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公开(公告)号：US08119740B2
公开(公告)日：2012-02-21
申请号：US10539048
申请日：2003-12-19
IPC分类号： C08F261/10
CPC分类号： C08F299/024 , C08F290/062 , C08F290/068
摘要： The invention describes curable liquid acryloyl group containing compositions, which are produced by reacting monofunctional vinyl compounds and multifunctional acrylic esters with β-dicarbonyl group containing compounds having two activated hydrogen atoms in its methylene position. These material can be polymerized or crosslinked by free radical polymerization, UV (ultraviolet) or electron-beam radiation. The curable liquid compositions are suitable for producing curable coatings, printing inks, adhesives, or molding compositions.
摘要翻译： 本发明描述了通过使单官能乙烯基化合物和多官能丙烯酸酯与含有二羰基的化合物在其亚甲基位置具有两个活化氢原子的化合物反应制备的含可固化液体丙烯酰基的组合物。 这些材料可以通过自由基聚合，UV（紫外）或电子束辐射聚合或交联。 可固化液体组合物适用于生产可固化涂料，印刷油墨，粘合剂或模塑组合物。
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公开(公告)号：US07923481B2
公开(公告)日：2011-04-12
申请号：US12682101
申请日：2008-10-31
申请人： Kai-Uwe Gaudl , Artur Lachowicz
发明人： Kai-Uwe Gaudl , Artur Lachowicz
CPC分类号： C08G65/18 , C08G65/105 , C08G65/22 , C08L63/00 , C08L71/00 , C08L2666/14
摘要： The present invention relates to a composition which is curable by radiation such as an ultraviolet ray or an electron beam. Specifically, the present invention relates to a curable composition which is useful for coatings and inks. The present invention provides a radiation curable composition that is highly cationically polymerizable and highly adhesive to substrates. A radiation curable composition of the present invention includes, as essential ingredients, a cationically polymerizable compound (a) represented by the following general formula 1 (wherein, R represents an alkyl group of 1 to 10 carbon atoms, R1 represents a hydrogen atom or a methyl group, n represents a number from 1 to 4, and m represents a number from 0 to 10); a cationic photoinitiator (b); and water (c).
摘要翻译： 本发明涉及通过紫外线或电子束等放射线固化的组合物。 具体地说，本发明涉及可用于涂料和油墨的可固化组合物。 本发明提供了高度阳离子聚合性和与基材高度粘合的可辐射固化组合物。 作为必要成分，本发明的可辐射固化组合物包括由以下通式1表示的阳离子聚合性化合物（a）（其中，R表示1〜10个碳原子的烷基，R 1表示氢原子或 甲基，n表示1〜4的数，m表示0〜10的数）。 阳离子光引发剂（b）; 和水（c）。
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公开(公告)号：US20100210751A1
公开(公告)日：2010-08-19
申请号：US12682101
申请日：2008-10-31
申请人： Kai-Uwe Gaudl , Artur Lachowicz
发明人： Kai-Uwe Gaudl , Artur Lachowicz
CPC分类号： C08G65/18 , C08G65/105 , C08G65/22 , C08L63/00 , C08L71/00 , C08L2666/14
摘要： The present invention relates to a composition which is curable by radiation such as an ultraviolet ray or an electron beam. Specifically, the present invention relates to a curable composition which is useful for coatings and inks. The present invention provides a radiation curable composition that is highly cationically polymerizable and highly adhesive to substrates. A radiation curable composition of the present invention includes, as essential ingredients, a cationically polymerizable compound (a) represented by the following general formula 1 (wherein, R represents an alkyl group of 1 to 10 carbon atoms, R1 represents a hydrogen atom or a methyl group, n represents a number from 1 to 4, and m represents a number from 0 to 10); a cationic photoinitiator (b); and water (c).
摘要翻译： 本发明涉及通过紫外线或电子束等放射线固化的组合物。 具体地说，本发明涉及可用于涂料和油墨的可固化组合物。 本发明提供了高度阳离子聚合性和与基材高度粘合的可辐射固化组合物。 作为必要成分，本发明的可辐射固化组合物包含由以下通式1表示的阳离子聚合性化合物（a）（其中，R表示1〜10个碳原子的烷基，R 1表示氢原子或 甲基，n表示1〜4的数，m表示0〜10的数）。 阳离子光引发剂（b）; 和水（c）。
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公开(公告)号：US20060148924A1
公开(公告)日：2006-07-06
申请号：US10539048
申请日：2003-12-19
申请人： Artur Lachowicz , Kai-Uwe Gaudl , Steven Nahm , Gerwald Grahe
发明人： Artur Lachowicz , Kai-Uwe Gaudl , Steven Nahm , Gerwald Grahe
IPC分类号： C08J3/28
CPC分类号： C08F299/024 , C08F290/062 , C08F290/068
摘要： The invention describes curable liquid acryloyl group containing compositions, which are produced by reacting monofunctional vinyl compounds and multifunctional acrylic esters with β-dicarbonyl group containing compounds having two activated hydrogen atoms in its methylene position. These material can be polymerized or crosslinked by free radical polymerization, UV (ultraviolet) or electron-beam radiation. The curable liquid compositions are suitable for producing curable coatings, printing inks, adhesives, or moulding compositions.
