摘要:
A core/shell polymer (A), comprising: a rubbery core comprising a crosslinked vinylidene fluoride copolymer (a) having a vinylidene fluoride content of 30-90 wt. % and a shell comprising a vinylidene fluoride polymer (b) having a vinylidene fluoride content which is larger than in the crosslinked vinylidene fluoride copolymer (a) and at least 80 wt. %, in a weight ratio (a)/(b) of 30/70-90/10. The vinylidene fluoride-based core/shell polymer (A) is excellent in mechanical properties including flexibility and resistance to nonaqueous electrolytic solutions, is capable of forming a composite electrode layer showing excellent flexibility and adhesion to an electroconductive substrate in combination with a powder active substance and is therefore suitable for use as a binder for nonaqueous electrochemical devices.
摘要:
A nonaqueous battery, such as a lithium ion battery, is formed from a polymer electrolyte comprising: a vinylidene fluoride copolymer comprises 80 to 97 wt. % of vinylidene fluoride monomer units and 3 to 20 wt. % of units of at least one monomer copolymerizable with the vinylidene fluoride monomer and has an inherent viscosity of 1.5 to 10 dl/g. The polymer electrolyte stably retains the nonaqueous electrolytic solution in a large amount and has excellent strength in this state.
摘要:
A negative electrode material for non-aqueous electrolyte secondary batteries, which is best suited for large current I/O non-aqueous electrolyte secondary batteries represented by those for hybrid electric vehicles (HEVs), which are unlikely to be influenced by the deterioration of battery characteristics due to water, and a production process thereof are provided.The negative electrode material having at least one exothermic peak in the range of not lower than 650° C. and lower than 700° C., and at least one exothermic peak in the range of not lower than 700° C. and lower than 760° C., in differential thermal analysis measured under an air flow. The production process of the negative electrode material for non-aqueous electrolyte secondary batteries is characterized by carbonizing a negative electrode material precursor having an oxygen content of not less than 5% by weight and less than 10% by weight, under an inert gas flow at a rate of not more than 120 ml/g·h, under a pressure of normal pressure to 10 kPa, at a temperature higher than 1100° C. and lower than 1500° C.
摘要:
A solid polymer electrolyte having improved ionic conductivity and adhesion with an electroconductive substrate and also remarkably enhanced heat resistance is formed with a vinylidene fluoride copolymer which contains 50-97 mol. % of vinylidene fluoride monomer and 0.1-5 mol. % of an unsaturated dibasic acid monoester or an epoxy group-containing vinyl monomer and further has been crosslinked, thereby improving the performances of a non-aqueous battery, such as a lithium ion battery.
摘要:
A non-aqueous battery comprising a positive electrode material capable of being doped with and liberating lithium, a negative electrode material capable of being doped with and liberating lithium, and a polymer electrolyte disposed between the positive and negative electrode materials. The polymer electrolyte is formed by mixing a vinylidene fluoride copolymer and a nonaqueous electrolytic solution with a solvent, followed by evaporation of the solvent, so as to retain a high proportion of the nonaqueous electrolytic solution, leading to high electroconductivity and excellent strength in this state. The vinylidene fluoride copolymer comprises 80 to 97 wt. % of vinylidene fluoride monomer units and 3 to 20 wt. % of units of at least one monomer copolymerizable with vinylidene fluoride monomer, and has an inherent viscosity of 1.7 to 7 dl/g, as measured at 30° C. in a solution at a concentration of 4 g of polymer in 1 liter of N,N-dimethylformamide.
摘要翻译:包括能够掺杂并释放锂的正极材料的非水电池,能够掺杂和释放锂的负极材料,以及设置在正极和负极材料之间的聚合物电解质。 通过将偏二氟乙烯共聚物和非水电解液与溶剂混合,然后蒸发溶剂,以保持高比例的非水电解液形成聚合物电解质,导致高导电性和优异的强度 。 偏二氟乙烯共聚物包含80至97wt。 %偏二氟乙烯单体单元和3至20wt。 至少一种可与偏二氟乙烯单体共聚的单体的单位百分数,并且在30℃下在浓度为4g聚合物1升N的溶液中测定的特性粘度为1.7至7dl / g ,N-二甲基甲酰胺。
摘要:
A process for producing a polymer electrolyte for a nonaqueous battery by mixing a vinylidene fluoride copolymer and a nonaqueous electrolytic solution with a solvent that can be evaporated, wherein the vinylidene fluoride copolymer comprises 80 to 97 wt. % of vinylidene fluoride monomer units and 3 to 20 wt % of units of at least one monomer copolymerizable with vinylidene fluoride monomer and has an inherent viscosity of 1.5 to 10 dl/g, and evaporating the solvent to form a polymer electrolyte comprising the vinylidene fluoride copolymer impregnated with the nonaqueous electrolytic solution.
摘要:
A core/shell polymer (A), comprising: a rubbery core comprising a crosslinked vinylidene fluoride copolymer (a) having a vinylidene fluoride content of 30-90 wt. % and a shell comprising a vinylidene fluoride polymer (b) having a vinylidene fluoride content which is larger than in the crosslinked vinylidene fluoride copolymer (a) and at least 80 wt. %, in a weight ratio (a)/(b) of 30/70-90/10. The vinylidene fluoride-based core/shell polymer (A) is excellent in mechanical properties including flexibility and resistance to nonaqueous electrolytic solutions, is capable of forming a composite electrode layer showing excellent flexibility and adhesion to an electroconductive substrate in combination with a powder active substance and is therefore suitable for use as a binder for nonaqueous electrochemical devices.
摘要:
A process for producing a polymer electrolyte for a nonaqueous battery by introducing 80 to 97 wt. % of vinylidene fluoride monomer and 3 to 20 wt % of at least one monomer copolymerizable with vinylidene fluoride monomer simultaneously all at once into a polymerization vessel, polymerizing the monomers to provide a vinylidene fluoride copolymer having polymerized units of the monomers and having an inherent viscosity of 1.5 to 10 dl/g, and impregnating the vinylidene fluoride copolymer with a nonaqueous electrolytic solution to provide a polymer electrolyte.
摘要:
A vinylidene fluoride polymer binder solution for forming an electrode for a non-aqueous-type battery is formed by adding an acid, preferably an organic acid, as a stabilizer to a solution of a vinylidene fluoride polymer in an organic solvent. The acid is preferably added in an amount sufficient to ensure a pH of at most 9 when measured with respect to a 10-times dilution of the binder solution with deionized water. The acid addition is effective for preventing a problematic viscosity increase in the binder solution and also gelling of an electrode-forming composition formed by adding a powdery electrode material in the binder solution.
摘要:
A dual-type pyroelectric elements. The first pyroelectric element is constituted by a larger electrode on a first surface and a smaller electrode on a second surface, respectively of a pyroelectric sheet. The second pyroelectric element is on the other hand constituted by a smaller electrode on the first surface and a larger electrode on the second surface respectively of the pyroelectric sheet. Further, takeout electrodes are taken out respectively integrally from the smaller electrodes on both surfaces of the pyroelectric sheet in mutually opposite directions. As a result, even if electrodes patterns on both surfaces of the pyroelectric sheet expected to be formed in alignment with each other are actually deviated positionally, the resultant pairs of pyroelectric elements are allowed to retain substantially identical effective light-receiving areas inclusive of those given by takeout electrodes, thus providing a dual pyroelectric sensor which is excellent in performance of canceling common-mode noises caused by a vibration, temperature change or background radiation.