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    Process for producing fluoroolefins
    1.
    发明授权
    Process for producing fluoroolefins 有权
    制备氟烯烃的方法

    公开(公告)号：US06548719B1

    公开(公告)日：2003-04-15

    申请号：US09962974

    申请日：2001-09-25

    申请人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland

    发明人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland

    IPC分类号： C07C1725

    CPC分类号： C07C17/04 ,  C07C17/25 ,  C07C19/14 ,  C07C21/18

    摘要： A process for producing a fluoroolefin of the formula: CF3CY═CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C(R1aR2b)C(R3cR4d), wherein R1, R2, R3, and R4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R1, R2, R3, and R4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olef in is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.

    摘要翻译： 制备下式的氟代烯烃的方法：CF 3 CY = CXnHp其中Y是氢原子或卤素原子（即氟，氯，溴或碘）; X是氢原子或卤素原子（即氟，氯，溴或碘）; n和p是独立地等于0,1或2的整数，条件是（n + p）= 2; 包括在相转移催化剂存在下使下式化合物：其中R 1，R 2，R 3和R 4独立地为氢原子或选自以下的卤素：式中：CF 3 C（R 1a R 2b）C（R 3 c R 4d） 氟，氯，溴和碘，条件是R 1，R 2，R 3和R 4中的至少一个是卤素，并且在相邻碳原子上具有至少一个氢和一个卤素; a和b独立地为0,1或2，（a + b）= 2; 且c和d独立地为0,1,2或3和（c + d）= 3; 和至少一种碱金属氢氧化物。 碱金属氢氧化物可以是例如氢氧化钾或氢氧化钠，相转移催化剂可以是例如至少一种：冠醚如18-冠-6和15-冠-5; 或鎓盐如季鏻盐和季铵盐。 烯烃可用作例如生产其它工业化学品的中间体，以及用作生产低聚物和聚合物的单体。

    Photochlorination of 1,1,1,3,3-pentafluoropropane
    2.
    发明授权
    Photochlorination of 1,1,1,3,3-pentafluoropropane 有权
    1,1,1,3,3-五氟丙烷的光氯化

    公开(公告)号：US06551469B1

    公开(公告)日：2003-04-22

    申请号：US09994438

    申请日：2001-11-27

    申请人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland ,  Martin E. Cheney

    发明人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland ,  Martin E. Cheney

    IPC分类号： C07C1700

    CPC分类号： C07C17/10 ,  C07C19/10

    摘要： A process for preparing 1-chloro-1,1,3,3,3-pentafluoropropane, CF3CH2CF2Cl, comprising contacting in a reaction zone in the substantial absence of oxygen, reactants comprising chlorine and 1,1,1,3,3-pentafluoropropane, CF3CH2CHF2 (also referred to as HFC-245fa), and subjecting the reactants to actinic radiation, such as UV light at about 2,000 to 4,000 Angstroms, wherein: (1) inert gas is present at a concentration equal to or less than about 5 wt. % of the total weight of reactants; (2) the molar ratio of chlorine to CF3CH2CHF2 is from about 0.2:1 to about 1.5:1; and (3) the concentration of chlorinated product produced having greater than one chlorine present in the molecule is less than or equal to about 10 wt. %.

    摘要翻译： 制备1-氯-1,1,3,3,3-五氟丙烷CF 3 CH 2 CF 2 Cl的方法，包括在基本不存在氧的反应区中接触，包含氯的反应物和1,1,1,3,3-五氟丙烷 ，CF 3 CH 2 CHF 2（也称为HFC-245fa），并使反应物进行光化辐射，例如约2,000至4,000埃的紫外光，其中：（1）惰性气体的存在浓度等于或小于约5 重量 反应物总重量的百分比; （2）氯与CF 3 CH 2 CHF 2的摩尔比为约0.2:1至约1.5:1; 和（3）分子中存在的具有大于一个氯的氯化产物的浓度小于或等于约10wt。 ％。

    Continuous process for the production of vinylidene chloride telomers
    4.
    发明授权
    Continuous process for the production of vinylidene chloride telomers 失效
    用于生产偏二氯乙烯调节剂的连续方法

    公开(公告)号：US5633413A

    公开(公告)日：1997-05-27

    申请号：US512575

    申请日：1995-08-08

    申请人： Michael Van Der Puy ,  Timothy R. Demmin ,  David E. Bradley

    发明人： Michael Van Der Puy ,  Timothy R. Demmin ,  David E. Bradley

    IPC分类号： C07C17/278 ,  C07C17/08 ,  C07C17/266 ,  C07C17/275

    CPC分类号： C07C17/278

    摘要： A process for the continuous production of telomers CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.n Cl where n=1-3 (Formula I) by the continuous reaction of CCl.sub.4 and vinylidene chloride in the presence of a solvent and a catalyst. The reaction to form CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl proceeds at a reaction rate constant k.sub.1. If n=1, CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl is continuously removed from the reactor. If n=2, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacts similarly with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 in a second reactor to form and remove CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl under conditions to have a reaction rate constant k.sub.2, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacted is greater than the ratio k.sub.2 /k.sub.1. If n=3, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl similarly reacts in a third reactor with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 to form CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.3 Cl under conditions to have a reaction rate constant k.sub.3, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl reacted is greater than the ratio k.sub.3 /k.sub.2.