摘要翻译： 本发明描述了通过使单官能乙烯基化合物和多官能丙烯酸酯与其在其亚甲基位置具有两个活化氢原子的含有β-二羰基的化合物反应制备的含可固化液体丙烯酰基的组合物。 这些材料可以通过自由基聚合，UV（紫外）或电子束辐射聚合或交联。 可固化液体组合物适用于生产可固化涂料，印刷油墨，粘合剂或模塑组合物。
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5.发明申请Curable resin compositions and process for preparing oligomers containing acrylate groups and substituted methacrylate groups 有权可固化树脂组合物和制备含有丙烯酸酯基团和取代的甲基丙烯酸酯基团的低聚物的方法公开(公告)号：US20050119361A1
公开(公告)日：2005-06-02
申请号：US10983247
申请日：2004-11-08
申请人： Artur Lachowicz , Kai-Uwe Gaudl , Gerwald Grahe
发明人： Artur Lachowicz , Kai-Uwe Gaudl , Gerwald Grahe
CPC分类号： C08F22/105
摘要： A curable resin composition which exhibits excellent hardness of their curing products as well as storage stability is provided, and a simple method to obtain acrylated resins is provided. The composition comprises a curable oligomer which has an acryloyl group and a substituted methacrylate group represented by the following structure The process comprises a reaction step of reacting at least one monomeric multifunctional acrylate in the presence of a tertiary organic phosphine.
摘要翻译： 提供了一种固化树脂组合物，其固化产物的硬度以及储存稳定性均优良，并且提供了获得丙烯酸树脂的简单方法。 该组合物包含具有由以下结构表示的丙烯酰基和取代的甲基丙烯酸酯基的可固化低聚物。该方法包括在叔有机膦存在下使至少一种单体多官能丙烯酸酯反应的反应步骤。
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公开(公告)号：US06348594B2
公开(公告)日：2002-02-19
申请号：US09363652
申请日：1999-07-30
申请人： Kai-Uwe Gaudl , Artur Lachowicz , Gerwald Grahe
发明人： Kai-Uwe Gaudl , Artur Lachowicz , Gerwald Grahe
IPC分类号： C07D23902
CPC分类号： C07D239/10 , D06M15/423
摘要： Urea derivatives of formula 1 for the hardening of hydroxyl group-containing polymers, wherein each of R1-R7 is a hydrogen atom or a linear or branched C1-C4-alkyl group, preferably methyl, ethyl, n-propyl, isopropyl, n-butyl or isobutyl, R1-R7 being identical or different, and R8 is a linear or branched C1-C6-alkyl group, preferably methyl, ethyl, n-propyl, isopropyl, n-butyl or isobutyl. The compounds 1 are prepared by reacting a compound 2 wherein R9 is a member selected from the group consisting of —CHO, —CH(OH)—OR8 and —CH(OH)2 with a urea derivative 3 optionally followed by etherification of the reaction product with an alcohol X—OH, wherein X is a linear or branched C1-C4-alkyl group.
摘要翻译： 式1的脲衍生物用于固化含羟基聚合物，其中R 1 -R 7是氢原子或直链或支链C 1 -C 4烷基，优选甲基，乙基，正丙基，异丙基，正丁基， 丁基或异丁基，R 1 -R 7相同或不同，R 8是直链或支链C 1 -C 6烷基，优选甲基，乙基，正丙基，异丙基，正丁基或异丁基。 化合物1通过使化合物2反应来制备，其中R9是选自-CHO，-CH（OH）-OR8和-CH（OH）2的成员与脲衍生物3，然后将反应产物醚化 醇X-OH，其中X是直链或支链C 1 -C 4 - 烷基。
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7.发明授权Curable resin compositions and process for preparing oligomers containing acrylate groups and substituted methacrylate groups 失效可固化树脂组合物和制备含有丙烯酸酯基团和取代的甲基丙烯酸酯基团的低聚物的方法公开(公告)号：US07385016B2
公开(公告)日：2008-06-10
申请号：US10322749
申请日：2002-12-19
申请人： Artur Lachowicz , Kai-Uwe Gaudl , Gerwald Grahe
发明人： Artur Lachowicz , Kai-Uwe Gaudl , Gerwald Grahe
CPC分类号： C08F22/105
摘要： A curable resin composition which exhibits excellent hardness of their curing products as well as storage stability is provided, and a simple method to obtain acrylated resins is provided. The composition comprises a curable oligomer which has an acryloyl group and a substituted methacrylate group represented by the following structure The process comprises a reaction step of reacting at least one monomeric multifunctional acrylate in the presence of a tertiary organic phosphine.
