公开(公告)号：US07271309B2

公开(公告)日：2007-09-18

申请号：US10477773

申请日：2002-03-26

申请人： Jürgen Eberhardt ,  Walter Boll ,  Henning Buchold ,  Holger Dropsch

发明人： Jürgen Eberhardt ,  Walter Boll ,  Henning Buchold ,  Holger Dropsch

IPC分类号： C07C2/58

CPC分类号： C07C2/58 ,  C07C2529/04

摘要： In the presence of a catalyst, at least one isoparaffin having 4 to 6 C atoms per molecule is reacted with at least one olefin having 2 to 6 C atoms per molecule in a liquid phase to obtain a product containing alkylate, a suspension containing isoparaffin and a granular zeolite catalyst being supplied to the upper region of a reaction column. Below the point where the catalyst-containing suspension is supplied, an isoparaffin-olefin mixture is introduced into the reaction column, the temperatures in the reaction column being maintained in the range from 50 to 120° C. From the bottom region of the reaction column a product mixture containing alkylate is withdrawn, and in a separation by distillation alkylate product is recovered therefrom. Preferably, isoparaffin and catalyst are recovered from the separation by distillation and at least partly recirculated to the upper region of the reaction column.

摘要翻译： 在催化剂的存在下，每分子具有4〜6个C原子的至少一种异构烷烃与至少一种在液相中每分子具有2〜6个C原子的烯烃反应，得到含有烷基化物的产物，含有异链烷烃的悬浮液， 将粒状沸石催化剂供给到反应塔的上部区域。 在提供含催化剂的悬浮液的点之下，将异链烷烃烯烃混合物引入反应塔中，将反应塔中的温度保持在50至120℃。从反应塔底部区域 取出含有烷基化物的产物混合物，并通过蒸馏分离从其中回收烷基化产物。 优选地，通过蒸馏从分离中回收异构烷烃和催化剂，并且至少部分地再循环到反应塔的上部区域。

公开(公告)号：US06953872B1

公开(公告)日：2005-10-11

申请号：US10030802

申请日：2000-05-31

申请人： Ulrich Koss ,  Martin Rothaemel ,  Peter König

发明人： Ulrich Koss ,  Martin Rothaemel ,  Peter König

IPC分类号： C07C4/06 ,  C10G11/00 ,  C10G11/10 ,  C10G70/04

CPC分类号： C10G70/041 ,  C07C4/06 ,  C07C2529/04 ,  C10G2400/20 ,  C07C11/02

摘要： This invention relates to a process of producing C2- to C4-olefins from steam and a feed mixture containing C4- to C8-olefins, wherein the feed mixture containing steam is introduced into a reactor with an inlet temperature of 300 to 700° C., said reactor comprising a bed of granular, form-selective zeolite catalyst, and wherein a product mixture containing steam and C2- to C4-olefins is withdrawn from the bed and is passed through at least one cooling means.

摘要翻译： 本发明涉及一种从蒸汽中生产C2-至C4-烯烃的方法和含有C4- C8-烯烃的进料混合物，其中将含有蒸汽的进料混合物引入入口温度为300-700℃的反应器中 所述反应器包括颗粒形式选择性沸石催化剂床，并且其中含有蒸汽和C 2 -C 4烯烃的产物混合物从床中排出并通过至少一个冷却装置。

公开(公告)号：US20020124690A1

公开(公告)日：2002-09-12

申请号：US10037482

申请日：2002-01-04

申请人： mg technologies ag

发明人： Andreas Orth ,  Martin Hirsch ,  Peter Weber

IPC分类号： C21B011/00

CPC分类号： C21B13/0033 ,  Y02P10/136

摘要： Granular coal and preheated granular iron ore are charged into a low-temperature carbonization reactor, in which temperatures in the range from 800 to 1050 null C. are produced by supplying gas containing oxygen and by partial oxidation of the components of the coal. In the low-temperature carbonization reactor, the granular solids are maintained in a turbulent movement. From the upper region of the reactor, hot exhaust gas is supplied to a solids separator. The granular iron ore is preheated by means of the hot exhaust gas and hot, granular mixture of iron ore and low-temperature coke is withdrawn as product from the reactor and/or from the separator. The low-temperature carbonization reactor may be designed as fluidized-bed reactor or as pneumatic conveyor section. The granular mixture of iron ore and low-temperature coke is suitable e.g. for a melt reduction process.

