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1.发明授权Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49 失效异构烷烃：在合成多孔MCM-49存在下进行烯烃烷基化
公开(公告)号：US5254792A
公开(公告)日：1993-10-19
申请号：US774482
申请日：1991-10-10
CPC分类号： C07C2/58 , C07C2529/70
摘要： The invention provides an isoparaffin: olefin alkylation process comprising contacting isoparaffin and olefin with a synthetic porous crystalline material which is characterized, in its uncalcined form, by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 20, X is a trivalent element and Y is a tetravalent element.
摘要翻译： 本发明提供了异链烷烃：烯烃烷基化方法，其包括使异链烷烃和烯烃与合成的多孔结晶材料接触，所述合成多孔结晶材料的特征在于其未煅烧形式，其X射线衍射图包括基本上如本说明书的表I所述的值，并且具有 包含摩尔关系X 2 O 3：（n）YO 2的组合物，其中n小于约20，X是三价元素，Y是四价元素。
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2.发明授权
公开(公告)号：US5475175A
公开(公告)日：1995-12-12
申请号：US228780
申请日：1994-04-18
申请人： Altaf Husain , Albin Huss, Jr. , Iraj I. Rahmim
发明人： Altaf Husain , Albin Huss, Jr. , Iraj I. Rahmim
CPC分类号： B01J29/65 , B01J37/0009 , C07C2/58 , B01J2229/42 , B01J29/70 , C07C2521/04 , C07C2529/70
摘要： This invention provides a process for upgrading hydrocarbon feedstock comprising the steps of:(i) recovering a C.sub.4 -rich aliphatic stream from a catalytic cracking process;(ii contacting said C.sub.4 -rich aliphatic stream with an isomerization catalyst comprising a zeolite sorbing 30 to 55 mg n-hexane at 90.degree. C., 83 torr, and 15 to 40 mg 3-methylpentane at 90.degree. C., 90 torr, per g dry zeolite in the hydrogen form in a first reaction stage to selectively isomerize C.sub.4 n-olefins to C.sub.4 isoolefins; and(iii) contacting the product stream from said first reaction stage with a solid acid alkylation catalyst selected from the group consisting of MCM-36 and MCM-49, as described herein and zeolites having a Constraint Index of less than or equal to about 2, to produce isoparaffinic alkylate gasoline.
摘要翻译： 本发明提供了一种用于升级烃原料的方法，包括以下步骤：（i）从催化裂化过程中回收富含C4的脂族物流; （ii）使所述富C4脂族物流与异构化催化剂接触，所述异构化催化剂包括在90℃下吸附30至55mg正己烷的沸石，83托和15至40mg 3-甲基戊烷，90℃，90托， 在氢气形式的每g干沸石中，在第一反应阶段中选择性地将C 4正构烯烃异构化为C 4异烯烃;和（iii）使来自所述第一反应阶段的产物流与固体酸烷基化催化剂接触，所述固体酸烷基化催化剂选自MCM -36和MCM-49，以及具有小于或等于约2的约束指数的沸石以产生异链烷烃烷基化汽油。
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公开(公告)号：US5258569A
公开(公告)日：1993-11-02
申请号：US929550
申请日：1992-08-13
IPC分类号： C07C2/58
CPC分类号： B01J29/049 , C07C2/58 , C07C2521/04 , C07C2529/70
摘要： The alkylation of isoparaffin with olefin to provide alkylate is carried out in the presence of, as catalyst, MCM-36.
摘要翻译： 异烯烃与烯烃的烷基化以提供烷基化物在作为催化剂MCM-36的存在下进行。
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公开(公告)号：US5625113A
公开(公告)日：1997-04-29
申请号：US365334
申请日：1994-12-28
CPC分类号： C07C2/58 , C07C2/62 , C07C9/16 , C07C2527/054 , C07C2529/70
摘要： A process is disclosed for alkylating an isoparaffin with an olefin comprising the steps of:(a) reacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in a first alkylation reaction stage at temperature from about -40.degree. C. to about 500.degree. C. and overall isoparaffin:olefin feed weight ratio of from about 1:1 to about 250:1 with a solid alkylation catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 35, X is a trivalent element and Y is a tetravalent element;(b) mixing the effluent from said first alkylation stage with additional olefin to evolve an intermediate stream having an isoparaffin:olefin weight ratio of from about 2:1 to about 100:1; and(c) reacting said intermediate stream in a second alkylation stage in the absence of intermediate fractionation with a liquid acid catalyst comprising H.sub.2 SO.sub.4 to produce C.sub.5 + alkylate.
