公开(公告)号：US5415768A

公开(公告)日：1995-05-16

申请号：US194609

申请日：1994-02-10

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/08 ,  B01D15/00 ,  B01J47/08 ,  C02F1/00 ,  C02F1/46 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96

CPC classification number: G01N30/6069 ,  B01D15/36 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6091 ,  G01N30/6095 ,  G01N30/80

Abstract: A flow-through capacitor and a controlled charge chromatography column system using the capacitor for the purification of a fluid-containing material, which column comprises an inlet for a fluid to be purified and an outlet for the discharge of the purified fluid, and a flow-through capacitor disposed within the column. The flow-through capacitor comprises a plurality of spirally-wound, stacked washer or rods to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to one side of the backing layer, such as carbon fibers, and a second high surface area conductive layer secured to the opposite side of the backing layer, the high surface area material layers arranged to face each other and separated by a nonconductive, ion-permeable spacer layer to insulate electrically the backing and conductive layer. The system includes a DC power source to charge the respective conductive layers with different polarities whereby a fluid-containing material passing through the column is purified by the electrically conductive, high surface area stationary phase and the retention thereof onto the high surface area layer and permitting, for example, the purification of aqueous solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种流通电容器和使用电容器的受控电荷色谱柱系统，用于净化含流体的材料，该柱包括用于待净化的流体的入口和用于排出纯化流体的出口， 通过电容器设置在该列内。 流通电容器包括多个螺旋卷绕的层叠的垫圈或杆，以包括第一导电背衬层，例如石墨，以及固定到背衬层的一侧的第一高表面积导电层，例如 碳纤维和固定到背衬层的相对侧的第二高表面积导电层，高表面积材料层布置为彼此面对并由不导电的离子可渗透间隔层隔开，以使背衬和导电 层。 该系统包括一个直流电源，用于以不同的极性对相应的导电层进行充电，由此通过该柱的含流体的材料被导电的高表面积固定相净化，并将其保留在高表面积层上并允许 例如，纯化诸如盐的液体的水溶液，并提供回收纯化液体。

公开(公告)号：US5360540A

公开(公告)日：1994-11-01

申请号：US27699

申请日：1993-03-08

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/00 ,  B01D15/08 ,  B01J47/08 ,  C02F1/00 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96

CPC classification number: B01J47/08 ,  B01D15/08 ,  B01D15/3885 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/6069 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/6043 ,  G01N30/6091 ,  G01N30/80

Abstract: A controlled charge chromatography column for the purification of a fluid-containing material, which column comprises a chromatographic column having an inlet for the introduction of a fluid to be purified and an outlet for the discharge of the purified fluid, and one or more concentrated materials and a flow-through capacitor disposed within the column between the inlet and the outlet, the flow-through capacitor means comprising a plurality of spirally wound or stacked washer layers to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to the backing layer, such as composed of porous carbon fibers and a non-conductive, porous spacer layer to electrically insulate the backing and conductive layer and to permit the flow of material therethrough, the flow-through capacitor to be connected to a DC power source to charge the respective conductive layers with different polarities whereby a fluid containing material through the column is purified by the electrically conductive stationary phase and the retention thereof onto the high surface area layer and permitting for example the purification of solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种用于纯化含液体材料的受控电荷色谱柱，该色谱柱包括具有用于引入待纯化流体的入口和用于排出纯化流体的出口的色谱柱，以及一种或多种浓缩物质 以及设置在入口和出口之间的柱内的流通电容器，所述流通电容器装置包括多个螺旋卷绕或堆叠的垫圈层，以包括第一导电背衬层，例如石墨，以及第一 固定到背衬层的高表面积导电层，例如由多孔碳纤维和非导电多孔间隔层组成，以使背衬和导电层电绝缘并允许材料流过其中，流过电容器 连接到DC电源以对具有不同极性的各个导电层​​充电，由此含有流体 通过该柱由导电固定相纯化，并将其保留在高表面积层上，并且允许例如净化诸如盐的液体溶液，并提供纯化液体的回收。

公开(公告)号：US5196115A

公开(公告)日：1993-03-23

申请号：US760752

申请日：1991-09-16

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/00 ,  B01D15/08 ,  B01J47/08 ,  C02F1/00 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96

CPC classification number: G01N30/6069 ,  B01D15/08 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/96 ,  B01D15/36 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/6043 ,  G01N30/80

