摘要:
In one aspect, combustion apparatus are described herein which, in some embodiments, can provide advantageous NOx loads while mitigating the formation of SCR catalyst deactivation species in the flue gas stream. In some embodiments, a combustion apparatus described herein comprises a furnace providing a flue gas stream, the furnace comprising a primary combustion zone having an air to fuel stoichiometric ratio ranging from 0.89 to 1.05 and air staging apparatus associated with the furnace.
摘要:
The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.
摘要:
In one aspect, structural catalyst bodies comprising one or more gradients of catalytic material are provided herein. In some embodiments, a structural catalyst body described herein comprises an inner partition wall having a first surface and a second surface opposite the first surface, the inner partition wall having a gradient of catalytic material along the width of the inner partition wall.
摘要:
An exhaust gas treatment catalyst for removal of one or more pollutants in an exhaust gas, the catalyst comprising: a SO3-reducing catalyst powder which removes the above-described pollutants; and a diluent powder which is not the SO3-reducing catalyst powder nor a catalyst for reactions between exhaust gas components and a reagent, wherein the SO3-reducing catalyst powder is dispersed in the diluent powder.
摘要:
In one aspect, structural catalyst bodies comprising one or more gradients of catalytic material are provided herein. In some embodiments, a structural catalyst body described herein comprises an inner partition wall having a first surface and a second surface opposite the first surface, the inner partition wall having a gradient of catalytic material along the width of the inner partition wall.
摘要:
The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.
摘要:
The present invention provides compositions, systems, and methods for achieving high efficiencies of nitrogen oxide (NOx) removal from exhaust gases while minimizing ammonia slip and sulfur dioxide oxidation. In one embodiment, a method of removing nitrogen oxides from an exhaust gas comprises providing a first catalyst layer, adding an ammonia-containing compound to the exhaust gas upstream of the first catalyst layer in excess of the stoichiometric equivalent of the nitrogen oxides in the exhaust gas, flowing the exhaust gas through the first catalyst layer, selectively catalytically decomposing ammonia in excess of the stoichiometric reaction equivalent of the nitrogen oxides in the exhaust gas, and catalytically reducing the nitrogen oxides by reaction with ammonia not selectively catalytically decomposed.
摘要:
In one aspect, structural catalyst bodies comprising one or more gradients of catalytic material are provided herein. In some embodiments, a structural catalyst body described herein comprises an inner partition wall having a first surface and a second surface opposite the first surface, the inner partition wall having a gradient of catalytic material along the width of the inner partition wall.
摘要:
In one aspect, structural catalyst bodies comprising one or more gradients of catalytic material are provided herein. In some embodiments, a structural catalyst body described herein comprises an inner partition wall having a first surface and a second surface opposite the first surface, the inner partition wall having a gradient of catalytic material along the width of the inner partition wall.
摘要:
Structural catalyst bodies are described herein which, in some embodiments, can be used in the treatment of nitrogen oxides present in exhaust or flue gases from stationary or mobile combustion sources. In some embodiments, a structural catalyst body described herein comprises an outer peripheral wall and a plurality of inner partition walls having an average thickness less than about 0.5 mm, the outer peripheral wall and the inner partition walls having dispersed throughout a chemical composition comprising 50-99.9% by weight an inorganic oxide composition, less than 3% by weight an inorganic extrusion aid and at least 0.1% by weight a catalytically active metal functional group comprising vanadium, the structural catalyst body having a crystalline vanadium pentoxide content less than 0.1 weight percent.