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    Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,3,3,3-hexafluoropropane
    1.
    发明申请
    Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,3,3,3-hexafluoropropane 有权
    制备1,1,1,3,3-五氟丙烷和1,1,1,3,3,3-六氟丙烷的方法

    公开(公告)号：US20070123742A1

    公开(公告)日：2007-05-31

    申请号：US10572627

    申请日：2004-10-13

    申请人： Velliyur Nott Rao ,  Allen Sievert

    发明人： Velliyur Nott Rao ,  Allen Sievert

    IPC分类号： C07C19/08

    CPC分类号： C07C17/23 ,  B01J23/002 ,  B01J23/26 ,  B01J27/12 ,  B01J37/26 ,  B01J2523/00 ,  C07C17/206 ,  C07C17/21 ,  C07C19/08 ,  C07C21/18 ,  C07C19/10 ,  B01J2523/27 ,  B01J2523/67

    摘要： A process for the manufacture of CF3CH2CHF2 and CF3CH2CF3 is disclosed. The process involves (a) reacting HF and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl═CF2 and CF3CHClCF3; (b) reacting CF3CCl═CF2 and CF3CHClCF3 produced in (a) with hydrogen to produce a product including both CF3CH2CHF2 and CF3CH2CF3; and (c) recovering CF3CH2CHF2 and CF3CH2CF3 from the product produced in (b). In (a), the CF3CCl═CF2 and CF3CHClCF3 are produced in the presence of a fluorination catalyst including a ZnCr2O4/crysta α-chromium oxide composition, a ZnCr2O4/crystalline α-chromium oxide composition which has been treated with a flourinating a agent, a zinc halide/α-chromium oxide composition and/or a zinc halideα-chromium oxide composition which has been treated with a fluorinating agent.

    摘要翻译： 用于制备CF 3 CH 2 CHF 2 CH 2和CF 3 CH 2的方法， SUB> CF 3 3 。 该方法包括（a）使HF和式CX 3 CCl-CClX（其中每个X独立地为F或Cl）的至少一种卤代丙烯反应，以产生包含CF 3 CCl-CF 2和CF 3 CHClCF 3; （b）使（a）中制备的CF 3 N 3 CCl-CF 2 H 2和CF 3 COClCF 3 N与氢 以产生包含CF 3 CH 2 CHF 2 CH 2和CF 3 CH 2 CH 2的化合物， CF 3 3; 和（c）回收CF 3 3 CH 2 CHF 2和CF 3 CH 2 2 / / SUB >（CF 3）3 。 在（a）中，CF 3 3 CCl-CF 2 CO 3和CF 3 CHClCF 3 3在存在下产生 的包含ZnCr 2 O 4 / SiO 2 /α-氧化铬组合物的氟化催化剂，ZnCr 2 O 4 O 3 已经用氟化剂处理过的已经用增稠剂，卤化锌/α-氧化铬组合物和/或卤化锌 - 铬 - 氧化铬组合物处理的结晶α-氧化铬组合物。

    Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane
    2.
    发明申请
    Process for the preparation of 1,1,1,3,3-pentafluoropropane and 1,1,1,2,3-pentafluoropropane 有权
    制备1,1,1,3,3-五氟丙烷和1,1,1,2,3-五氟丙烷的方法

    公开(公告)号：US20060217578A1

    公开(公告)日：2006-09-28

    申请号：US10572626

    申请日：2004-10-13

    申请人： Velliyu Nott Rao ,  Allen Sievert

    发明人： Velliyu Nott Rao ,  Allen Sievert

    IPC分类号： C07C19/08

    CPC分类号： B01J23/002 ,  B01J23/26 ,  B01J27/12 ,  B01J35/0006 ,  B01J37/26 ,  B01J2523/00 ,  C07C17/21 ,  C07C17/23 ,  C07C19/08 ,  C07C19/10 ,  B01J2523/27 ,  B01J2523/67

