公开(公告)号：US4374021A

公开(公告)日：1983-02-15

申请号：US225927

申请日：1981-01-19

申请人： David B. Bartholic

发明人： David B. Bartholic

IPC分类号： C10G25/09 ,  C10G25/12 ,  C10G55/06

CPC分类号： C10G25/09 ,  C10G2300/107

摘要： An improved process is provided for decarbonizing, demetallizing and/or desalting a hydrocarbon feed stock by: contacting, in a selective vaporization step, for a short hydrocarbon residence time at an elevated contact temperature, the feed stock with an inert solid contact material in a confined rising vertical column to vaporize a major portion of the feed stock and to provide, as combustible deposits on the contact material, an unvaporized minor portion of the feed stock which includes high Conradson Carbon components and/or metal-containing components of the feed stock; separating the vaporized major portion of the feed stock from the contact material bearing the combustible deposits; contacting in a combustion step the contact material, bearing the combustible deposits, with an oxidizing gas to oxidize the combustible deposits and generate heat, whereby the contact material is heated by combustion of the combustible deposits; and recycling the so-heated contact material to contact further feed stock in the selective vaporization step. The improvement in the process comprises:contacting the contact material in the combustion step with less than the stoichiometric amount of oxidizing gas, required to oxidize completely the combustible deposits, so that oxidizable high Conradson Carbon and/or metal-containing components of the combustible deposits are only partially oxidized to carbon monoxide and so that there is a reducing atmosphere in the combustion step.

摘要翻译： 提供了一种改进的方法，用于通过以下步骤脱碳，脱金属和/或脱盐烃原料：在选择性蒸发步骤中，在升高的接触温度下使短暂的烃停留时间接触，所述原料与惰性固体接触材料在 限制上升的立柱以蒸发原料的主要部分，并且作为可接触材料上的可燃沉积物，提供原料的未蒸发的次要部分，其包含高的康拉逊碳组分和/或原料的含金属成分 ; 将原料的蒸发的主要部分与承载可燃沉积物的接触材料分离; 在燃烧步骤中将承载可燃沉积物的接触材料与氧化气体接触以氧化可燃沉积物并产生热量，由此通过燃烧可燃沉积物来加热接触材料; 并且在所述选择性蒸发步骤中回收所述被加热的接触材料以接触另外的原料。 该方法的改进包括：使燃烧步骤中的接触材料与化学计量的化学计量量的氧化气体接触，使氧化完全可燃沉积物所需的氧化气体，使可燃性高的康拉逊碳和/或含金属成分的可燃沉积物 仅部分氧化成一氧化碳，并且在燃烧步骤中存在还原气氛。

公开(公告)号：US4339352A

公开(公告)日：1982-07-13

申请号：US238272

申请日：1981-02-25

申请人： Frank Pitts ,  Jack A. Tiethof ,  Robert A. Burns

发明人： Frank Pitts ,  Jack A. Tiethof ,  Robert A. Burns

IPC分类号： B01J20/12 ,  B01J21/20

CPC分类号： B01J20/12

摘要： A novel sorptive clay product is formed by treating attapulgite clay with sodium silicate and heating to expel moisture such that the product contains about 7-20% total volatile matter. Acid may also be added such that the pH of aqueous slurry is in the range 5 to 10. This sorptive clay product exhibits water and oil absorption and resistance to wet breakdown equivalent to higher-temperature activated attapulgite products.

摘要翻译： 通过用硅酸钠处理绿坡缕石粘土并加热以排出水分使得产物含有约7-20％的总挥发性物质形成新颖的吸附性粘土产品。 还可以加入酸，使得水性浆料的pH在5至10的范围内。该吸附性粘土产品表现出吸水性和吸水性，耐湿分解相当于高温活化的绿坡缕石产品。

