摘要:
A process is disclosed for passivating the reactivity of contaminant metals, such as nickel and vanadium, which have been deposited on a catalytic cracking catalyst, by adding to the cracking catalyst a mixture of a calcium-containing material and a magnesium-containing material in a separate reactor in the presence of steam. The preferred calcium-containing material is dolomite and the preferred magnesium-containing material is sepiolite. It is also preferred to include antimony and/or bismuth compounds in the additive mixture.
摘要:
Methanation of carbon oxides such as carbon monoxide and carbon dioxide with hydrogen to produce methane is carried out with the aid of a heated catalyst which is the calcination product of a serpentine containing nickel and optionally magnesium and other elements together with silicon in the essentially laminar nickel serpentine. The catalysts exhibit good conversion at relatively low temperatures, are relatively insensitive to high temperature excursions, and have an extended life.
摘要:
A novel particulate material for promoting combustion of carbon monoxide to carbon dioxide in the regeneration zone of a cyclic fluid cracking process without substantially affecting the ability of separate fluid cracking catalyst particles containing an active crystalline zeolitic aluminosilicate component to catalyze the hydrocarbon conversion reaction in the conversion zone. The novel promoter particles comprise coherent, catalytically inert microspheres of calcined kaolin clay having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of about 2/1, a surface area (B.E.T.) in the range of about 10 to 15 m.sup.2 /g., a pore volume (as determined by nitrogen absorption) in the range of about 0.02 to 0.04 cc./gm., the calcined microspheres being impregnated with a trace amount of a platinum compound and being free from a component capable of cracking hydrocarbons in the absence of added hydrogen.
摘要翻译:一种用于在循环流体裂解过程的再生区中促进一氧化碳燃烧到二氧化碳的新型颗粒材料,而基本上不影响包含活性结晶沸石硅铝酸盐组分的分离的流体裂解催化剂颗粒在转化中催化烃转化反应的能力 区。 新型促进剂颗粒包含SiO 2 / Al 2 O 3摩尔比为约2/1,表面积(BET)为约10至15m2 / g范围内的煅烧高岭土的相干,催化惰性微球,孔体积( 通过氮吸收测定)在约0.02至0.04cc./gm的范围内,煅烧微球体用微量的铂化合物浸渍,并且在不存在加入氢气的情况下不含能够裂解烃的组分。
摘要:
A composition useful for processing hydrocarbonaceous feedstocks is disclosed comprising a mixture of a calcium/magnesium-containing material and a magnesium-containing material. The preferred calcium/magnesium-containing material is dolomite and the preferred magnesium-containing material is sepiolite.
摘要:
A process for cracking high metals content feedstocks which comprises contacting said feedstocks under catalytic cracking conditions with a novel catalytic cracking composition comprising a solid cracking catalyst and an alumina diluent.
摘要:
A process for cracking high metals content feedstocks which comprises contacting said charge stock under catalytic cracking conditions with a novel catalytic cracking composition comprising a solid cracking catalyst and a diluent containing a selected magnesium compound or a selected magnesium compound in combination with one or more heat-stable metal compounds.
摘要:
A dual component cracking catalyst system is disclosed comprising zeolite as a first component and a mixture of a calcium/magnesium-containing material and a magnesium-containing material as a second component. The preferred calcium/magnesium-containing material is dolomite and the preferred magnesium-containing material is sepiolite.
摘要:
A process for cracking high metals content feedstocks which comprises contacting said feedstocks under catalytic cracking conditions with a novel catalytic cracking composition comprising a solid cracking catalyst and a magnesium oxide diluent.