    摘要： A process is disclosed for the manufacture of CF3CH2CHF2 and CF3CHFCH2F. The process involves (a) reacting hydrogen fluoride, chlorine, and at least one halopropene of the formula CX3CCl═CClX (where each X is independently F or Cl) to produce a product including both CF3CCl2CClF2 and CF3CClFCCl2F; (b) reacting CF3CCl2CClF2 and CF3CClFCCl2F produced in (a) with hydrogen to produce a product including both CF3CH2CHF2, and CF3CHFCH2F; and (c) recovering CF3CH2CHF2 and CF3CHFCH2F from the product produced in (b). In (a), the CF3CCl2CClF2 and CF3CClFCCl2F are produced in the presence of a chlorofluorination catalyst including a ZnCr2O4/crystalline α-chromium oxide composition, a ZnCr2O4/crystalline α-chromium oxide composition which has been treated with a fluorinating agent, a zinc halide/α-chromium oxide composition and/or a zinc halide/α-chromium oxide composition which has been treated with a fluorinating agent.

    摘要翻译： 公开了用于制造CF 3 CH 2 CHF 2 CH 2和CF 3 CHFCH 2的方法 F。 该方法包括（a）使氟化氢，氯和式CX 3 CCl-CClX（其中每个X独立地为F或Cl）的至少一种卤代丙烯反应以产生包含CF 3 3 CCl 2 CClF 2和CF 3 CClFCCl 2 F; （b）使CF 3 3 CCl 2 CClF 2和CF 3 CClFCCl 2 2和/ （a）中用氢气生产的产物，以产生包含CF 3 3 CH 2 CHF 2 2和CF 3 H 2的产物， 2> CHFCH 2＆lt; 2＆gt; 和（c）回收CF 3 CH 2 CHF 2和CF 3 CHFCH 2

    Noncatalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane
    3.
    发明申请
    Noncatalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane 审中-公开
    从1,1,1,3,3,3-六氟丙烷非催化制备1,1,3,3,3-五氟丙烯

    公开(公告)号：US20060094911A1

    公开(公告)日：2006-05-04

    申请号：US11259901

    申请日：2005-10-27

    申请人： Velliyur Rao ,  Allen Sievert ,  Ralph Miller

    发明人： Velliyur Rao ,  Allen Sievert ,  Ralph Miller

    IPC分类号： C07C17/25

    CPC分类号： C01B7/196 ,  C07C17/25 ,  C07C17/38 ,  C07C21/18 ,  Y02P20/582

    摘要： 1,1,3,3,3-Pentafluoropropene (CF3CH═CF2, HFC-1225zc) can be produced by pyrolyzing 1,1,1,3,3,3-hexafluoropropane (CF3CH2CF3, HFC-236fa) in the absence of dehydrofluorination catalyst at temperatures of from about 700° C. to about 1000° C. and total pressures of about atmosphere pressure in an empty, tubular reactor, the interior surfaces of which comprise materials of construction resistant to hydrogen fluoride.

    摘要翻译： 1,1,3,3,3-五氟丙烯（CF 3 CH-CF 2 H 2，HFC-1225zc）可以通过将1,1,1,3， 在不存在脱氟化氢催化剂的情况下，在约700℃的温度下，将3,3-六氟丙烷（CF 3 CH 2 CH 3 CF 3，HFC-236fa） 在空的管式反应器中的约+约1000℃和约大气压的总压力，其内表面包括耐氟化氢的结构材料。

    Cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalyst precursors
    5.
    发明申请
    Cobalt-substituted chromium oxide compositions, their preparation, and their use as catalysts and catalyst precursors 有权
    钴取代的氧化铬组合物，它们的制备及其作为催化剂和催化剂前体的用途

    公开(公告)号：US20050228202A1

    公开(公告)日：2005-10-13

    申请号：US10523228

    申请日：2003-08-21

    申请人： Mario Nappa ,  Velliyur Nott Rao ,  H. Rosenfeld ,  Shekhar Subramoney ,  Munirpallam Subramanian ,  Allen Sievert