公开(公告)号：US4274942A

公开(公告)日：1981-06-23

申请号：US26935

申请日：1979-04-04

申请人： David B. Bartholic ,  Don S. Chin

发明人： David B. Bartholic ,  Don S. Chin

IPC分类号： B01J21/20 ,  C10G11/18

CPC分类号： C10G11/187 ,  B01J21/20 ,  Y02P30/446 ,  Y10S208/01 ,  Y10S502/517

摘要： Process and system are described for control of sulfur oxide in emissions to the atmosphere from regenerators of Fluid Catalytic Cracking Units (FCC) in a manner which improves the operation of the regenerator and/or the reactor. Spent FCC cracking catalyst containing sulfur-bearing inactivating carbonaceous deposit is partially oxidized, preferably in the presence of steam, thereby producing a mixture of CO and CO.sub.2 and releasing sulfur in the resulting reducing atmosphere as vaporous hydrogen sulfide before the catalyst is regenerated, whereby the amount of sulfur convertible to noxious SOx in the regenerator flue gas is reduced. By the disclosed process and system, the quantity of oxygen introduced is predetermined and controlled in response to hydrogen content of the coke on the partially oxidized catalyst or an SOx analyzer associated with the regenerator can be used as a control tool. Preferably, spent catalyst is partially oxidized in the presence of steam in a vessel separate from the regenerator and reactor, whereby the effluent can be utilized as a source of low BTU gas.

摘要翻译： 描述了处理和系统，以改善再生器和/或反应器的操作的方式来控制从流化催化裂化装置（FCC）的再生器排放到大气中的硫氧化物。 含有含硫失活碳质沉积物的废FCC裂解催化剂部分氧化，优选在蒸汽存在下，由此产生CO和CO 2的混合物，并且在催化剂再生之前，在所得的还原气氛中释放出硫化氢作为气态硫化氢， 在再生器烟气中可转化为有害SOx的硫的量减少。 通过公开的方法和系统，引入的氧气的量是预定的并且响应于部分氧化的催化剂上的焦炭的氢含量而被控制，或者可以将与再生器相关联的SOx分析仪用作控制工具。 优选地，废催化剂在与再生器和反应器分离的容器中的蒸汽存在下被部分氧化，由此流出物可以用作低BTU气体的来源。

公开(公告)号：US4256567A

公开(公告)日：1981-03-17

申请号：US79227

申请日：1979-09-26

申请人： David B. Bartholic

发明人： David B. Bartholic

IPC分类号： C10G9/32 ,  C10G21/22 ,  C10G25/09 ,  C10G53/06 ,  C10G55/04 ,  C10G55/06 ,  C10G53/10 ,  C10G53/08

CPC分类号： C10G9/32 ,  C10G2300/107

摘要： Petroleum crudes, residual stocks, gas oils and the like which contain metals are pretreated with a sulfonating agent and the mixture separated into two fractions of which the lesser in volume has a greater concentration of metal and Conradson Carbon components. One or both of those fractions is mixed with a catalytically inert solid at high temperature to transfer metallic compounds and Conradson Carbon components to the solid for improvement of the fraction.

摘要翻译： 含有金属的石油原油，残渣，瓦斯油等用磺化剂预处理，将混合物分成两部分，体积较小，金属和康拉逊碳组分浓度较高。 这些级分中的一种或两种在高温下与催化惰性固体混合以将金属化合物和康拉德森碳组分转移到固体中以改进级分。

公开(公告)号：US4241142A

公开(公告)日：1980-12-23

申请号：US971365

申请日：1978-12-20

申请人： Adam F. Kaliski ,  Richard R. Berube ,  John C. Nease

发明人： Adam F. Kaliski ,  Richard R. Berube ,  John C. Nease

IPC分类号： C09C1/42 ,  D21H19/40 ,  B05D3/02 ,  B05D3/12 ,  B32B23/08 ,  B32B27/10

CPC分类号： C09C1/42 ,  D21H19/40 ,  C01P2004/20 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/10 ,  C01P2006/22 ,  Y10T428/31895 ,  Y10T428/31906 ,  Y10T428/31975

摘要： A novel clay pigment, the manufacture thereof and the use of the pigment in the production of dull and matte-finish coated printing papers. The novel clay pigment comprises a mixture of a coarse-size fraction of naturally-occurring kaolin clay containing a substantial proportion of kaolinite booklets in the particle size range of 2 to 5 .mu.m equivalent spherical diameter (e.s.d.) and mechanically delaminated kaolin platelets in the particle size range of 2 to 10 .mu.m e.s.d.