Abstract: A controlled charge chromatography column for the purification of a fluid containing materials, which column comprises a chromatographic column having an inlet for the introduction of a fluid to be purified and an outlet for the discharge of the purified fluid, and one or more concentrated materials and a flow-through capacitor disposed within the column between the inlet and the outlet, the flow-through capacitor means comprising a plurality of spirally wound, spaced apart layers to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to the backing layer, such as composed of porous carbon fibers and a non-conductive, porous spacer layer to electrically insulate the backing and conductive layer and to permit the flow of material therethrough, the flow-through capacitor to be connected to a DC power source to charge the respective conductive layers with different polarities whereby a fluid containing material through the column is purified by the electrically conductive stationary phase and the retention thereof onto the high surface area layer and permitting for example the purification of solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种用于净化含有液体材料的受控电荷色谱柱，该色谱柱包括具有用于引入待纯化流体的入口和用于排出纯化流体的出口的色谱柱，以及一种或多种浓缩物质和 流过电容器，设置在入口和出口之间的塔内，流通电容器装置包括多个螺旋缠绕的间隔开的层，以包括第一导电背衬层，例如石墨，第一高度 固定到背衬层的表面积导电层，例如由多孔碳纤维和非导电多孔间隔层组成，以使背衬和导电层电绝缘并允许材料流过其中，流通电容器为 连接到DC电源以对具有不同极性的各导电层充电，由此含有流体的材料 通过该柱由导电固定相纯化，并将其保留在高表面积层上，并允许例如净化液体溶液如盐，并提供纯化液体的回收。

公开(公告)号：US5192432A

公开(公告)日：1993-03-09

申请号：US792902

申请日：1991-11-15

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/00 ,  B01D15/08 ,  B01J47/08 ,  C02F1/00 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96

CPC classification number: G01N30/6069 ,  B01D15/08 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/6043 ,  G01N30/80

Abstract: A controlled charge chromatography column for the purification of a fluid containing materials, which column comprises a chromatographic column having an inlet for the introduction of a fluid to be purified and an outlet for the discharge of the purified fluid, and one or more concentrated materials and a flow-through capacitor disposed within the column between the inlet and the outlet, the flow-through capacitor means comprising a plurality of spirally wound, spaced apart layers to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to the backing layer, such as composed of porous carbon fibers and a non-conductive, porous spacer layer to electrically insulate the backing and conductive layer and to permit the flow of material therethrough, the flow-through capacitor to be connected to a DC power source to charge the respective conductive layers with different polarities whereby a fluid containing material through the column is purified by the electrically conductive stationary phase and the retention thereof onto the high surface area layer and permitting for example the purification of solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种用于净化含有液体材料的受控电荷色谱柱，该色谱柱包括具有用于引入待纯化流体的入口和用于排出纯化流体的出口的色谱柱，以及一种或多种浓缩物质和 流过电容器，设置在入口和出口之间的塔内，流通电容器装置包括多个螺旋缠绕的间隔开的层，以包括第一导电背衬层，例如石墨，第一高度 固定到背衬层的表面积导电层，例如由多孔碳纤维和非导电多孔间隔层组成，以使背衬和导电层电绝缘并允许材料流过其中，流通电容器为 连接到DC电源以对具有不同极性的各导电层充电，由此含有流体的材料 通过该柱由导电固定相纯化，并将其保留在高表面积层上，并允许例如净化液体溶液如盐，并提供纯化液体的回收。

公开(公告)号：US5779891A

公开(公告)日：1998-07-14

申请号：US834259

申请日：1997-04-15

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: C02F1/46 ,  B01D15/00 ,  B01D35/06 ,  B01J47/08 ,  C02F1/00 ,  C02F1/469 ,  C25B9/10 ,  G01N30/02 ,  G01N30/46 ,  G01N30/50 ,  G01N30/60 ,  G01N30/96 ,  B01D15/08

CPC classification number: C02F1/4691 ,  B01D15/00 ,  B01J47/08 ,  G01N30/50 ,  G01N30/6069 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/461 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6095

Abstract: A foul-resistant, flow-through capacitor, a system employing the capacitor and a method of separation is disclosed wherein the capacitor has at least one anode and cathode electrode pair. The electrodes are formed of high surface area, electrically conductive material and have an open, preferably straight, fluid flow-through path. Typically, the flow path is formed by a plurality of straight, parallel, spaced apart electrodes with the flow path not greater than one of the X-Y-Z distance components of the capacitor. The flow-through capacitor avoids fouling in use and may be employed with saturated waste or other streams.

