公开(公告)号：US08969511B2

公开(公告)日：2015-03-03

申请号：US13560149

申请日：2012-07-27

申请人： Lars Zander ,  Uwe Franken ,  Christiane Kunze ,  Michael Krebs ,  Johann Klein

发明人： Lars Zander ,  Uwe Franken ,  Christiane Kunze ,  Michael Krebs ,  Johann Klein

IPC分类号： C08G65/04 ,  C08G63/91 ,  C08G65/20 ,  C08G65/26 ,  C09D171/02 ,  C09J171/02

CPC分类号： C08G63/916 ,  C08G65/20 ,  C08G65/2663 ,  C08G2650/24 ,  C09D171/02 ,  C09J171/02

摘要： Polyether block copolymers of the general structure B-(A-OH)n are described, where n is greater than or equal to 2 and blocks A are made up of polyoxypropylene units and the central block B of polyoxytetramethylene, polyoxyethylene, polybutadiene, polyisoprene, polyacrylate, polymethacrylate, polyamide, polyurethane, or polyester units. These polyether block copolymers are suitable for the manufacture of compositions that serve as the basis for preparations for use as a one-component moisture-hardening or two-component adhesive or sealant, for assembly bonding, for areal bonding, and/or for coating, as a reactive melt adhesive or as a laminating adhesive.

摘要翻译： 其中n为大于或等于2的聚醚嵌段共聚物，其中A为聚氧丙烯单元，聚氧四亚甲基，聚氧乙烯，聚丁二烯，聚异戊二烯， 聚丙烯酸酯，聚甲基丙烯酸酯，聚酰胺，聚氨酯或聚酯单元。 这些聚醚嵌段共聚物适用于制造用作单组分湿固化或双组分粘合剂或密封剂，用于组装粘合，用于面接合和/或涂覆的制剂的基础的组合物， 作为反应性熔融粘合剂或作为层压粘合剂。

公开(公告)号：US08609800B2

公开(公告)日：2013-12-17

申请号：US12906397

申请日：2010-10-18

申请人： Helene Boudet ,  Andreas Bolte ,  Thomas Bachon ,  Lars Zander ,  Christiane Kunze ,  Johann Klein ,  Nicole Ditges

发明人： Helene Boudet ,  Andreas Bolte ,  Thomas Bachon ,  Lars Zander ,  Christiane Kunze ,  Johann Klein ,  Nicole Ditges

IPC分类号： C08G18/83

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/765 ,  C08G2190/00 ,  C08G18/289

摘要： Silylated polyurethanes can be manufactured by reacting at least one polyol compound, having a molecular weight from 4000 to 20,000 dalton, with a diisocyanate, with a stoichiometric excess of the diisocyanate compound with respect to the polyol compound or compounds, with the result that a polyurethane prepolymer that is isocyanate-terminated is formed; and by subsequently reacting the polyurethane prepolymer with one or more OH-terminated silanes of formula (1) to yield a polyurethane having predominantly terminal alkoxysilyl groups. In formula (1), m is equal to 0, 1, or 2, R1 is an alkyl residue having 1 to 4 carbon atoms, R2 is an alkyl residue having 1 to 4 carbon atoms, R3 is a divalent organic residue having 1 to 12 atoms, selected from C, N, S, and/or O, in the chain, but by preference exclusively carbon atoms, R4 is a hydrogen atom or an alkyl residue having 1 to 10 carbon atoms, and R is a difunctional organic group, preferably a linear or branched alkyl group having 1 to 6 carbon atoms. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.

