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206 条记录 (耗时 0.027 秒)

    Organic compound conversion with ammonium hydroxide and alkali metal aluminate treated zeolite
    82.
    发明授权
    Organic compound conversion with ammonium hydroxide and alkali metal aluminate treated zeolite 失效
    用氢氧化铵和碱金属铝酸盐处理的沸石的有机化合物转化

    公开(公告)号：US4780194A

    公开(公告)日：1988-10-25

    申请号：US910244

    申请日：1986-09-18

    申请人： Clarence D. Chang ,  Joseph N. Miale

    发明人： Clarence D. Chang ,  Joseph N. Miale

    IPC分类号： B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C10G11/05 ,  C07C1/24 ,  C10G47/20 ,  C10G49/08

    CPC分类号： B01J29/40 ,  B01J29/65 ,  B01J29/70

    摘要： This invention relates to acid catalysis, e.g. cracking, of organic compound feedstock, e.g. hydrocarbons, over catalyst material treated in a special way for increasing the acid catalytic activity thereof. In particular, a novel catalyst activation process is followed to enhance the alpha value of high-silica zeolite catalyst by contact with an ammoniacal solution of ammonium hydroxide and an alkali metal aluminate under appropriate conditions of time, temperature of pH.

    摘要翻译： 本发明涉及酸催化，例如 有机化合物原料的裂化，例如。 碳氢化合物，以特殊方式处理以提高其酸催化活性的催化剂材料。 特别地，遵循新的催化剂活化方法，以在适当的时间，pH温度条件下，通过与铵氢氧化铵和碱金属铝酸盐的氨溶液接触来提高高二氧化硅沸石催化剂的α值。

    Catalytic conversion
    84.
    发明授权
    Catalytic conversion 失效
    催化转化

    公开(公告)号：US4645864A

    公开(公告)日：1987-02-24

    申请号：US818968

    申请日：1986-01-08

    申请人： Clarence D. Chang ,  Joseph N. Miale

    发明人： Clarence D. Chang ,  Joseph N. Miale

    IPC分类号： B01J29/04 ,  C01B39/02 ,  C07C1/20 ,  C07C11/20

    CPC分类号： C01B39/026 ,  B01J29/04 ,  C01B35/1009

    摘要： A method for increasing the total amount of lattice metal in the framework of a particular porous inorganic crystalline composition, its conversion to hydrogen or hydronium form and use thereof as a catalyst component having enhanced catalytic activity for conversion of oxygenates to hydrocarbons is provided.

    摘要翻译： 提供了一种在特定的多孔无机结晶组合物的骨架中增加晶格金属总量的方法，其转化为氢或水合物形式，并且其用作催化剂组分的用途，其具有提高的含氧化合物转化为烃的催化活性。

    Hydrolysis of olefin oxides to glycols
    87.
    发明授权
    Hydrolysis of olefin oxides to glycols 失效
    将烯烃氧化物水解成二醇

    公开(公告)号：US4620044A

    公开(公告)日：1986-10-28

    申请号：US787931

    申请日：1985-10-16

    申请人： Clarence D. Chang ,  Stuart D. Hellring

    发明人： Clarence D. Chang ,  Stuart D. Hellring

    IPC分类号： B01J29/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/10 ,  C07C41/02 ,  C07C43/11 ,  C07C67/00 ,  C07C35/14

    CPC分类号： C07C41/02 ,  C07C29/106 ,  C07B2200/09 ,  C07C2101/14 ,  Y02P20/52

    摘要： Hydrolysis of olefin oxides to their corresponding glycols was catalyzed by a steam stable zeolite, in its acid form, characterized by a constraint index within the range of about 1 to 12. Conversions of olefin oxide, in the presence of water, proceeded with minimal catalyst degradation. The acidity of the zeolite enabled the use of milder conditions than generally applied for this hydrolysis with no loss of desired selectivity. In addition, the described procedure offered the advantages typically associated with a heterogeneous catalyst (e.g., ease of separation, use of fixed bed reactor, etc.).

    摘要翻译： 将烯烃氧化物水解成其相应的二醇是通过其酸形式的蒸气稳定沸石催化的，其特征在于约1至12范围内的约束指数。在水存在下，烯烃氧化物的转化以最小催化剂 降解。 沸石的酸度使得能够使用比通常用于该水解的温和条件，而不损失所需的选择性。 此外，所描述的方法提供了通常与非均相催化剂相关的优点（例如，易于分离，使用固定床反应器等）。

    Catalysis over activated high silica zeolites
    90.
    发明授权
    Catalysis over activated high silica zeolites 失效
    催化活性高的二氧化硅沸石

    公开(公告)号：US4540840A

    公开(公告)日：1985-09-10

    申请号：US668352

    申请日：1984-11-05

    申请人： Joseph N. Miale ,  Clarence D. Chang

    发明人： Joseph N. Miale ,  Clarence D. Chang

    IPC分类号： B01J29/40 ,  C07C1/20

    CPC分类号： B01J29/40 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42

    摘要： A process is provided for conducting organic compound conversion over a catalyst composition comprising a supported crystalline zeolite having a high initial silica-to-alumina mole ratio, said supported zeolite being prepared by compositing said crystalline zeolite with a support matrix material, calcining the resulting supported zeolite, contacting said calcined supported zeolite with volatile boron fluoride in a dry environment until said supported zeolite is saturated with said boron fluoride, purging unreacted boron fluoride from said boron fluoride contacted supported zeolite, hydrolyzing said boron fluoride contacted supported zeolite, and converting said hydrolyzed material to hydrogen form.

    摘要翻译： 提供了一种用于通过催化剂组合物进行有机化合物转化的方法，所述催化剂组合物包含具有高初始二氧化硅 - 氧化铝摩尔比的负载型结晶沸石，所述负载型沸石是通过将所述结晶沸石与载体基质材料进行复合而制备的， 沸石，在干燥环境下将所述煅烧的负载型沸石与挥发性氟化硼接触，直到所述负载的沸石被所述氟化硼饱和，从所述氟化硼接触的负载型沸石中吹扫未反应的氟化硼，水解所述氟化硼接触的负载型沸石，并将所述水解的 材料为氢形式。