子的烯烃的醛和/或醇。 在均匀溶解在反应介质中的未络合的铑催化剂存在下进行。 保持铑的催化活性，首先通过含氮络合剂如磺化或羧化吡啶，喹啉等的水溶液从最初排出的反应混合物中提取铑的催化活性。 在加氢甲酰化反应中重复使用的复合铑的再循环中，含水铑萃取物进料到预羰化阶段，其中在基本上不溶于水的有机液体存在下进行所需的预羰基化， 一氧化碳，合成气或含有一氧化碳的另一种气体混合物，从50至1000巴和50至180℃。然后将从该预羰化阶段排出的混合物分离成含有主要部分铑的有机相， 相含有络合剂。 然后将所得到的含再生催化剂的含铑有机相进料到加氢甲酰化阶段以完成其再循环。

    Preparation of aldehydes
    85.
    发明授权
    Preparation of aldehydes 失效
    醛的制备

    公开(公告)号：US5696297A

    公开(公告)日：1997-12-09

    申请号：US510540

    申请日：1995-08-02

    申请人： Heinz-Josef Kneuper ,  Rocco Paciello ,  Michael Roper

    发明人： Heinz-Josef Kneuper ,  Rocco Paciello ,  Michael Roper

    IPC分类号： C07C45/50 ,  C07C45/80

    CPC分类号： C07C45/50 ,  C07C45/80

    摘要： Aldehydes or aldehydes and alcohols are prepared by hydroformylation of olefins of more than 3 carbon atoms by a process comprising the stage of hydroformylation by means of a rhodium catalyst homogeneously dissolved in the reaction medium, the separation of the rhodium catalyst from the discharge from the hydroformylation reaction and the recycling of the rhodium separated from the hydroformylation discharge to the hydroformylation stage, wherein the rhodium catalyst is extracted from the hydroformylation discharge into the aqueous phase by means of an aqueous solution of a water-soluble, phosphorus-containing complexing agent selected from the group consisting of the mono- or polysulfonated mono- and oligophosphines and/or from the group consisting of the mono- or polycarboxylated mono- or oligophosphines or the mono- or polysulfonated oligophosphites and the aldehyde or the aldehyde and the alcohol are isolated from the extracted hydroformylation discharge, the aqueous rhodium-containing extract is fed to a precarbonylation stage and is subjected to a precarbonylation in the precarbonylation stage in the presence of an essentially water-insoluble, organic liquid and in the presence of carbon monoxide or of a carbon monoxide-containing gas mixture.

    摘要翻译： 醛或醛和醇通过包括通过均匀溶解在反应介质中的铑催化剂的加氢甲酰化阶段的方法加氢甲酰化大于3个碳原子的烯烃来制备，铑催化剂与加氢甲酰化的分离 反应和从加氢甲酰化放电分离出的铑的再循环到加氢甲酰化阶段，其中通过水溶性含磷络合剂的水溶液将铑催化剂从加氢甲酰化排放物中提取到水相中，所述水溶性含磷络合剂选自 由单或多羧基单 - 和寡膦组成的组和/或由单羧酸或多羧基单 - 或寡膦或单磺酸或多磺酸的低聚亚磷酸酯和醛或醛和醇组成的组分离自 提取加氢甲酰化放电，含水铑 将入料提取物进料至预羰化阶段，并在基本上不溶于水的有机液体和一氧化碳或含一氧化碳的气体混合物存在下，在预羰化阶段进行预羰基化。