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公开(公告)号:US08366894B2
公开(公告)日:2013-02-05
申请号:US12660197
申请日:2010-02-22
Applicant: Mourad Manoukian , Anthony B. LaConti , W. Michael Krebs , Linda A. Tempelman , John W. Forchione, Jr. , Erich Muehlanger, Jr.
Inventor: Mourad Manoukian , Anthony B. LaConti , W. Michael Krebs , Linda A. Tempelman , John W. Forchione, Jr. , Erich Muehlanger, Jr.
IPC: G01N27/26 , G01N27/407
CPC classification number: G01N27/404
Abstract: A multi-gas microsensor assembly for simultaneously detecting carbon dioxide and oxygen in real time. According to one embodiment, the assembly comprises a non-conductive, solid substrate. A plurality of sensing electrodes, a single reference electrode, and a single counter electrode are positioned on one side of the non-conductive, solid substrate. In addition, all of the electrodes are in intimate contact with the same side of a solid-polymer electrolyte anion-exchange membrane, the solid polymer electrolyte membrane having at least one gas diffusion opening aligned with each sensing electrode. The sensor is operated in a three-electrode potentiostatic mode, in which a constant potential is maintained between the sensing and reference electrodes, and the current is measured between the sensing and counter electrodes. Control of the electrodes is achieved with a small bi-potentiostat. The design of the bi-potentiostat allows at least two different sensing electrodes to share the same counter and reference electrodes.
Abstract translation: 用于同时检测二氧化碳和氧气的多气体微量传感器组件。 根据一个实施例,组件包括非导电固体衬底。 多个感测电极,单个参考电极和单个对电极位于非导电固体衬底的一侧。 此外,所有电极与固体聚合物电解质阴离子交换膜的同一侧紧密接触,固体聚合物电解质膜具有与每个感测电极对准的至少一个气体扩散开口。 传感器在三电极恒电位模式下工作,其中在感测和参考电极之间保持恒定电位,并且在感测和对电极之间测量电流。 电极的控制通过小型双电位稳定器实现。 双电位器的设计允许至少两个不同的感测电极共享相同的计数器和参考电极。
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公开(公告)号:US07968326B2
公开(公告)日:2011-06-28
申请号:US12691421
申请日:2010-01-21
Applicant: Hanns Misiak , Michael Krebs , Timothy O'Connell , Karl-Heinz Maurer , Cornelia Kluin , Inken Prüser
Inventor: Hanns Misiak , Michael Krebs , Timothy O'Connell , Karl-Heinz Maurer , Cornelia Kluin , Inken Prüser
IPC: B09B3/00
CPC classification number: C08G18/289 , C09K3/1018
Abstract: The present invention relates to the use of enzymes and/or whole-cell catalysts for the removal of undesired by-products from crosslinkable preparations.
Abstract translation: 本发明涉及酶和/或全细胞催化剂用于从可交联制剂中除去不需要的副产物的用途。
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公开(公告)号:US07267878B2
公开(公告)日:2007-09-11
申请号:US10703341
申请日:2003-11-07
Applicant: Hartmut Primke , Gerald Petry , Ingolf Scheffler , Juergen Wichelhaus , Michael Krebs , Michael Rudolph , Andrew Nixon , Hans-Peter Kohlstadt
Inventor: Hartmut Primke , Gerald Petry , Ingolf Scheffler , Juergen Wichelhaus , Michael Krebs , Michael Rudolph , Andrew Nixon , Hans-Peter Kohlstadt
IPC: B32B27/00
CPC classification number: B29B9/10 , B29K2105/0097 , C08G18/12 , C08G18/4018 , C08G2170/20 , C08J3/12 , C08J2367/02 , C08L29/00 , C09J5/06 , C09J175/04 , C09J201/02 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/3158 , C08G18/307
Abstract: A moisture-curing hot-melt-adhesive composition in granulate, tablet or powder form can be produced by a.) fusing the reactive hot-melt-adhesive composition and heating the melt, subject to exclusion of moisture, b.) extruding this melt through one or more dies onto a cooled surface, subject to exclusion of moisture, c.) cooling the granulate, subject to exclusion of moisture, whereby the composition solidifies, d.) removing the cooled hot-melt-adhesive granulate, e.) filling the granulate into moisture-tight packages, subject to exclusion of moisture. These reactive hot-melt adhesives are pourable and free-flowing and therefore can be used with all conventional application machines for hot-melt adhesives.
