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    Process for producing fluoroolefins
    1.
    发明授权
    Process for producing fluoroolefins 有权
    制备氟烯烃的方法

    公开(公告)号：US06548719B1

    公开(公告)日：2003-04-15

    申请号：US09962974

    申请日：2001-09-25

    申请人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland

    发明人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland

    IPC分类号： C07C1725

    CPC分类号： C07C17/04 ,  C07C17/25 ,  C07C19/14 ,  C07C21/18

    摘要： A process for producing a fluoroolefin of the formula: CF3CY═CXnHp wherein Y is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); X is a hydrogen atom or a halogen atom (i.e., fluorine, chlorine, bromine or iodine); n and p are integers independently equal to 0, 1 or 2, provided that (n+p)=2; comprising contacting, in the presence of a phase transfer catalyst, a compound of the formula: CF3C(R1aR2b)C(R3cR4d), wherein R1, R2, R3, and R4 are independently a hydrogen atom or a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, provided that at least one of R1, R2, R3, and R4 is halogen and there is at least one hydrogen and one halogen on adjacent carbon atoms; a and b are independently=0, 1 or 2 and (a+b)=2; and c and d are independently=0, 1, 2 or 3 and (c+d)=3; and at least one alkali metal hydroxide. The alkali metal hydroxide can be, for example, potassium or sodium hydroxide and the phase transfer catalyst can be, for example, at least one: crown ether such as 18-crown-6 and 15-crown-5; or onium salt such as, quaternary phosphonium salt and quaternary ammonium salt. The olef in is useful, for example, as an intermediate for producing other industrial chemicals and as a monomer for producing oligomers and polymers.

    摘要翻译： 制备下式的氟代烯烃的方法：CF 3 CY = CXnHp其中Y是氢原子或卤素原子（即氟，氯，溴或碘）; X是氢原子或卤素原子（即氟，氯，溴或碘）; n和p是独立地等于0,1或2的整数，条件是（n + p）= 2; 包括在相转移催化剂存在下使下式化合物：其中R 1，R 2，R 3和R 4独立地为氢原子或选自以下的卤素：式中：CF 3 C（R 1a R 2b）C（R 3 c R 4d） 氟，氯，溴和碘，条件是R 1，R 2，R 3和R 4中的至少一个是卤素，并且在相邻碳原子上具有至少一个氢和一个卤素; a和b独立地为0,1或2，（a + b）= 2; 且c和d独立地为0,1,2或3和（c + d）= 3; 和至少一种碱金属氢氧化物。 碱金属氢氧化物可以是例如氢氧化钾或氢氧化钠，相转移催化剂可以是例如至少一种：冠醚如18-冠-6和15-冠-5; 或鎓盐如季鏻盐和季铵盐。 烯烃可用作例如生产其它工业化学品的中间体，以及用作生产低聚物和聚合物的单体。

    Photochlorination of 1,1,1,3,3-pentafluoropropane
    2.
    发明授权
    Photochlorination of 1,1,1,3,3-pentafluoropropane 有权
    1,1,1,3,3-五氟丙烷的光氯化

    公开(公告)号：US06551469B1

    公开(公告)日：2003-04-22

    申请号：US09994438

    申请日：2001-11-27

    申请人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland ,  Martin E. Cheney

    发明人： Haridasan K. Nair ,  Michael Van Der Puy ,  David Nalewajek ,  Timothy R. Demmin ,  Andrew J. Poss ,  David E. Bradley ,  Ian R. Shankland ,  Martin E. Cheney

    IPC分类号： C07C1700

    CPC分类号： C07C17/10 ,  C07C19/10

    摘要： A process for preparing 1-chloro-1,1,3,3,3-pentafluoropropane, CF3CH2CF2Cl, comprising contacting in a reaction zone in the substantial absence of oxygen, reactants comprising chlorine and 1,1,1,3,3-pentafluoropropane, CF3CH2CHF2 (also referred to as HFC-245fa), and subjecting the reactants to actinic radiation, such as UV light at about 2,000 to 4,000 Angstroms, wherein: (1) inert gas is present at a concentration equal to or less than about 5 wt. % of the total weight of reactants; (2) the molar ratio of chlorine to CF3CH2CHF2 is from about 0.2:1 to about 1.5:1; and (3) the concentration of chlorinated product produced having greater than one chlorine present in the molecule is less than or equal to about 10 wt. %.