Abstract translation: 公开了一种防污流通电容器，采用电容器的系统和分离方法，其中电容器具有至少一个阳极和阴极电极对。 电极由高表面积的导电材料形成并且具有开放的，优选直的流体流通路径。 通常，流动路径由多个直的，平行的间隔开的电极形成，流动路径不大于电容器的X-Y-Z距离分量中的一个。 流通电容器避免使用中的结垢，并且可以与饱和废物或其它流一起使用。

公开(公告)号：US5620597A

公开(公告)日：1997-04-15

申请号：US541880

申请日：1995-10-10

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: C02F1/46 ,  B01D15/00 ,  B01D35/06 ,  B01J47/08 ,  C02F1/00 ,  C02F1/469 ,  C25B9/10 ,  G01N30/02 ,  G01N30/46 ,  G01N30/50 ,  G01N30/60 ,  G01N30/96 ,  B01D15/08

CPC classification number: C02F1/4691 ,  B01D15/00 ,  B01J47/08 ,  G01N30/50 ,  G01N30/6069 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/461 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6095

Abstract: A foul-resistant, flow-through capacitor, a system employing the capacitor and a method of separation is disclosed wherein the capacitor has at least one anode and cathode electrode pair. The electrodes are formed of high surface area, electrically conductive material and have an open, preferably straight, fluid flow-through path. Typically, the flow path is formed by a plurality of straight, parallel, spaced apart electrodes with the flow path not greater than one of the X-Y-Z distance components of the capacitor. The flow-through capacitor avoids fouling in use and may be employed with saturated waste or other streams.

Abstract translation: 公开了一种防污流通电容器，采用电容器的系统和分离方法，其中电容器具有至少一个阳极和阴极电极对。 电极由高表面积的导电材料形成并且具有开放的，优选直的流体流通路径。 通常，流动路径由多个直的，平行的间隔开的电极形成，流动路径不大于电容器的X-Y-Z距离分量中的一个。 流通电容器避免使用中的结垢，并且可以与饱和废物或其它流一起使用。

公开(公告)号：US5200068A

公开(公告)日：1993-04-06

申请号：US819828

申请日：1992-01-13

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/08 ,  B01D15/00 ,  B01J47/08 ,  C02F1/00 ,  C02F1/46 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96 ,  H01G9/00 ,  H01G11/00 ,  H01G11/40 ,  H01G11/42 ,  H01G11/68

CPC classification number: G01N30/50 ,  B01D15/36 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/6069 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6091 ,  G01N30/6095 ,  G01N30/80

Abstract: A controlled charge chromatography column for the purification of a fluid-containing material, which column comprises a chromatographic column having an inlet for the introduction of a fluid to be purified and an outlet for the discharge of the purified fluid, and one or more concentrated materials and a flow-through capacitor disposed within the column between the inlet and outlet, the flow-through capacitor means comprising a plurality of spirally wound or stacked washer layers to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to the backing layer, such as composed of porous carbon fibers and a non-conductive, porous spacer layer to electrically insulate the backing and conductive layer and to permit the flow of material therethrough, the flow-through capacitor to be connected to a DC power source to charge the respective conductive layers with different polarities whereby a fluid containing material through the colum is purified by the electrically conductive stationary phase and the retention thereof onto the high surface area layer and permitting for example the purification of solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种用于纯化含液体材料的受控电荷色谱柱，该色谱柱包括具有用于引入待纯化流体的入口和用于排出纯化流体的出口的色谱柱，以及一种或多种浓缩物质 以及设置在入口和出口之间的柱内的流通电容器，所述流通电容器装置包括多个螺旋卷绕或堆叠的垫圈层，以包括第一导电背衬层，例如石墨，以及第一高度 固定到背衬层的表面积导电层，例如由多孔碳纤维和非导电多孔间隔层组成，以使背衬和导电层电绝缘并允许材料流过其中，流通电容器为 连接到DC电源以对具有不同极性的各导电层充电，由此含有流体的材料 通过导管将导电固定相纯化，并将其保留在高表面积层上，并允许例如净化诸如盐的液体溶液，并提供纯化液体的回收。

公开(公告)号：US6127474A

公开(公告)日：2000-10-03

申请号：US921738

申请日：1997-08-27

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: C08K3/00

CPC classification number: C08K3/0033 ,  C02F1/4691

Abstract: A high tensile strength, fluorocarbon-conductive, particle binder material useful as electrodes in a flow-through capacitor. The material comprises electrodes formed from fibrillated fine fibers, conductive carbon particles and a small amount of a polymeric binder. The method includes admixing the materials, fibrillating the polymers, and extruding the material to electrode forms.