    发明人： Mario Nappa ,  Velliyur Nott Rao ,  H. Rosenfeld ,  Shekhar Subramoney ,  Munirpallam Subramanian ,  Allen Sievert

    IPC分类号： C01G37/02 ,  B01J23/26 ,  B01J23/86 ,  B01J27/06 ,  B01J27/132 ,  B01J35/00 ,  B01J35/10 ,  B01J37/02 ,  B01J37/03 ,  C07B39/00 ,  C07B61/00 ,  C07C17/00 ,  C07C17/08 ,  C07C17/10 ,  C07C17/20 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C17/358 ,  C07C17/37 ,  C07C19/08 ,  C07C21/18

    CPC分类号： C07C17/21 ,  B01J23/864 ,  B01J35/002 ,  B01J35/1014 ,  B01J37/0236 ,  B01J37/03 ,  C07C17/00 ,  C07C17/08 ,  C07C17/10 ,  C07C17/20 ,  C07C17/206 ,  C07C17/23 ,  C07C17/25 ,  C07C17/358 ,  C07C17/37 ,  C07C21/18 ,  C07C21/04 ,  C07C19/08 ,  C07C21/06 ,  C07C19/12 ,  C07C19/10

    摘要： A crystalline alpha-chromium oxide where from about 0.05 atom % to about 6 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by trivalent cobalt (Co+3) atoms is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline cobalt-substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline cobalt-substituted alpha-chromium oxide. The method involves (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble cobalt salt and a soluble trivalent chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a cobalt concentration of from about 0.05 mole % to about 6 mole % of the total concentration of cobalt and chromium in the solution; and after at least three moles E of ammonium per mole of chromium in the solution has been added to the solution, (b) collecting the co-precipitated solid formed in (a); (c) drying the collected solid; and (d) calcining the dried solid. Also disclosed is a chromium-containing catalyst composition comprising a chromium-containing component prepared by treating the crystalline cobalt-substituted alpha-chromium oxide with a fluorinating agent; and a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of a catalyst. The process involves using as the catalyst a composition comprising the crystalline cobalt-substituted alpha-chromium oxide and/or the treated cobalt-substituted alpha-chromium oxide.

    摘要翻译： 公开了一种结晶α-Cr氧化物，其中α-Cr氧化物晶格中约0.05原子％至约6原子％的铬原子被三价钴（Co + O 3+）原子所取代。 还公开了含铬催化剂组合物，其包含结晶钴取代的α-氧化铬作为含铬组分; 以及制备包含结晶钴取代的α-氧化铬的组合物的方法。 该方法包括（a）通过向可溶性钴盐和可溶性三价铬盐的水溶液中加入氢氧化铵共沉淀固体，该溶液在溶液中每摩尔铬含有至少三摩尔硝酸盐，并且具有钴浓度 为溶液中钴和铬的总浓度的约0.05摩尔％至约6摩尔％ 并且在溶液中每摩尔铬至少三摩尔E之后的铵加入到溶液中，（b）收集（a）中形成的共沉淀固体; （c）干燥收集的固体; 和（d）煅烧干燥的固体。 还公开了一种含铬催化剂组合物，其包含通过用氟化剂处理结晶钴取代的α-氧化铬制备的含铬组分; 以及在催化剂存在下改变烃或卤代烃中的氟分布（即含量和/或排列）的方法。 该方法包括使用包含结晶钴取代的α-氧化铬和/或经处理的钴取代的α-氧化铬的组合物作为催化剂。

    1,1,1,3,3-Pentafluorobutane refrigerant or heat transfer fluid compositions comprising hydrofluorocarbon and uses thereof
    7.
    发明申请
    1,1,1,3,3-Pentafluorobutane refrigerant or heat transfer fluid compositions comprising hydrofluorocarbon and uses thereof 失效
    1,1,1,3,3-五氟丁烷制冷剂或包含氢氟烃的传热流体组合物及其用途