    摘要翻译： 制备1-氯-1,1,3,3,3-五氟丙烷CF 3 CH 2 CF 2 Cl的方法，包括在基本不存在氧的反应区中接触，包含氯的反应物和1,1,1,3,3-五氟丙烷 ，CF 3 CH 2 CHF 2（也称为HFC-245fa），并使反应物进行光化辐射，例如约2,000至4,000埃的紫外光，其中：（1）惰性气体的存在浓度等于或小于约5 重量 反应物总重量的百分比; （2）氯与CF 3 CH 2 CHF 2的摩尔比为约0.2:1至约1.5:1; 和（3）分子中存在的具有大于一个氯的氯化产物的浓度小于或等于约10wt。 ％。

    Process for the preparation of hexafluoro-2-butyne
    3.
    发明授权
    Process for the preparation of hexafluoro-2-butyne 有权
    制备六氟-2-丁炔的方法

    公开(公告)号：US08524955B2

    公开(公告)日：2013-09-03

    申请号：US13110974

    申请日：2011-05-19

    申请人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

    发明人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

    IPC分类号： C07C17/093

    CPC分类号： C07C17/354 ,  C07C17/23 ,  C07C17/37 ,  C07C21/22 ,  C07C21/18 ,  C07C21/09

    摘要： Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF3CX═CXCF3, where X=halogen; and (b) treating CF3CX═CXCF3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF3CX═CXCF3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF3CX═CHCF3 is greatly reduced or eliminated.

    摘要翻译： 公开了制备六氟-2-丁炔的方法，包括以下步骤：（a）提供包含CF 3 C X = CXCF 3的组合物，其中X =卤素; 和（b）在卤素受体化合物Y的存在下用脱卤催化剂处理CF 3 C X = CXCF 3，其中Y不是氢。 卤素受体化合物Y是能够被卤化的物质，优选具有多重键的化合物，如炔烃，烯烃，烯烃或一氧化碳。 能够被卤化的另一种合适的材料是环丙烷。 催化剂有效地将卤素从CF 3 C X = CXCF 3转移到卤素受体化合物。 由于Y不是氢，CF3CX = CHCF3的形成大大降低或消除。

    Process for cis 1,1,1,4,4,4-hexafluoro-2-butene
    4.
    发明授权
    Process for cis 1,1,1,4,4,4-hexafluoro-2-butene 有权
    顺式1,1,1,4,4,4-六氟-2-丁烯的方法

    公开(公告)号：US08901360B2

    公开(公告)日：2014-12-02

    申请号：US13110979

    申请日：2011-05-19

    申请人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy

    发明人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy

    IPC分类号： C07C21/18 ,  C07C17/278 ,  C07C17/04 ,  C07C17/20 ,  C07C17/23 ,  C07C17/25 ,  C07C17/354

    CPC分类号： C07C17/278 ,  C07C17/04 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C17/354 ,  C07C19/10 ,  C07C21/22 ,  C07C21/18

    摘要： Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluorobutene comprising the steps of (a) reacting CCl4 with a compound having the formula CF3CX═CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF3CXClCXHCCl3; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF3CXHCXHCF3; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF3C≡CCF3; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula:

    摘要翻译： 公开了一种制备顺式-1,1,1,4,4,4-六氟丁烯的方法，包括以下步骤：（a）使CCl4与具有式CF 3 C X = C X H的化合物反应，其中每个X独立地为卤素或氢， 形成式CF3CXClCXHCCl3的化合物; （b）氟化步骤（a）中形成的化合物以形成具有式CF 3 C XHCXHCF 3的化合物; （c）通过选自脱卤化氢，脱卤和两种反应的反应转化步骤（b）中形成的化合物，以形成具有式CF 3C≡CCF3的化合物; 和（d）用氢气将步骤（c）中形成的化合物催化还原以形成具有下式的化合物：

    PROCESS FOR CIS 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE
    7.
    发明申请
    PROCESS FOR CIS 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE 有权
    CIS 1,1,1,4,4,4-HEXAFLOROR-2-BUTENE的方法

