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    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE
    82.
    发明申请
    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE 有权
    制备十六烷基-2-丁基的方法

    公开(公告)号：US20110288348A1

    公开(公告)日：2011-11-24

    申请号：US13110974

    申请日：2011-05-19

    申请人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

    发明人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

    IPC分类号： C07C17/357

    CPC分类号： C07C17/354 ,  C07C17/23 ,  C07C17/37 ,  C07C21/22 ,  C07C21/18 ,  C07C21/09

    摘要： Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF3CX═CXCF3, where X=halogen; and (b) treating CF3CX═CXCF3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF3CX═CXCF3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF3CX═CHCF3 is greatly reduced or eliminated.

    摘要翻译： 公开了制备六氟-2-丁炔的方法，包括以下步骤：（a）提供包含CF 3 C X = CXCF 3的组合物，其中X =卤素; 和（b）在卤素受体化合物Y的存在下，用脱卤催化剂处理CF 3 C X = C X CF 3，其中Y不是氢。 卤素受体化合物Y是能够被卤化的物质，优选具有多重键的化合物，如炔烃，烯烃，烯烃或一氧化碳。 能够被卤化的另一种合适的材料是环丙烷。 催化剂有效地将卤素从CF 3 C X = C x CF 3转移到卤素受体化合物。 由于Y不是氢，所以CF 3 C X = CHCF 3的形成大大降低或消除。

    Chloro- And Bromo-Fluoro Olefin Compounds Useful As Organic Rankine Cycle Working Fluids
    83.
    发明申请
    Chloro- And Bromo-Fluoro Olefin Compounds Useful As Organic Rankine Cycle Working Fluids 有权
    氯和氟氟烯烃化合物可用作有机兰金循环工作液

    公开(公告)号：US20100139274A1

    公开(公告)日：2010-06-10

    申请号：US12630647

    申请日：2009-12-03

    申请人： Gary Zyhowski ,  Ryan Hulse ,  Haridasan K. Nair ,  David Nalewajek ,  Rajiv R. Singh

    发明人： Gary Zyhowski ,  Ryan Hulse ,  Haridasan K. Nair ,  David Nalewajek ,  Rajiv R. Singh

    IPC分类号： F01K25/08 ,  F01K23/02 ,  F01K23/08 ,  C07C21/18

    CPC分类号： C09K5/048 ,  C07B2200/09 ,  C07C21/18 ,  C09K5/045 ,  C09K2205/126 ,  F01K25/06 ,  F01K25/08

    摘要： Aspects of the present invention are directed to working fluids and their use in processes wherein the working fluids comprise compounds having the structure of formula (I): wherein R1, R2, R3, and R4 are each independently selected from the group consisting of: H, F, Cl, Br, and C1-C6 alkyl, at least C6 aryl, at least C3 cycloalkyl, and C6-C15 alkylaryl optionally substituted with at least one F, Cl, or Br, wherein formula (I) contains at least one F and at least one Cl or Br, provided that if any R is Br, then the compound does not have hydrogen. The working fluids are useful in Rankine cycle systems for efficiently converting waste heat generated from industrial processes, such as electric power generation from fuel cells, into mechanical energy or further to electric power. The working fluids of the invention are also useful in equipment employing other thermal energy conversion processes and cycles.

    摘要翻译： 本发明的方面涉及工作流体及其在工作流体中的用途，其中工作流体包含具有式（I）结构的化合物：其中R 1，R 2，R 3和R 4各自独立地选自：H ，F，Cl，Br和C 1 -C 6烷基，至少C 6芳基，至少C 3环烷基和任选被至少一个F，Cl或Br取代的C 6 -C 15烷基芳基，其中式（I）含有至少一个 F和至少一个Cl或Br，条件是如果任何R是Br，则化合物不具有氢。 工作流体在兰金循环系统中有用，可有效地将工业过程产生的废热（如燃料电池的发电）转化为机械能或进一步电力。 本发明的工作流体也可用于采用其它热能转换过程和循环的设备中。

    Novel photoresist monomers and polymers
    85.
    发明申请
    Novel photoresist monomers and polymers 审中-公开
    新型光致抗蚀剂单体和聚合物

    公开(公告)号：US20060008731A1

    公开(公告)日：2006-01-12

    申请号：US10888746

    申请日：2004-07-09

    申请人： Michael Van Der Puy ,  Jingji Ma ,  Dennis Lavery ,  Lawrence Ford ,  Haridasan Nair ,  David Nalewajek ,  Andrew Poss ,  Leonard Stachura

    发明人： Michael Van Der Puy ,  Jingji Ma ,  Dennis Lavery ,  Lawrence Ford ,  Haridasan Nair ,  David Nalewajek ,  Andrew Poss ,  Leonard Stachura

    IPC分类号： G03C1/492

    CPC分类号： C07C23/27 ,  C07C17/30 ,  G03F7/0046 ,  G03F7/0395

    摘要： Monomers and polymers useful for forming photoresists. More particularly, photoresists, as well as monomers and polymers for photoresists useful in micro-lithography, specifically monomers bearing acid-labile groups of reduced optical density. The resulting photoresists exhibit improved transparency to 157 nm light. The photoresist compositions are composed of a mixture of at least one water insoluble, acid decomposable polymer which is prepared from at least one monomer having a monomeric unit structure which comprises: where Hal=F, Cl or Br and X=H or F; and which is substantially transparent to ultraviolet radiation at a wavelength of about 157 nm, and at least one photoacid generator capable of generating an acid upon exposure to sufficient activating energy at a wavelength of about 157 nm.