摘要翻译： 甲硅烷基化聚氨酯可以通过使至少一种分子量为4000至20,000道尔顿的多元醇化合物与二异氰酸酯相对于多元醇化合物或化合物与化学计量过量的二异氰酸酯化合物反应而制备，结果是聚氨酯 形成异氰酸酯封端的预聚物; 并随后使聚氨酯预聚物与一种或多种式（1）的OH封端的硅烷反应，得到主要具有末端烷氧基甲硅烷基的聚氨酯。 在式（1）中，m等于0,1或2，R 1是具有1至4个碳原子的烷基，R 2是具有1至4个碳原子的烷基，R 3是具有1至 在链中选自C，N，S和/或O的12个原子，但仅仅是碳原子，R4是氢原子或具有1-10个碳原子的烷基，R是双官能有机基团 优选具有1-6个碳原子的直链或支链烷基。 甲硅烷基化聚氨酯适用于作为粘合剂，密封剂或涂层剂的制剂。

公开(公告)号：US08563675B2

公开(公告)日：2013-10-22

申请号：US12701959

申请日：2010-02-08

申请人： Lars Zander ,  Thomas Bachon ,  Christiane Kunze ,  Johann Klein ,  Daniela Braun ,  Sara Gonzalez ,  Ulrich Neuhausen

发明人： Lars Zander ,  Thomas Bachon ,  Christiane Kunze ,  Johann Klein ,  Daniela Braun ,  Sara Gonzalez ,  Ulrich Neuhausen

IPC分类号： C08G77/46 ,  C08F283/06

CPC分类号： C08G65/30 ,  C08G65/33344 ,  C08G65/33351 ,  C08G65/336

摘要： The present invention relates to silane-crosslinking curable compositions encompassing a polymer P having at least two terminal groups of the following formulas (I) and (II) -Am-K1—SiR1XY (I), -Am-K2—SiR2XY (II), and/or two polymers P1 and P2, polymer P1 having terminal groups of the following formula (I) -Am-K1—SiR1XY (I), and polymer P2 having terminal groups of the following formula (II) -Am-K2—SiR2XY (II), in which A denotes a divalent bonding group, K1, K2, mutually independently, denote a divalent aliphatic hydrocarbon group that has a main chain of 1 to 6 carbon atoms, the hydrocarbon groups K1, K2 being different, X, Y mutually independently denote a hydroxy group or a hydrolyzable group, R1, R2 mutually independently denote a hydrocarbon residue having 1 to 20 carbon atoms, and m assumes the values 0 or 1.

摘要翻译： 本发明涉及包含具有下式（I）和（II）-Am-K1-SiR1XY（I），-Am-K2-SiR2XY（Ⅱ）的至少两个末端的聚合物P的硅烷交联固化性组合物， ，和/或两种聚合物P1和P2，具有下式（I）-Am-K1-SiR1XY（I）的末端的聚合物P1和具有下式（II）的末端的聚合物P2-A-K2- 其中A表示二价键合基​​团的SiR2XY（II），K1，K2彼此独立地表示具有1-6个碳原子的主链，烃基K1，K2不同的二价脂族烃基，X， Y相互独立地表示羟基或可水解基团，R 1，R 2相互独立地表示碳原子数1〜20的烃残基，m表示0或1。

公开(公告)号：US20130085239A1

公开(公告)日：2013-04-04

申请号：US13560149

申请日：2012-07-27

申请人： Lars Zander ,  Uwe Franken ,  Christiane Kunze ,  Michael Krebs ,  Johann Klein

发明人： Lars Zander ,  Uwe Franken ,  Christiane Kunze ,  Michael Krebs ,  Johann Klein

IPC分类号： C08G63/91

CPC分类号： C08G63/916 ,  C08G65/20 ,  C08G65/2663 ,  C08G2650/24 ,  C09D171/02 ,  C09J171/02

摘要： Polyether block copolymers of the general structure B-(A-OH)n are described, where n is greater than or equal to 2 and blocks A are made up of polyoxypropylene units and the central block B of polyoxytetramethylene, polyoxyethylene, polybutadiene, polyisoprene, polyacrylate, polymethacrylate, polyamide, polyurethane, or polyester units. These polyether block copolymers are suitable for the manufacture of compositions that serve as the basis for preparations for use as a one-component moisture-hardening or two-component adhesive or sealant, for assembly bonding, for areal bonding, and/or for coating, as a reactive melt adhesive or as a laminating adhesive.