    公开(公告)号：US20110288346A1

    公开(公告)日：2011-11-24

    申请号：US13110979

    申请日：2011-05-19

    申请人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy

    发明人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy

    IPC分类号： C07C17/354

    CPC分类号： C07C17/278 ,  C07C17/04 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C17/354 ,  C07C19/10 ,  C07C21/22 ,  C07C21/18

    摘要： Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluoropropene comprising the steps of (a) reacting CCl4 with a compound having the formula CF3CX═CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF3CXClCXHCCl3; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF3CXHCXHCF3; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF3C≡CCF3; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula:

    摘要翻译： 公开了一种制备顺式-1,1,1,4,4,4-六氟丙烯的方法，包括以下步骤：（a）使CCl4与具有式CF 3 C X = C X H的化合物反应，其中每个X独立地为卤素或氢， 形成式CF3CXClCXHCCl3的化合物; （b）氟化步骤（a）中形成的化合物以形成具有式CF 3 C XHCXHCF 3的化合物; （c）通过选自脱卤化氢，脱卤和两种反应的反应转化步骤（b）中形成的化合物，以形成具有式CF 3C≡CCF3的化合物; 和（d）用氢气将步骤（c）中形成的化合物催化还原以形成具有下式的化合物：

    Process for the preparation of fluorinated cis-alkene
    8.
    发明授权
    Process for the preparation of fluorinated cis-alkene 有权
    氟化顺式烯烃的制备方法

    公开(公告)号：US08604257B2

    公开(公告)日：2013-12-10

    申请号：US13110998

    申请日：2011-05-19

    申请人： Andrew Joseph Poss ,  Michael Van Der Puy ,  Rajiv Ratna Singh ,  David Nalewajek ,  Haridasan K. Nair

    发明人： Andrew Joseph Poss ,  Michael Van Der Puy ,  Rajiv Ratna Singh ,  David Nalewajek ,  Haridasan K. Nair

    IPC分类号： C07C17/266

    CPC分类号： C07C17/23 ,  C07B2200/09 ,  C07C17/10 ,  C07C17/206 ,  C07C17/278 ,  C07C21/18 ,  C07C19/10

    摘要： Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).

    摘要翻译： 公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。 还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含 顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。

    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE
    10.
    发明申请
    PROCESS FOR THE PREPARATION OF HEXAFLUORO-2-BUTYNE 有权
    制备十六烷基-2-丁基的方法

    公开(公告)号：US20110288348A1

    公开(公告)日：2011-11-24

    申请号：US13110974

    申请日：2011-05-19

    申请人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

    发明人： Andrew Joseph Poss ,  David Nalewajek ,  Haridasan K. Nair ,  Michael Van Der Puy ,  Rajiv Ratna Singh

    IPC分类号： C07C17/357

    CPC分类号： C07C17/354 ,  C07C17/23 ,  C07C17/37 ,  C07C21/22 ,  C07C21/18 ,  C07C21/09

    摘要： Disclosed is a process for making hexafluoro-2-butyne comprising the steps of: (a) providing a composition comprising CF3CX═CXCF3, where X=halogen; and (b) treating CF3CX═CXCF3 with a dehalogenation catalyst in the presence of a halogen acceptor compound Y, where Y is not hydrogen. The halogen acceptor compound Y is a material capable of being halogenated, preferably a compound having a multiple bond, such as an alkyne, alkene, allene, or carbon monoxide. Another suitable material capable of being halogenated is a cyclopropane. A catalyst effectively transfers halogen from CF3CX═CXCF3 to the halogen acceptor compound. Since Y is not hydrogen, the formation of CF3CX═CHCF3 is greatly reduced or eliminated.

    摘要翻译： 公开了制备六氟-2-丁炔的方法，包括以下步骤：（a）提供包含CF 3 C X = CXCF 3的组合物，其中X =卤素; 和（b）在卤素受体化合物Y的存在下，用脱卤催化剂处理CF 3 C X = C X CF 3，其中Y不是氢。 卤素受体化合物Y是能够被卤化的物质，优选具有多重键的化合物，如炔烃，烯烃，烯烃或一氧化碳。 能够被卤化的另一种合适的材料是环丙烷。 催化剂有效地将卤素从CF 3 C X = C x CF 3转移到卤素受体化合物。 由于Y不是氢，所以CF 3 C X = CHCF 3的形成大大降低或消除。