Process for the preparation of polycarbonates
    3.
    发明授权
    Process for the preparation of polycarbonates 失效
    聚碳酸酯的制备方法

    公开(公告)号:US5807964A

    公开(公告)日:1998-09-15

    申请号:US818867

    申请日:1997-03-17

    IPC分类号: C08G64/30 C08G64/00

    CPC分类号: C08G64/307

    摘要: A process for the preparation of poly(arylcarbonate)s, relying on reaction of dialkyl carbonates with bisphenols and using selected organotin and oganotitanium catalysts. The process is preferably performed in a first step in which bisphenols and dialkyl carbonates are reacted using a catalyst to obtain an oligo(arylcarbonate). The oligo(arylcarbonate) then undergoes a post polycondensation in a second step, either by itself or with diphenyl carbonate. The second step also uses a catalyst. The process yields poly(arylcarbonate)s that are characteristically free of color and gel.

    摘要翻译: 一种制备聚(芳基碳酸酯)的方法,其依赖于碳酸二烷基酯与双酚的反应,并使用选定的有机锡和催化剂。 该方法优选在使用催化剂反应双酚和碳酸二烷基酯以获得低聚(芳基碳酸酯)的第一步骤中进行。 然后,寡(芳基碳酸酯)在第二步中经由本身或与碳酸二苯酯进行后缩聚反应。 第二步也使用催化剂。 该方法产生特征上没有颜色和凝胶的聚(芳基碳酸酯)。