摘要翻译： 其中n为大于或等于2的聚醚嵌段共聚物，其中A为聚氧丙烯单元，聚氧四亚甲基，聚氧乙烯，聚丁二烯，聚异戊二烯， 聚丙烯酸酯，聚甲基丙烯酸酯，聚酰胺，聚氨酯或聚酯单元。 这些聚醚嵌段共聚物适用于制造用作单组分湿固化或双组分粘合剂或密封剂，用于组装粘合，用于面接合和/或涂覆的制剂的基础的组合物， 作为反应性熔融粘合剂或作为层压粘合剂。

公开(公告)号：US08076444B2

公开(公告)日：2011-12-13

申请号：US12732233

申请日：2010-03-26

申请人： Ulrich Neuhausen ,  Daniela Braun ,  Johann Klein ,  Christiane Kunze ,  Sara Gonzalez ,  Lars Zander ,  Thomas Bachon

发明人： Ulrich Neuhausen ,  Daniela Braun ,  Johann Klein ,  Christiane Kunze ,  Sara Gonzalez ,  Lars Zander ,  Thomas Bachon

IPC分类号： C08G77/04

CPC分类号： C08G65/30 ,  C08G65/33351 ,  C08G65/336 ,  C09D171/02 ,  C09K3/10 ,  C09K2200/0657

摘要： The invention relates to silane cross-linking curable compositions, comprising a polymer P with at least two terminal groups of the following formulae (I) and (II) -Am-K1—SiXYZ (I), -Am-K2—SiXYZ (II), and/or two polymers P1 and P2, the polymer P1 having terminal groups of the following formula (I) -Am-K1—SiXYZ (I), and the polymer P2 having terminal groups of the following formula (II) -Am-K2—SiXYZ (II). In said formulae, A represents a bivalent binding group K1 and K2 independently of one another represent a bivalent aliphatic hydrocarbon group with a main chain of between 1 and 6 carbon atoms, the hydrocarbon groups K1, K2 being different, X, Y and Z independently of one another represent a hydroxy group of a hydrolysable group and m stands for 0 or 1.

摘要翻译： 本发明涉及硅烷交联可固化组合物，其包含具有至少两个下式（I）和（II）的末端的聚合物P：-Am-K1-SiXYZ（I），-Am-K2-SiXYZ（II ）和/或两种聚合物P1和P2，具有下式（I）-Am-K1-SiXYZ（I）的端基的聚合物P1和具有下式（II）的端基的聚合物P2-Am -K2-SiXYZ（II）。 在所述式中，A表示二价结合基团K1和K2彼此独立地表示主链为1-6个碳原子的二价脂族烃基，烃基K1，K2独立地为X，Y和Z独立地 彼此表示可水解基团的羟基，m表示0或1。

公开(公告)号：US20110028640A1

公开(公告)日：2011-02-03

申请号：US12906215

申请日：2010-10-18

申请人： Johann Klein ,  Sara Gonzalez ,  Lars Zander ,  Christiane Kunze ,  Thomas Bachon ,  Andreas Bolte ,  Martin Majolo ,  Thomas Tamcke

发明人： Johann Klein ,  Sara Gonzalez ,  Lars Zander ,  Christiane Kunze ,  Thomas Bachon ,  Andreas Bolte ,  Martin Majolo ,  Thomas Tamcke