摘要翻译： 将粒状煤和预热的粒状铁矿石装入低温碳化反应器中，在低温碳化反应器中，通过供给含氧的气体和煤的组分的部分氧化，产生800至1050℃的温度。 在低温碳化反应器中，粒状固体维持在湍流运动中。 从反应器的上部区域向固体分离器供给热废气。 颗粒铁矿石通过热废气预热，铁矿石和低温焦炭的热粒状混合物作为产物从反应器和/或分离器中取出。 低温碳化反应器可以设计为流化床反应器或气动输送机部分。 铁矿石和低温焦炭的颗粒状混合物是合适的。 用于熔融还原过程。

公开(公告)号：US07547428B2

公开(公告)日：2009-06-16

申请号：US10473320

申请日：2002-02-26

申请人： William Davey

发明人： William Davey

IPC分类号： C01C1/04 ,  C01B3/22 ,  C07C273/04

CPC分类号： C01B3/56 ,  C01B3/025 ,  C01B3/323 ,  C01B3/52 ,  C01B3/586 ,  C01B2203/0415 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01C1/0405 ,  Y02P20/52

摘要： Ammonia is catalytically produced from a nitrogen-hydrogen mixture. First of all, a vaporous feed mixture, which comprises 30 to 60 vol-% methanol and 40 to 70 vol-% steam and has a volume ratio steam:methanol of 1 to 3, is passed through at least one bed of a breakdown catalyst at pressures in the range from 30 to 200 bar, the temperatures in the catalyst bed lying in the range from 200 to 500° C. From the catalyst bed, a first gas mixture is withdrawn, which, calculated dry, comprises 40 to 80 vol-% H2 and 10 to 30 vol-% CO2. The first gas mixture is cooled, CO2 is removed in a gas cleaning, and a second gas mixture is generated, which comprises at least 95 vol-% nitrogen and hydrogen, and which is supplied as synthesis gas to an ammonia synthesis for the catalytic production of ammonia.

摘要翻译： 氨由氮 - 氢混合物催化产生。 首先，将包含30至60体积％甲醇和40至70体积％蒸汽并且具有1至3的蒸汽：甲醇的体积比的蒸气进料混合物通过至少一个分解催化剂床 在30至200巴的压力范围内，催化剂床中的温度在200至500℃的范围内。从催化剂床中取出第一气体混合物，其计算干燥，包含40至80体积％ - ％H2和10〜30vol-％CO2。 将第一气体混合物冷却，在气体清洁中除去CO 2，并且产生第二气体混合物，其包含至少95体积％的氮和氢，并且其作为合成气体供应到用于催化生产的氨合成 的氨。

公开(公告)号：US07038065B2

公开(公告)日：2006-05-02

申请号：US10344034

申请日：2001-07-11

申请人： Volker Franz ,  Helmuth Domes

发明人： Volker Franz ,  Helmuth Domes

IPC分类号： C07D305/12

CPC分类号： C07C51/265 ,  C07C51/252 ,  C07C57/04 ,  C07C63/16 ,  C07C63/26

摘要： A process for catalytically generating organic substances by partial oxidation of an organic feedstock in the presence of molecular oxygen at temperatures in the range from 200 to 500° C. in at least one cooling-tube reactor, wherein 40 to 100 wt-% of the total amount of catalyst is disposed as a coating on the outside of the cooling tubes.

摘要翻译： 一种在至少一个冷却管式反应器中，在分子氧存在下在200-500℃范围内的有机原料部分氧化催化产生有机物质的方法，其中40-100重量％ 催化剂的总量作为涂层设置在冷却管的外侧。

公开(公告)号：US06984289B2

公开(公告)日：2006-01-10

申请号：US10179864

申请日：2002-06-25

申请人： Helmuth Domes ,  Thomas Gutermuth ,  Herbert Feisel ,  Lutz Urban

发明人： Helmuth Domes ,  Thomas Gutermuth ,  Herbert Feisel ,  Lutz Urban

IPC分类号： B01D1/14 ,  C07D307/89

CPC分类号： C07D307/89

摘要： Process for generating a homogeneous gas mixture of o-xylene and air for the production of phthalic anhydride wherein o-xylene is completely evaporated in the absence of oxygen, superheated and then mixed with air and supplied to a phthalic anhydride reactor.