摘要翻译： 公开了一种用烯烃烷基化异链烷烃的方法，该方法包括以下步骤：（a）使第一烷基化反应阶段中具有4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃反应， 40℃至约500℃，总异构链烷烃：烯烃进料重量比为约1:1至约250:1，其中固体烷基化催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括值 基本上如说明书的表I所述，并且具有包含摩尔关系X 2 O 3：（n）YO 2的组成，其中n小于约35，X是三价元素，Y是四价元素; （b）将来自所述第一烷基化阶段的流出物与另外的烯烃混合以产生具有约2:1至约100:1的异链烷烃：烯烃重量比的中间料流; 和（c）在不与中间分级分离的第二烷基化阶段中使所述中间物流与包含H 2 SO 4的液体酸催化剂反应，以产生C5 +烷基化物。
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公开(公告)号：US5191147A
公开(公告)日：1993-03-02
申请号：US785398
申请日：1991-10-30
CPC分类号： C07C2/58 , B01J29/041 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/16
摘要： The present invention provides a process for alkylating an isoparaffin with an olefin comprising contacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in an alkylation reaction zone at temperature from about -20.degree. C. to about 200.degree. C. in the presence of a Bronsted acid and an inorganic, porous crystalline phase material having, after calcination, a d-spacing greater than about 18 Angstrom Units and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 50 torr and 25.degree. C., wherein the molar ratio of said isoparaffin to said olefin is from about 1:1 to about 250:1 to evolve a product stream containing C.sub.5 + alkylate. In a preferred embodiment, the alkylation catalyst complex comprises a Bronsted acid and an inorganic, porous crystalline phase material having, after calcination, a hexagonal arrangement of uniformly-sized pores having diameters of at least about 13 Angstrom Units and exhibiting a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units.
摘要翻译： 本发明提供了一种用烯烃烷基化异链烷烃的方法，包括在烷基化反应区中将约4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃在约-20℃至约 在布朗斯台德酸和无机多孔结晶相材料存在下，在煅烧后，d-间距大于约18埃单位，苯吸附量大于15克苯/ 100克 所述材料在50托和25℃下，其中所述异链烷烃与所述烯烃的摩尔比为约1:1至约250:1，以放出含有C5 +烷基化物的产物流。 在优选的实施方案中，烷基化催化剂络合物包括布朗斯台德酸和无机多孔结晶相材料，其在煅烧之后具有直径为至少约13埃单位的均匀尺寸的孔的六边形排列并且显示出六边形电子衍射图 可以用大于约18埃单位的d100值进行索引。
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公开(公告)号：US5146029A
公开(公告)日：1992-09-08
申请号：US579766
申请日：1990-09-10
CPC分类号： B01J29/04 , C07C2/12 , C07C2529/70
摘要： Light olefins are converted to isoalkene-rich hydrocarbon products, e.g., isobutene and isoamylenes with zeolite MCM-22 catalyst.
摘要翻译： 使用沸石MCM-22催化剂将轻质烯烃转化为富含异烯烃的烃产物，例如异丁烯和异戊烯。
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7.发明授权Highly selective N-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性N-烯烃异构化方法
公开(公告)号：US5237121A
公开(公告)日：1993-08-17
申请号：US925442
申请日：1992-08-11
IPC分类号： C07C5/27
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化成异烯烃的方法，其中线性烯烃例如正丁烯与包含ZSM-22的催化剂接触，ZSM-22的晶体尺寸 最大尺寸不大于0.5微米。 该方法在异构化条件下进行以产生相应碳数的异烯烃，例如异丁烯。 即使在相对较低的温度下也能获得高的全部异烯烃收率。
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8.发明授权Highly selective n-olefin isomerization process using low zeolite content ZSM-35 catalyst 失效使用低沸石含量的ZSM-35催化剂的高选择性正烯烃异构化方法
公开(公告)号：US5523511A
公开(公告)日：1996-06-04
申请号：US228779
申请日：1994-04-18
CPC分类号： B01J29/65 , B01J29/7042 , B01J29/7046 , C07C5/2775 , B01J2229/26 , B01J2229/42
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100.degree. to 750.degree. C. and linear olefin space velocities of less than 30 WHSV. The process uses a catalyst composition comprising 5 to 40 wt % ZSM-35, and 60 to 95 wt % inorganic oxide matrix, e.g., silica.
摘要翻译： 公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触， 可以包括100℃至750℃的温度和低于30WHSV的线性烯烃空速。 该方法使用包含5至40重量％的ZSM-35和60至95重量％的无机氧化物基质如二氧化硅的催化剂组合物。
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公开(公告)号：US5449851A
公开(公告)日：1995-09-12
申请号：US49586
申请日：1993-04-19
CPC分类号： B01J29/65 , C07C5/2775 , B01J2229/26 , B01J2229/42 , B01J29/7042 , B01J29/7046
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High iso-olefin selectivities thus can be obtained, even at relatively low temperatures and high linear olefin partial pressures.
摘要翻译： 公开了一种用于线性烯烃的有机原料的高度选择性骨架异构化的方法，其中线性烯烃例如正丁烯在异构化条件下与包含ZSM-35的催化剂接触以产生相应碳数的异烯烃，例如， 异丁烯 因此，即使在较低的温度和高的线性烯烃分压下，也可以获得高的异烯烃选择性。
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10.发明授权Highly selective n-olefin isomerization process using microcrystalline ZSM-22 失效使用微晶ZSM-22的高选择性n-烯烃异构化方法
公开(公告)号：US5157194A
公开(公告)日：1992-10-20
申请号：US811355
申请日：1991-12-20
CPC分类号： C07C5/2775
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-22 having a crystal size whose largest dimension is no greater than 0.5 micron. The process is carried out under isomerization conditions to produce iso-olefins of corresponding carbon number, e.g., isobutene. High overall iso-olefin yields thus can be obtained, even at relatively low temperatures.
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