摘要翻译： 提供了一种固化树脂组合物，其固化产物的硬度以及储存稳定性均优良，并且提供了获得丙烯酸树脂的简单方法。 该组合物包含具有由以下结构表示的丙烯酰基和取代的甲基丙烯酸酯基的可固化低聚物。该方法包括在叔有机膦存在下使至少一种单体多官能丙烯酸酯反应的反应步骤。
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公开(公告)号：US07166648B2
公开(公告)日：2007-01-23
申请号：US10507209
申请日：2003-04-03
申请人： Artur Lachowicz , Kai-Uwe Gaudl , Jens Ferbitz , Gerwald F. Grahe , Yu Jing , Wu Guanghui
发明人： Artur Lachowicz , Kai-Uwe Gaudl , Jens Ferbitz , Gerwald F. Grahe , Yu Jing , Wu Guanghui
IPC分类号： C08F2/46
CPC分类号： C08F2/50
摘要： A photoinitiator is provided which exhibits excellent photosensitivity, yields colorless products, and is usable in thick layer UV curable coating. A novel chemical compound is also provided which is usable for the photoinitator. Photocurable composition is also provided which has these properties. The photoinitiator consists essentially of a compound having a molecular weight of 1000 or less, and having a chemical structure represented by the following formula (1), wherein R3 and R4 independently denote a specific alkyl group, and R1 and R2 independently denote an electron attracting group or a specific alkyl group, and weight percentage of a chemical structure element represented by the following formula (2), which is expressed in formula (1) based on the total molecular weight of the compound, is 17% to 54% by mass.
摘要翻译： 提供光敏引发剂，其具有优异的光敏性，产生无色产物，并且可用于厚层可UV固化涂层。 还提供了可用于光电二极管的新型化合物。 还提供了具有这些性质的光固化性组合物。 光引发剂基本上由分子量为1000或更小的化合物组成，并且具有由下式（1）表示的化学结构，其中R 3和R 4 独立地表示特定的烷基，R 1和R 2分别独立地表示吸电子基团或特定的烷基，并且由下式表示的化学结构元素的重量百分数 基于化合物的总分子量，式（1）表示的式（2）为17〜54质量％。
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公开(公告)号：US20050256218A1
公开(公告)日：2005-11-17
申请号：US10507209
申请日：2003-04-03
申请人： Artur Lachowicz , Kai-Uwe Gaudl , Jens Ferbitz , Gerwald Grahe , Yu Jing , Wu Guanghui
发明人： Artur Lachowicz , Kai-Uwe Gaudl , Jens Ferbitz , Gerwald Grahe , Yu Jing , Wu Guanghui
IPC分类号： C07C49/12 , C07C59/347 , C07C69/716 , C07C255/17 , C07C317/24 , C08F2/50 , C08F4/00 , C09D4/00 , G03F7/031 , C08G2/00
CPC分类号： C08F2/50
摘要： A photoinitiator is provided which exhibits excellent photosensitivity, yields colorless products, and is usable in thick layer UV curable coating. A novel chemical compound is also provided which is usable for the photoinitator. Photocurable composition is also provided which has these properties. The photoinitiator consists essentially of a compound having a molecular weight of 1000 or less, and having a chemical structure represented by the following formula (1), wherein R3 and R4 independently denote a specific alkyl group, and R1 and R2 independently denote an electron attracting group or a specific alkyl group, and weight percentage of a chemical structure element represented by the following formula (2), which is expressed in formula (1) based on the total molecular weight of the compound, is 17% to 54% by mass.
摘要翻译： 提供光敏引发剂，其具有优异的光敏性，产生无色产物，并且可用于厚层可UV固化涂层。 还提供了可用于光电二极管的新型化合物。 还提供了具有这些性质的光固化性组合物。 光引发剂基本上由分子量为1000或更小的化合物组成，并且具有由下式（1）表示的化学结构，其中R 3和R 4 独立地表示特定的烷基，R 1和R 2分别独立地表示吸电子基团或特定的烷基，并且由下式表示的化学结构元素的重量百分数 基于化合物的总分子量，式（1）表示的式（2）为17〜54质量％。
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10.发明授权Curable resin compositions and process for preparing oligomers containing acrylate groups and substituted methacrylate groups 有权可固化树脂组合物和制备含有丙烯酸酯基团和取代的甲基丙烯酸酯基团的低聚物的方法公开(公告)号：US07235616B2
公开(公告)日：2007-06-26
申请号：US10983247
申请日：2004-11-08
申请人： Artur Lachowicz , Kai-Uwe Gaudl , Gerwald Grahe
发明人： Artur Lachowicz , Kai-Uwe Gaudl , Gerwald Grahe
CPC分类号： C08F22/105
摘要： A curable resin composition which exhibits excellent hardness of their curing products as well as storage stability is provided, and a simple method to obtain acrylated resins is provided. The composition comprises a curable oligomer which has an acryloyl group and a substituted methacrylate group represented by the following structure The process comprises a reaction step of reacting at least one monomeric multifunctional acrylate in the presence of a tertiary organic phosphine.
摘要翻译： 提供了一种固化树脂组合物，其固化产物的硬度以及储存稳定性均优良，并且提供了获得丙烯酸树脂的简单方法。 该组合物包含具有由以下结构表示的丙烯酰基和取代的甲基丙烯酸酯基的可固化低聚物。该方法包括在叔有机膦存在下使至少一种单体多官能丙烯酸酯反应的反应步骤。
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