IPC分类号： C08L83/08 ,  C08G77/08

CPC分类号： C08G18/4866 ,  C08G18/10 ,  C08G18/227 ,  C08G2190/00 ,  C09J175/08 ,  C08G18/718

摘要： The invention relates to a method for producing cross-linkable formulations. In a first step of the method, at least one α,ω-difunctional organic polymer of formula (1) X-A-X (1) is converted into organyloxysilyl-terminated polymers P1, using organofunctional silanes of formula (2) Y—R—Si—(R1)m(—OR2)3m (2), in the presence of catalysts (A) selected from the group consisting of potassium, iron, indium, zinc, bismuth and copper compounds. In said formulae, R is a bivalent, optionally substituted hydrocarbon group which comprises between 1 and 12 carbon atoms and can be interrupted with heteroatoms, R1 and R2 are the same or different, monovalent, optionally substituted hydrocarbon groups which comprise between 1 and 12 carbon atoms and can be interrupted with heteroatoms, A is bivalent, optionally substituted hydrocarbon group which comprises at least 6 carbon atoms and can be interrupted with heteroatoms, m is equal to 0, 1 or 2, X is a hydroxyl group and Y is an isocyanate group, or X is an isocyanate group and Y is a hydroxyl group or a primary or secondary amino group. In a second step, the polymers P1 obtained in the first step are mixed with a silane condensation catalyst (B) selected from the group consisting of compounds of elements of the third main group and/or fourth secondary group and heterocyclic organic amines, amine complexes of the element compounds, or the mixtures thereof. Optionally, said mixture is mixed with other substances (C). The formulations do not contain organic tin compounds, and are suitable for using as adhesives, sealants, or coating agents.

摘要翻译： 本发明涉及一种生产可交联制剂的方法。 在该方法的第一步中，使用式（2）的有机官能硅烷将至少一种式（1）XAX（1）的α，ω-双官能有机聚合物转化为有机甲硅烷基封端的聚合物P1，Y-R-Si- （R1）m（-OR2）3m（2），在选自钾，铁，铟，锌，铋和铜化合物的催化剂（A）的存在下。 在所述式中，R是二价任选取代的烃基，其包含1至12个碳原子并且可被杂原子间隔，R 1和R 2是相同或不同的，包含1至12个碳的单价，任选取代的烃基 原子并且可以被杂原子中断，A是二价的，任选取代的烃基，其包含至少6个碳原子并且可以被杂原子间隔，m等于0,1或2，X是羟基，Y是异氰酸酯 基团，或X为异氰酸酯基团，Y为羟基或伯或仲氨基。 在第二步骤中，将第一步中获得的聚合物P1与选自第三主族和/或第四仲
子的元素化合物和杂环有机胺的硅烷缩合催化剂（B），胺络合物 的元素化合物，或其混合物。 任选地，将所述混合物与其它物质（C）混合。 配方不含有机锡化合物，适用于粘合剂，密封剂或涂层剂。

公开(公告)号：US08067508B2

公开(公告)日：2011-11-29

申请号：US12416404

申请日：2009-04-01

申请人： Daniela Braun ,  Johann Klein ,  Thomas Bachon ,  Andreas Bolte ,  Christiane Kunze

发明人： Daniela Braun ,  Johann Klein ,  Thomas Bachon ,  Andreas Bolte ,  Christiane Kunze

IPC分类号： C08L83/06

CPC分类号： C08L101/10 ,  C08G18/3893 ,  C08G18/4825 ,  C08G18/71 ,  C08G18/718

摘要： This disclosure relates to a curable composition comprising at least one polymer A with at least one reactive silyl group and at least one polymer B with at least one reactive silyl group, the number of reactive silyl groups in the polymer A being greater or equal to the number of silyl groups in polymer B and the reactive silyl groups being capable of cross-linking to form siloxane bonds. The disclosure also relates to preparations containing a composition of this type and to the use of said compositions.