摘要翻译： 一种新型粘土颜料，其制造方法和颜料在生产无光泽和无光泽涂布印刷纸中的用途。 新型粘土颜料包含粗粒度的天然高岭土的混合物，其中含有相当大比例的高岭土小册子，粒度范围为2至5μm当量球形直径（esd），并且机械分层的高岭土血小板 粒度范围为2〜10微米

公开(公告)号：US4235753A

公开(公告)日：1980-11-25

申请号：US21214

申请日：1979-03-16

申请人： Stanley M. Brown ,  Gerald M. Woltermann

发明人： Stanley M. Brown ,  Gerald M. Woltermann

IPC分类号： B01J20/18 ,  B01J29/08 ,  C10G11/05 ,  B01J29/06

CPC分类号： C10G11/05 ,  B01J20/183 ,  B01J29/08 ,  B01J2229/26 ,  B01J2229/64 ,  Y10S423/22 ,  Y10S423/25

摘要： An improved process for the production of mechanically strong shaped crystalline zeolitic aluminosilicate bodies from precursor bodies composed of kaolin clay calcined at elevated temperature, the crystallized bodies having essentially the same size and shape as the precursor bodies. Conversion of the calcined clay contained in the precursor bodies to a mixture of crystalline zeolitic alluminosilicate component and a porous amorphous silica-alumina component takes place as a result of reaction between the calcined clay and an aqueous alkaline liquid in which the bodies are immersed. The improved process features the presence of a solution of aluminosilicate nucleation centers during such reaction.

摘要翻译： 一种用于在由高温煅烧的高岭土组成的前体体中生产机械强力形状的结晶沸石铝硅酸盐体的改进方法，结晶体具有与前体体基本相同的尺寸和形状。 作为煅烧粘土与浸渍体的水性碱性液体之间的反应的结果，将前驱体中包含的煅烧粘土转化为结晶沸石硅铝酸盐组分和多孔无定形二氧化硅 - 氧化铝组分的混合物。 改进的方法特征在于这种反应期间硅铝酸盐成核中心的溶液的存在。

公开(公告)号：US4229287A

公开(公告)日：1980-10-21

申请号：US966485

申请日：1978-12-04

申请人： Vuko M. Lepetic

发明人： Vuko M. Lepetic

IPC分类号： B03D1/001 ,  B03D1/04

CPC分类号： B03D1/002 ,  B03D1/012 ,  B03D2201/06 ,  B03D2203/02

摘要： Tin values in the form of cassiterite (SnO.sub.2) are recovered from aqueous pulps of finely divided cassiterite-bearing ore, preconcentrate or concentrate by froth flotation. The ore pulps are deslimed thoroughly, partially or not at all. Slimes, gangue or waste minerals in the pulps are selectively depressed by use of a metal salt/silicate reagent combination. The cassiterite is floated at a mildly acidic to neutral pH, generally in the range of about 5 to 6, by one and/or more highly selective tin collectors such as sulfosuccinamates, aspartates, phosphonates, etc., at environmental or, preferably, elevated pulp temperature. Flotation machine impeller speeds are within conventional range or higher, preferably the latter. The cleaning of the thus-produced cassiterite rougher flotation concentrate is performed after an additional (secondary) conditioning step whereby an additional depressant, such as tannic acid, sulfuric acid, sodium fluosilicate, sodium lignin sulfonate or activated charcoal is used.