Abstract translation: 用作流通电容器中的电极的高拉伸强度，碳氟化合物导电的颗粒粘合剂材料。 该材料包括由原纤化细纤维，导电碳颗粒和少量聚合物粘合剂形成的电极。 该方法包括混合材料，使聚合物原纤化，并将材料挤压成电极形式。

公开(公告)号：US5748437A

公开(公告)日：1998-05-05

申请号：US653832

申请日：1996-05-28

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/08 ,  B01D15/00 ,  B01J47/08 ,  C02F1/00 ,  C02F1/46 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96 ,  H01G4/35

CPC classification number: G01N30/6069 ,  B01D15/36 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6091 ,  G01N30/6095 ,  G01N30/80

Abstract: A flow-through capacitor and a controlled charge chromatography column system using the capacitor for the purification of a fluid-containing material, which column comprises an inlet for a fluid to be purified and an outlet for the discharge of the purified fluid, and a flow-through capacitor disposed within the column. The flow-through capacitor comprises a plurality of spirally-wound, stacked washer or rods to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to one side of the backing layer, such as carbon fibers, and a second high surface area conductive layer secured to the opposite side of the backing layer, the high surface area material layers arranged to face each other and separated by a nonconductive, ion-permeable spacer layer to insulate electrically the backing and conductive layer. The system includes a DC power source to charge the respective conductive layers with different polarities whereby a fluid-containing material passing through the column is purified by the electrically conductive, high surface area stationary phase and the retention thereof onto the high surface area layer and permitting, for example, the purification of aqueous solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种流通电容器和使用电容器的受控电荷色谱柱系统，用于净化含流体的材料，该柱包括用于待净化的流体的入口和用于排出纯化流体的出口， 通过电容器设置在该列内。 流通电容器包括多个螺旋卷绕的层叠的垫圈或杆，以包括第一导电背衬层，例如石墨，以及固定到背衬层的一侧的第一高表面积导电层，例如 碳纤维和固定到背衬层的相对侧的第二高表面积导电层，高表面积材料层布置为彼此面对并由不导电的离子可渗透间隔层隔开，以使背衬和导电 层。 该系统包括一个直流电源，用于以不同的极性对相应的导电层进行充电，由此通过该柱的含流体的材料被导电的高表面积固定相净化，并将其保留在高表面积层上并允许 例如，纯化诸如盐的液体的水溶液，并提供回收纯化液体。

公开(公告)号：US5547581A

公开(公告)日：1996-08-20

申请号：US439310

申请日：1995-05-11

Applicant: Marc D. Andelman

Inventor： Marc D. Andelman

IPC: B01D15/08 ,  B01D15/00 ,  B01J47/08 ,  C02F1/00 ,  C02F1/46 ,  C02F1/469 ,  G01N30/02 ,  G01N30/38 ,  G01N30/50 ,  G01N30/60 ,  G01N30/80 ,  G01N30/96

CPC classification number: G01N30/6069 ,  B01D15/36 ,  B01D15/3885 ,  B01J47/08 ,  C02F1/4691 ,  G01N30/50 ,  G01N30/96 ,  C02F2301/024 ,  G01N2030/027 ,  G01N2030/965 ,  G01N30/02 ,  G01N30/38 ,  G01N30/60 ,  G01N30/6043 ,  G01N30/6091 ,  G01N30/6095 ,  G01N30/80

Abstract: A flow-through capacitor and a controlled charge chromatography column system using the capacitor for the purification of a fluid-containing material, which column comprises an inlet for a fluid to be purified and an outlet for the discharge of the purified fluid, and a flow-through capacitor disposed within the column. The flow-through capacitor comprises a plurality of spirally-wound, stacked washer or rods to include a first electrically conductive backing layer, such as of graphite, and a first high surface area conductive layer secured to one side of the backing layer, such as carbon fibers, and a second high surface area conductive layer secured to the opposite side of the backing layer, the high surface area material layers arranged to face each other and separated by a nonconductive, ion-permeable spacer layer to insulate electrically the backing and conductive layer. The system includes a DC power source to charge the respective conductive layers with different polarities whereby a fluid-containing material passing through the column is purified by the electrically conductive, high surface area stationary phase and the retention thereof onto the high surface area layer and permitting, for example, the purification of aqueous solutions of liquids, such as salt, and providing for the recovery of a purified liquid.

Abstract translation: 一种流通电容器和使用电容器的受控电荷色谱柱系统，用于净化含流体的材料，该柱包括用于待净化的流体的入口和用于排出纯化流体的出口， 通过电容器设置在该列内。 流通电容器包括多个螺旋卷绕的层叠的垫圈或杆，以包括第一导电背衬层，例如石墨，以及固定到背衬层的一侧的第一高表面积导电层，例如 碳纤维和固定到背衬层的相对侧的第二高表面积导电层，高表面积材料层布置为彼此面对并由不导电的离子可渗透间隔层隔开，以使背衬和导电 层。 该系统包括一个直流电源，用于以不同的极性对相应的导电层进行充电，由此通过该柱的含流体的材料被导电的高表面积固定相净化，并将其保留在高表面积层上并允许 例如，纯化诸如盐的液体的水溶液，并提供回收纯化液体。