摘要翻译： 本公开涉及包含至少一种具有至少一个反应性甲硅烷基的聚合物A和至少一种具有至少一个反应性甲硅烷基的聚合物B的可固化组合物，聚合物A中的反应性甲硅烷基的数目大于或等于 聚合物B中的甲硅烷基数以及反应性甲硅烷基能够交联以形成硅氧烷键。 本公开还涉及含有这种类型的组合物和所述组合物的用途的制剂。

公开(公告)号：US20110071254A1

公开(公告)日：2011-03-24

申请号：US12897850

申请日：2010-10-05

申请人： Thomas Bachon ,  Lars Zander ,  Sara Gonzalez ,  Christiane Kunze ,  Johann Klein ,  Daniela Braun

发明人： Thomas Bachon ,  Lars Zander ,  Sara Gonzalez ,  Christiane Kunze ,  Johann Klein ,  Daniela Braun

IPC分类号： C08L83/04 ,  C08G18/08 ,  C08G59/14

CPC分类号： C09K3/1021 ,  C08G18/4854 ,  C08G18/4866 ,  C08G18/718 ,  C08G2190/00 ,  C09J175/08

摘要： The invention relates to a silylated polyurethane that is manufactured by reacting at least one polyether compound having an OH number per DIN 53783 between 3 and 20 mg KOH/g, made up of at least two polyoxyalkylene blocks A and B, the number of carbon atoms in the alkylene units of blocks A and B differing by at least 1, with one or more isocyanatosilanes of formula (I): OCN—R—Si—(R1)m(—OR2)3-m, in which m is 0, 1, or 2, each R2 is an alkyl residue having 1 to 4 carbon atoms, each R1 is an alkyl residue having 1 to 4 carbon atoms, and R is a difunctional organic group, in order to cap the hydroxyl groups of the prepolymer with the isocyanatosilane, thereby forming a silylated polyurethane that comprises alkoxysilyl groups as reactive end groups. The silylated polyurethanes that are described are suitable for the manufacture of adhesive, sealant, or coating-agent preparations having good mechanical properties.

摘要翻译： 本发明涉及一种甲硅烷基化聚氨酯，其通过使至少一种具有根据DIN 53783的OH值的至少一种聚醚化合物在3至20mg KOH / g之间，由至少两个聚亚氧烷基嵌段A和B组成，碳原子数 在一个或多个式（I）的异氰酸基硅烷：其中m为0的OCN-R-Si-（R1）m（-OR2）3-m的亚烷基单元中与至少1个不同的嵌段A和B的亚烷基单元， 1或2，每个R 2是具有1至4个碳原子的烷基残基，每个R 1是具有1至4个碳原子的烷基，R是双官能有机基团，以便将预聚物的羟基封端 异氰酸甲硅烷，从而形成包含烷氧基甲硅烷基作为反应性端基的甲硅烷基化聚氨酯。 所述的甲硅烷基化聚氨酯适用于制造具有良好机械性能的粘合剂，密封剂或涂布剂制剂。

公开(公告)号：US20110034627A1

公开(公告)日：2011-02-10

申请号：US12906397

申请日：2010-10-18

申请人： Helene Boudet ,  Andreas Bolte ,  Thomas Bachon ,  Lars Zander ,  Christiane Kunze ,  Johann Klein ,  Nicole Ditges

发明人： Helene Boudet ,  Andreas Bolte ,  Thomas Bachon ,  Lars Zander ,  Christiane Kunze ,  Johann Klein ,  Nicole Ditges

IPC分类号： C08L83/08 ,  C08G77/22

CPC分类号： C09J175/04 ,  C08G18/10 ,  C08G18/765 ,  C08G2190/00 ,  C08G18/289

摘要： Silylated polyurethanes can be manufactured by reacting at least one polyol compound, having a molecular weight from 4000 to 20,000 dalton, with a diisocyanate, with a stoichiometric excess of the diisocyanate compound with respect to the polyol compound or compounds, with the result that a polyurethane prepolymer that is isocyanate-terminated is formed; and by subsequently reacting the polyurethane prepolymer with one or more OH-terminated silanes of formula (1) to yield a polyurethane having predominantly terminal alkoxysilyl groups. In formula (1), m is equal to 0, 1, or 2, R1 is an alkyl residue having 1 to 4 carbon atoms, R2 is an alkyl residue having 1 to 4 carbon atoms, R3 is a divalent organic residue having 1 to 12 atoms, selected from C, N, S, and/or O, in the chain, but by preference exclusively carbon atoms, R4 is a hydrogen atom or an alkyl residue having 1 to 10 carbon atoms, and R is a difunctional organic group, preferably a linear or branched alkyl group having 1 to 6 carbon atoms. The silylated polyurethanes are suitable for use in a preparation as an adhesive, sealant, or coating agent.