    摘要翻译： 用于形成光致抗蚀剂的单体和聚合物。 更具体地，光致抗蚀剂以及用于微光刻的光致抗蚀剂的单体和聚合物，特别是带有降低光密度的酸不稳定基团的单体。 所得到的光致抗蚀剂显示出对157nm光的改善的透明度。 光致抗蚀剂组合物由至少一种不溶于水的可酸分解聚合物的混合物组成，该聚合物由至少一种具有单体单元结构的单体制备，其中Hal = F，Cl或Br，X = H或F; 并且其对于约157nm的波长的紫外线辐射是基本上透明的，以及至少一种能够在暴露于约157nm的波长的足够活化能时产生酸的光酸产生剂。

    Continuous production of chlorodifluoroacetyl fluoride via chlorotrifluoroethylene oxidation
    86.
    发明申请
    Continuous production of chlorodifluoroacetyl fluoride via chlorotrifluoroethylene oxidation 审中-公开
    通过氯三氟乙烯氧化连续生产氯二氟乙酰氟

    公开(公告)号：US20050113606A1

    公开(公告)日：2005-05-26

    申请号：US10718475

    申请日：2003-11-20

    申请人： Robert Bell ,  Timothy Demmin ,  David Bradley ,  David Nalewajek

    发明人： Robert Bell ,  Timothy Demmin ,  David Bradley ,  David Nalewajek

    IPC分类号： C07C51/21 ,  C07C51/58

    CPC分类号： C07C51/58 ,  C07C53/48

    摘要： The invention pertains to a process for preparing chlorodifluoroacetyl fluoride (CDAF) by oxidation of chlorotrifluoroethylene (CTFE) in a solvent using a continuously stirred tank reactor. It provides a process for the production of chlorodifluoroacetyl fluoride by comprises reacting a solvent solution of chlorotrifluoroethylene with oxygen in a reactor to form a product which comprises chlorodifluoroacetyl fluoride. The reacting may be conducted in a continuous or batch mode.

    摘要翻译： 本发明涉及通过使用连续搅拌釜式反应器在溶剂中氧化三氟氯乙烯（CTFE）来制备氯二氟乙酰氟（CDAF）的方法。 它提供了一种生产氯二氟乙酰氟的方法，包括在反应器中使氯三氟乙烯的溶剂溶液与氧反应形成包含氯二氟乙酰氟的产物。 反应可以以连续或间歇的方式进行。

    Process of making fluorinated alcohols
    89.
    发明授权
    Process of making fluorinated alcohols 失效
    制备氟化醇的方法

    公开(公告)号：US06673976B1

    公开(公告)日：2004-01-06

    申请号：US10247383

    申请日：2002-09-19

    申请人： Haridasan K. Nair ,  David Nalewajek ,  Andrew Poss

    发明人： Haridasan K. Nair ,  David Nalewajek ,  Andrew Poss

    IPC分类号： C07C3134

    CPC分类号： C07C29/44 ,  C07C31/34 ,  C07C31/38

    摘要： Provided are methods of producing fluorinated alcohols from non-perfluorinated fluoroolefins and methanol. Certain preferred embodiments of such methods involve advantageously reacting a non-perfluorinated fluoroolefin with methanol under ambient-pressure and/or low-temperature conditions.

    摘要翻译： 提供从非全氟化氟烯烃和甲醇制备氟化醇的方法。 这些方法的某些优选实施方案涉及在环境压力和/或低温条件下有利地使非全氟化氟烯烃与甲醇反应。

    Process for producing fluoroolefins
    90.
    发明授权
    Process for producing fluoroolefins 有权
    制备氟烯烃的方法

    公开(公告)号：US06548719B1

    公开(公告)日：2003-04-15

    申请号：US09962974

    申请日：2001-09-25

    申请人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland

    发明人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland

    IPC分类号： C07C1725

    CPC分类号： C07C17/04 ,  C07C17/25 ,  C07C19/14 ,  C07C21/18

    摘要： A process for producing a fluoroolefin of the formula: CF3CY═CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C(R1aR2b)C(R3cR4d), wherein R1, R2, R3, and R4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R1, R2, R3, and R4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olef in is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.

    摘要翻译： 制备下式的氟代烯烃的方法：CF 3 CY = CXnHp其中Y是氢原子或卤素原子（即氟，氯，溴或碘）; X是氢原子或卤素原子（即氟，氯，溴或碘）; n和p是独立地等于0,1或2的整数，条件是（n + p）= 2; 包括在相转移催化剂存在下使下式化合物：其中R 1，R 2，R 3和R 4独立地为氢原子或选自以下的卤素：式中：CF 3 C（R 1a R 2b）C（R 3 c R 4d） 氟，氯，溴和碘，条件是R 1，R 2，R 3和R 4中的至少一个是卤素，并且在相邻碳原子上具有至少一个氢和一个卤素; a和b独立地为0,1或2，（a + b）= 2; 且c和d独立地为0,1,2或3和（c + d）= 3; 和至少一种碱金属氢氧化物。 碱金属氢氧化物可以是例如氢氧化钾或氢氧化钠，相转移催化剂可以是例如至少一种：冠醚如18-冠-6和15-冠-5; 或鎓盐如季鏻盐和季铵盐。 烯烃可用作例如生产其它工业化学品的中间体，以及用作生产低聚物和聚合物的单体。