摘要翻译： 锡石（SnO2）形式的锡值通过泡沫浮选由含细碎矿石，预浓缩物或浓缩物的纸浆中回收。 矿浆完全脱落，部分或不完全脱落。 通过使用金属盐/硅酸盐试剂组合选择性地抑制纸浆中的泥土，脉石或废矿物质。 锡石通过一种和/或多种高度选择性的锡收集剂如磺基琥珀酸盐，天冬氨酸盐，膦酸盐等在温和的酸性至中性pH下漂浮，通常在约5至6的范围内，在环境条件下，或优选升高 纸浆温度。 浮选机叶轮速度在常规范围内或更高，优选后者。 在另外的（二次）调节步骤之后进行如此生产的锡石粗糙浮选精矿的清洗，由此使用另外的抑制剂，如丹宁酸，硫酸，氟硅酸钠，木质素磺酸钠或活性炭。

公开(公告)号：US4214978A

公开(公告)日：1980-07-29

申请号：US042918

申请日：1979-05-29

申请人： James V. Kennedy ,  Lawrence B. Dight

发明人： James V. Kennedy ,  Lawrence B. Dight

IPC分类号： B01J21/16 ,  B01J23/40 ,  B01J29/90 ,  C10G11/05 ,  C10G11/18 ,  C10G11/04 ,  B01J8/24 ,  B01J23/64

CPC分类号： C10G11/05 ,  B01J21/16 ,  B01J23/40 ,  B01J29/90 ,  C10G11/18 ,  Y02P30/446

摘要： A novel particulate material for promoting combustion of carbon monoxide to carbon dioxide in the regeneration zone of a cyclic fluid cracking process without substantially affecting the ability of separate fluid cracking catalyst particles containing an active crystalline zeolitic aluminosilicate component to catalyze the hydrocarbon conversion reaction in the conversion zone. The novel promoter particles comprise coherent, catalytically inert microspheres of calcined kaolin clay having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of about 2/1, a surface area (B.E.T.) in the range of about 10 to 15 m.sup.2 /g., a pore volume (as determined by nitrogen absorption) in the range of about 0.02 to 0.04 cc./g., the calcined microspheres being impregnated with a trace amount of a platinum compound and being free from a component capable of cracking hydrocarbons in the absence of added hydrogen.

摘要翻译： 一种用于在循环流体裂解过程的再生区中促进一氧化碳燃烧到二氧化碳的新型颗粒材料，而基本上不影响包含活性结晶沸石硅铝酸盐组分的分离的流体裂解催化剂颗粒在转化中催化烃转化反应的能力 区。 新型促进剂颗粒包含SiO 2 / Al 2 O 3摩尔比为约2/1，表面积（BET）为约10至15m2 / g范围内的煅烧高岭土的相干，催化惰性微球，孔体积（ 通过氮吸收测定）在约0.02至0.04cc./g的范围内，煅烧微球体被微量铂化合物浸渍，并且在不存在加入氢气的情况下不含能够裂解烃的组分。

公开(公告)号：US4207416A

公开(公告)日：1980-06-10

申请号：US888802

申请日：1978-03-21

申请人： James D. Hoeschele

发明人： James D. Hoeschele

IPC分类号： C07D239/54 ,  C07F15/00 ,  C07H23/00 ,  C07H19/06 ,  C07H19/10

CPC分类号： C07H23/00 ,  C07D239/54 ,  C07F15/0093

摘要： Ethylenediamineplatinum(II) 2,4-dioxopyrimidine complexes are characterized by high anti-tumor activity and low mammalian toxicity.

摘要翻译： 亚乙基二胺（II）2,4-二氧嘧啶配合物的特征在于高抗肿瘤活性和低的哺乳动物毒性。

公开(公告)号：US4200618A

公开(公告)日：1980-04-29

申请号：US15768

申请日：1979-02-28

申请人： Frank Pitts

发明人： Frank Pitts

IPC分类号： C01F5/30

CPC分类号： C01F5/30

摘要： An improved method of preparing magnesium chloride in which magnesium oxide, hydroxide or carbonate or a material containing magnesium oxide is caused to react with waste chlorides produced in the manufacture of titanium tetrachloride and the solution of magnesium chloride so formed is separated from insoluble matter.

摘要翻译： 制备氯化镁的改进方法，其中使氧化镁，氢氧化物或碳酸盐或含有氧化镁的材料与在制造四氯化钛中产生的废氯化物和如此形成的氯化镁溶液反应与不溶物分离。