摘要翻译： 甲硅烷基化聚氨酯可以通过使至少一种分子量为4000至20,000道尔顿的多元醇化合物与二异氰酸酯相对于多元醇化合物或化合物与化学计量过量的二异氰酸酯化合物反应而制备，结果是聚氨酯 形成异氰酸酯封端的预聚物; 并随后使聚氨酯预聚物与一种或多种式（1）的OH封端的硅烷反应，得到主要具有末端烷氧基甲硅烷基的聚氨酯。 在式（1）中，m等于0,1或2，R 1是具有1至4个碳原子的烷基，R 2是具有1至4个碳原子的烷基，R 3是具有1至 在链中选自C，N，S和/或O的12个原子，但仅仅是碳原子，R4是氢原子或具有1-10个碳原子的烷基，R是双官能有机基团 优选具有1-6个碳原子的直链或支链烷基。 甲硅烷基化聚氨酯适用于作为粘合剂，密封剂或涂层剂的制剂。

公开(公告)号：US08642669B2

公开(公告)日：2014-02-04

申请号：US13010344

申请日：2011-01-20

申请人： Wilfried Huebner ,  Milan Sebestian ,  Christiane Kunze ,  Lars Zander ,  Johann Klein

发明人： Wilfried Huebner ,  Milan Sebestian ,  Christiane Kunze ,  Lars Zander ,  Johann Klein

IPC分类号： C08G77/04

CPC分类号： C08J9/143 ,  C08G18/10 ,  C08G18/163 ,  C08G18/289 ,  C08G18/4216 ,  C08G18/4845 ,  C08G18/809 ,  C08G2101/00 ,  C08G2190/00 ,  C08J9/141 ,  C08J9/142 ,  C08J2207/04 ,  C08J2375/04 ,  C08G18/48 ,  C08G18/32 ,  C08G18/66

摘要： The invention relates to a foamable mixture which contains at least one alkoxysilane-terminated prepolymer and which can be produced of a) at least one alkoxysilane that was functionalized with isocyanate groups and that can be produced of at least one hydroxyfunctional and/or aminofunctional alkoxysilane and at least one diisocyanate or polyisocyanate, and b) at least one compound that contains at least one OH group, and at least one blowing agent, characterized in that the foamable mixture has a dynamic viscosity of 100 to 25,000 mPas, preferably 500 to 10,000 mPas, at 23° C. The invention further relates to a method for producing said foamable mixture. The foamable mixtures according to the invention are suitable for sealing, insulating and mounting joints, roof surfaces, windows and doors or for filling hollow spaces.

摘要翻译： 本发明涉及一种可发泡混合物，其含有至少一个烷氧基硅烷封端的预聚物，其可由以下物质制备：a）至少一种烷氧基硅烷，其被异氰酸酯基团官能化，并且可由至少一种羟基官能和/或氨基官能的烷氧基硅烷制备， 至少一种二异氰酸酯或多异氰酸酯，和b）至少一种含有至少一个OH基团的化合物和至少一种发泡剂，其特征在于可发泡混合物的动态粘度为100至25,000mPas，优选为500至10,000mPas ，在23℃。本发明还涉及一种生产所述可发泡混合物的方法。 根据本发明的可发泡混合物适用于密封，绝缘和安装接头，屋顶表面，窗户和门，或用于填充中空空间。