    公开(公告)号：US20050151111A1

    公开(公告)日：2005-07-14

    申请号：US11014435

    申请日：2004-12-16

    申请人： Barbara Minor ,  Mario Nappa ,  Allen Sievert

    发明人： Barbara Minor ,  Mario Nappa ,  Allen Sievert

    IPC分类号： C09K5/04 ,  C09K5/00

    CPC分类号： C09K5/045 ,  C09K2205/112 ,  C09K2205/22

    摘要： Disclosed herein are 1,1,1,3,3-pentafluorobutane refrigerant or heat transfer fluid compositions further comprising hydrofluorocarbon, N-(difluoromethyl)-N,N-dimethylamine, 1,1,1,2,2-pentafluoro-2-[(pentafluoroethyl)thio]ethane or mixtures thereof, which are useful in refrigerain or air conditioning apparatus or as heat transfer fluids. The compositions of the present invention are also useful in centrifugal compressor apparatus that employ two-stage compressors or single slab.single pass heat exchangers.

    摘要翻译： 本文公开了1,1,1,3,3-五氟丁烷制冷剂或传热流体组合物，其还包含氢氟烃，N-（二氟甲基）-N，N-二甲胺，1,1,1,2,2-五氟-2- 乙醚或其混合物，其可用于制冷剂或空调设备或作为传热流体。 本发明的组合物也可用于使用两级压缩机或单片式单通道热交换器的离心式压缩机设备中。

    Copper-Substituted Chromium Oxide Compositions, Their Preparation, and Their Use as Catalysts and Catalyst Precursors
    9.
    发明申请
    Copper-Substituted Chromium Oxide Compositions, Their Preparation, and Their Use as Catalysts and Catalyst Precursors 审中-公开

    公开(公告)号：US20100152503A1

    公开(公告)日：2010-06-17

    申请号：US11988256

    申请日：2006-08-04

    申请人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Sievert ,  Shekhar Subramoney

    发明人： Velliyur Nott Mallikarjuna Rao ,  H. David Rosenfeld ,  Allen Sievert ,  Shekhar Subramoney

    IPC分类号： C07C17/358 ,  C07C17/00 ,  C07C17/37 ,  C01G37/02 ,  B01J23/26

    CPC分类号： B01J23/868 ,  B01J37/0009 ,  B01J37/0236 ,  B01J37/03 ,  B01J37/26 ,  C07C17/206 ,  C07C17/21 ,  C07C17/25 ,  C07C17/358 ,  C07C17/37 ,  C07C21/18 ,  C07C19/10

    摘要： A crystalline alpha-chromium oxide where from about 0.05 atom % to about 5 atom % of the chromium atoms in the alpha-chromium oxide lattice are replaced by divalent copper (Cu+2) atoms is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline copper-substituted alpha-chromium oxide; and methods for preparing a composition comprising the crystalline copper-substituted alpha-chromium oxide. One method involves (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble copper salt and a soluble trivalent chromium salt that contains at least three moles of nitrate per mole of chromium in the solution and has a copper concentration of from about 0.05 atom % to about 5 atom % of the total concentration of copper and chromium in the solution; and after at least three moles of ammonium per mole of chromium in the solution has been added to the solution, (b) collecting the co-precipitated solid formed in (a); (c) drying the collected solid; and (d) calcining the dried solid. Another method involves (a) preparing an aqueous solution of a soluble copper salt and a soluble trivalent chromium salt that contains a copper concentration of from about 0.05 atom % to about 5 atom % of the total concentration of copper and chromium in the solution, (b) evaporating the solution to dryness, and (c) calcining the dried solid. Also disclosed is a chromium-containing catalyst composition comprising a chromium-containing component prepared by treating the crystalline copper-substituted alpha-chromium oxide with a fluorinating agent; and a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of a catalyst. The process involves using as the catalyst a composition comprising the crystalline copper-substituted alpha-chromium oxide and/or the treated copper-substituted alpha-chromium oxide.