摘要翻译： 用于产生邻二甲苯和空气的均匀气体混合物以生产邻苯二甲酸酐的方法，其中邻二甲苯在不存在氧气的情况下完全蒸发，过热，然后与空气混合并供给邻苯二甲酸酐反应器。

公开(公告)号：US06841064B1

公开(公告)日：2005-01-11

申请号：US10148826

申请日：2000-11-16

申请人： Hans-Jürgen Weiss ,  Ingo Dreher ,  Udo Zentner

发明人： Hans-Jürgen Weiss ,  Ingo Dreher ,  Udo Zentner

IPC分类号： C10G7/00 ,  C10B49/20 ,  C10G9/00 ,  C10G9/28 ,  B01D3/06 ,  B01D3/00

CPC分类号： C10B49/20 ,  C10G9/005 ,  C10G9/28

摘要： Residual oil from the processing of crude oil, natural bitumen or oil sand is mixed in a mixer with granular, hot coke as heat carrier (heat carrier coke) in a weight ratio of 1:3 to 1:30, where on the granules of the heat carrier coke there is first of all formed a liquid residue film which partly evaporates in the mixer. Gases and vapors and moist, sticky coke are withdrawn from the mixer. The mixture of coke and residual oil is introduced into a subsequently connected stirred tank in which the mixture slowly moves downwards while being stirred mechanically at a temperature of 450 to 600° C. and preferably at 480 to 550° C. Dry, flowable coke is withdrawn from the stirred tank. Usually, the dwell time of the heat carrier coke in the stirred tank is 1 to 30 minutes.

摘要翻译： 来自加工原油，天然沥青或油砂的残余油在混合器中与作为热载体（热载体焦炭）的颗粒状焦炭（重量比为1:3至1:30）混合，其中颗粒状 首先，热载体焦炭形成了在混合器中部分蒸发的液体残余物膜。 将气体和蒸气和潮湿的粘稠焦炭从混合器中取出。 将焦炭和残余油的混合物引入随后连接的搅拌釜中，其中混合物在450-600℃，优选480-550℃的温度下机械搅拌的同时慢慢地向下移动。干燥的可流动的焦炭为 从搅拌罐中取出。 通常，搅拌釜中的载体焦炭的停留时间为1〜30分钟。

公开(公告)号：US07015369B2

公开(公告)日：2006-03-21

申请号：US10296356

申请日：2001-05-22

申请人： Markus Hack ,  Ulrich Koss ,  Peter König ,  Martin Rothaemel ,  Hans-Dieter Holtmann

发明人： Markus Hack ,  Ulrich Koss ,  Peter König ,  Martin Rothaemel ,  Hans-Dieter Holtmann

IPC分类号： C07C1/00 ,  C07C6/00

CPC分类号： C07C11/06 ,  C07C1/20 ,  Y02P20/584

摘要： A process for producing propylene from methanol, wherein methanol vapor is reacted on a first catalyst to obtain a first vapor mixture containing dimethyl ether (DME), which is reacted on a form-selective zeolite catalyst disposed as bed in at least two series-connected shaft reactors to produce a product mixture containing propylene.

摘要翻译： 一种从甲醇生产丙烯的方法，其中甲醇蒸汽在第一催化剂上反应，以获得含有二甲醚（DME）的第一蒸气混合物，其在形式选择性沸石催化剂上反应，床形成为至少两个串联连接 轴反应器以产生含有丙烯的产物混合物。

公开(公告)号：US20020060158A1

公开(公告)日：2002-05-23

申请号：US10010327

申请日：2001-11-08

申请人： mg technologies ag

发明人： Helmut Schatton ,  Nikola Anastasijevic

IPC分类号： C25D005/20 ,  C25D021/10

CPC分类号： C25B15/08

摘要： An electrolyte line extends from the outlet of an electrolysis device to a collecting tank and from the same back to the inlet of the electrolysis device. The electrolyte is passed from the outlet of the electrolysis device to a first container which is disposed at a higher level than a second container. Electrolyte collected in the first container is periodically discharged through a first syphon line into the second container, and electrolyte collected in the second container is periodically discharged through a second syphon line into the collecting tank which is disposed at a lower level than the second container. The outlet end of each syphon line is disposed at a distance above the liquid level of the container disposed thereunder, so that electrolyte always flows only in one of the two syphon lines or in none of the syphon lines. When electrolyte flows in none of the two syphon lines, electrolyte is preferably supplied from the collecting tank into the second container.

摘要翻译： 电解质线从电解装置的出口延伸到收集罐，并从电解装置的相反的背面延伸到入口。 电解质从电解装置的出口通过到比第二容器高的第一容器。 收集在第一容器中的电解质通过第一虹吸管周期性地排放到第二容器中，并且收集在第二容器中的电解质通过第二虹吸管周期性地排放到设置在比第二容器更低的水平的收集罐中。 每个虹吸管的出口端设置在设置在其下方的容器的液面之上的距离处，使得电解质总是仅在两个虹吸管中的一个中或不在虹吸管中的一个中流动。 当电解质不流入两条虹吸管中时，电解质优选从收集罐供入第二容器。