    摘要翻译： 在溶剂和催化剂存在下，通过CCl4和偏二氯乙烯的连续反应连续生产调节剂CCl 3（CH 2 Cl 2）n Cl，其中n = 1-3（式I）的方法。 形成CCl 3（CH 2 Cl 2）Cl的反应以反应速率常数k1进行。 如果n = 1，则从反应器中连续除去CCl 3（CH 2 Cl 2））Cl。 如果n = 2，则在第二反应器中除去的CCl 3（CH 2 Cl 2 Cl 2）Cl类似地与CCl 4和CH 2 = CCl 2反应，以在具有反应速率常数k2的条件下形成和除去CCl 3（CH 2 Cl 2）2 Cl，其中摩尔量 的CCl4至CCl3（CH2Cl2）Cl反应的比值大于k2 / k1的比例。 如果n = 3，则除去的CCl 3（CH 2 Cl 2）2 Cl类似地在第三反应器中与CCl 4和CH 2 = CCl 2反应以在具有反应速率常数k 3的条件下形成CCl 3（CH 2 Cl 2）3 Cl，其中CCl 4的摩尔量 至CCl 3（CH 2 Cl 2）2 Cl反应的比例大于k3 / k2的比例。

    .alpha.-Nitrosoketal dimers and production of .alpha.-oximinoketals therefrom
    7.
    发明授权
    .alpha.-Nitrosoketal dimers and production of .alpha.-oximinoketals therefrom 失效
    α-硝基二缩酮二聚体和由其衍生的α-肟基酮

    公开(公告)号：US4206112A

    公开(公告)日：1980-06-03

    申请号：US968935

    申请日：1978-12-13

    申请人： Milorad M. Rogic ,  Michael D. Swerdloff ,  Timothy R. Demmin

    发明人： Milorad M. Rogic ,  Michael D. Swerdloff ,  Timothy R. Demmin

    IPC分类号： C07D317/72 ,  C07J41/00 ,  C07C105/00 ,  C07C131/00

    CPC分类号： C07J41/0016 ,  C07D317/72

    摘要： This invention describes novel ketals of .alpha.-oximinoketones, methods for the preparation of these compounds and includes novel intermediates formed during the production thereof. The novel class of compounds disclosed herein includes both .alpha.-oximinoketals, as well as the cyclic ketals of .alpha.-oximinoketones. This invention also discloses a novel class of .alpha.-nitrosoketal dimers produced during the synthesis of the corresponding .alpha.-oximinoketals, and it also discloses novel methods in the production thereof.

    摘要翻译： 本发明描述了α-肟基酮的新型缩酮，制备这​​些化合物的方法，包括在其制备过程中形成的新型中间体。 本文公开的新一类化合物包括α-肟基酮，以及α-肟基酮的环缩酮。 本发明还公开了在合成相应的α-肟基时产生的一类新的α-亚硝基二酮二聚体，并且还公开了其生产中的新方法。

    Preparation of muconic acid mononitriles and copper(II)-ammonia reagent therefor
    9.
    发明授权
    Preparation of muconic acid mononitriles and copper(II)-ammonia reagent therefor 失效
    制备粘酸单体和铜（II） - 氨试剂

    公开(公告)号：US4335010A

    公开(公告)日：1982-06-15

    申请号：US230761

    申请日：1981-02-02

    申请人： Timothy R. Demmin ,  Milorad M. Rogic

    发明人： Timothy R. Demmin ,  Milorad M. Rogic

    IPC分类号： C01G3/14 ,  C07C57/16 ,  C07C120/00

    CPC分类号： C07C255/00 ,  C01G3/14

    摘要： Substituted and unsubstituted phenols, catechols and orthobenzoquinones are converted to muconic acid mononitriles by reaction with copper(II)-ammonia reagents. The copper(II)-ammonia reagents can be prepared by the reaction of cuprous chloride with oxygen or air in liquid ammonia or in ammonium hydroxide or in pyridine followed by addition of ammonia or ammonium hydroxide. The muconic acid mononitriles are useful as monomers or comonomers and as intermediates in the manufacture of substituted and unsubstituted 6-aminocaproic acids, caprolactams and polyamides.

    摘要翻译： 通过与铜（II） - 氨试剂的反应将取代和未取代的酚，儿茶酚和邻苯醌被转化成粘康酸单腈。 铜（II） - 氨试剂可以通过氯化亚铜与氧气或空气在液氨或氢氧化铵或吡啶中反应，然后加入氨或氢氧化铵来制备。 粘康酸单腈可用作单体或共聚单体，也可用作制备取代和未取代的6-氨基己酸，己内酰胺和聚酰胺的中间体。

    Copper (II) reagent and preparation thereof
    10.
    发明授权
    Copper (II) reagent and preparation thereof 失效
    铜（II）试剂及其制备

    公开(公告)号：US4208341A

    公开(公告)日：1980-06-17

    申请号：US1990

    申请日：1979-01-08

    申请人： Timothy R. Demmin ,  Milorad M. Rogic

    发明人： Timothy R. Demmin ,  Milorad M. Rogic

    IPC分类号： C01G3/02 ,  C07F1/00 ,  C08G73/26 ,  C07F1/08

    CPC分类号： C01G3/02 ,  C07F1/005 ,  C08G73/26

    摘要： Muconic acid monoesters of alkanediols of 2-6 carbons and of phenol are prepared by copper (II) oxidative cleavage of phenols, catechols or orthobenzoquinones. The products are useful as comonomers in polyamides and other polymers. The alkanediol or phenol is introduced into the copper (II) reactant or catalyst.

    摘要翻译： 通过酚，邻苯二酚或邻苯醌的铜（II）氧化裂解制备2-6个碳原子和酚的烷二醇的粘蛋白酸单酯。 该产品可用作聚酰胺和其它聚合物中的共聚单体。 将链烷二醇或苯酚引入到铜（II）反应物或催化剂中。