    Functionalized Copolymers of Terminally Functionalized Perfluoro (Alkyl Vinyl Ether) Reactor Wall for Photochemical Reactions, Process for Increasing Fluorine Content in Hydrocaebons and Halohydrocarbons and Olefin Production
    10.
    发明申请
    Functionalized Copolymers of Terminally Functionalized Perfluoro (Alkyl Vinyl Ether) Reactor Wall for Photochemical Reactions, Process for Increasing Fluorine Content in Hydrocaebons and Halohydrocarbons and Olefin Production 审中-公开
    用于光化学反应的末端官能化全氟（烷基乙烯醚）反应器壁的官能化共聚物，增加氢化碳和卤代烃中的氟含量和烯烃生产的方法

    公开(公告)号：US20070265368A1

    公开(公告)日：2007-11-15

    申请号：US11792639

    申请日：2005-12-19

    申请人： Velliyur Nott Mallikarjuna Rao ,  Allen Sievert

    发明人： Velliyur Nott Mallikarjuna Rao ,  Allen Sievert

    IPC分类号： C07C17/00 ,  C08J3/28

    CPC分类号： B01J19/127 ,  B01J8/08 ,  B01J19/123 ,  B01J19/24 ,  B01J19/2415 ,  B01J19/243 ,  B01J23/26 ,  B01J37/088 ,  B01J2219/00822 ,  B01J2219/00831 ,  B01J2219/00833 ,  B01J2219/00835 ,  B01J2219/00936 ,  B01J2219/00943 ,  B01J2219/0204 ,  C07C17/10 ,  C07C17/206 ,  C07C17/25 ,  C07C19/08 ,  C07C19/10 ,  C07C19/12 ,  C07C21/18 ,  C07C21/185

    摘要： A photochemical reaction apparatus including a reactor and a light source situated so that light from the light source is directed through a portion of the reactor wall is disclosed. The apparatus is characterized by the portion of the reaction wall comprising a functionalized copolymer of a terminally functionalized perfluoro(alkyl vinyl ether). Also described is a photochemical reaction process using said reactor. The functional group of the copolymer of the apparatus and the process is selected from —SO2F, —SO2CI, —SO3H, —CO2R (where R is H or C1-C3 alkyl), —PO3H2, and salts thereof. A process for increasing the flourine content of at least one compound selected from hydrocarbons and halohydrocarbons, comprising: (a) photochlorinating said at least one compound, and (b) reacting the halogenated hydrocarbon in (a) with HF. A process for producing an olefinic compound, comprising: (a) photochlorinating at least one compound selected from hydrocarbons and halohydrocarbons containing at least two carbon atoms and at least two hydrogen atoms to produce a halogenated hydrocarbon containing a hydrogen substituent and a chlorine substituent on adjacent carbon atoms; and (b) subjecting the halogenated hydrocarbon produced in (a) to dehydrohalogenation.

    摘要翻译： 公开了一种光化学反应装置，其包括反应器和光源，其位于使得来自光源的光被引导通过反应器壁的一部分。 该装置的特征在于反应壁的一部分包含末端官能化的全氟（烷基乙烯基醚）的官能化共聚物。 还描述了使用所述反应器的光化学反应过程。 该装置和方法的共聚物的官能团选自-SO 2 F，-SO 2 Cl，-SO 3 H ，-CO 2 R（其中R为H或C 1 -C 3烷基），-PO 3 H 2 H 2，及其盐。 一种提高至少一种选自烃和卤代烃的化合物的含量的方法，包括：（a）将所述至少一种化合物进行光氯化，和（b）使（a）中的卤代烃与HF反应。 一种制备烯烃化合物的方法，包括：（a）将至少一种选自含有至少两个碳原子和至少两个氢原子的烃和卤代烃的化合物进行光氯化以产生在邻近的含氢取代基和氯取代基的卤代烃 碳原子 和（b）使（a）中制备的卤代烃脱卤化氢。