Abstract translation: a)通过以下方法制备颗粒状,片状或粉末形式的湿固化热熔粘合剂组合物:a)将反应性热熔粘合剂组合物熔合并加热熔体,排除水分,b)将该熔体挤出 通过一个或多个模具到冷却的表面上,排除水分,c。)冷却颗粒,排除水分,由此组合物固化,d。)去除冷却的热熔胶粘剂颗粒,例如, 将颗粒填充到防潮包装中,排除潮湿。 这些反应性热熔粘合剂是可倾倒和自由流动的,因此可以与所有常规的热熔粘合剂应用机一起使用。
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公开(公告)号:US20060175009A1
公开(公告)日:2006-08-10
申请号:US11373784
申请日:2006-03-10
Applicant: Michael Krebs , Uwe Franken , Christian Kremer
Inventor: Michael Krebs , Uwe Franken , Christian Kremer
IPC: C09J101/00
CPC classification number: C08G18/4202 , C08G18/12 , C08G2170/20 , C08G2250/00 , C08L75/04 , C09J5/06 , C09J2475/00 , C08G18/307
Abstract: Reactive adhesives are prepared based on polyurethane compositions obtained by reacting at least one type of polyol with at least one type of diisocyanate containing at least 80 percent by weight 2,4′-diphenylmethane diisocyanate. Such adhesives are applied to a surface to be glued of at least one substrate, thermally reactivated separately in time and/or space from application of the adhesive, and then used to join together the substrates to be adhered to each other.
Abstract translation: 基于通过使至少一种类型的多元醇与至少一种含有至少80重量%的2,4'-二苯基甲烷二异氰酸酯的二异氰酸酯反应而获得的聚氨酯组合物来制备反应性粘合剂。 这样的粘合剂被施加到待粘合的至少一个基底的表面上,在施加粘合剂的时间和/或空间中分开热重新激活,然后用于将待粘附的基底彼此连接在一起。
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公开(公告)号:US20050222363A1
公开(公告)日:2005-10-06
申请号:US11042742
申请日:2005-01-24
Applicant: Michael Krebs , Uwe Franken , Christoph Lohr
Inventor: Michael Krebs , Uwe Franken , Christoph Lohr
CPC classification number: C08G18/12 , C08G18/4202 , C08G18/4252 , C08G2170/20 , C08G2250/00 , C08L25/16 , C08L31/04 , C08L2666/04 , C09J175/06 , C08G18/307
Abstract: A reactive hotmelt adhesive is prepared which contains a reaction product of a stoichiometric excess of a polyisocyanate with a hydroxyl-functional polyester-ether block copolymer based on aromatic dicarboxylic acids. The adhesive additionally contains a reaction product of a polyisocyanate and at least one of either a polyether polyol or a polyester polyol. A thermoplastic polymer may also be present.
Abstract translation: 制备反应性热熔粘合剂,其包含化学计量过量的多异氰酸酯与基于芳族二羧酸的羟基官能的聚酯 - 醚嵌段共聚物的反应产物。 粘合剂另外含有多异氰酸酯与聚醚多元醇或聚酯多元醇中的至少一种的反应产物。 也可以存在热塑性聚合物。
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公开(公告)号:US06465104B1
公开(公告)日:2002-10-15
申请号:US09694172
申请日:2000-10-23
Applicant: Michael Krebs , Yingjie Li , Ingolf Scheffler
Inventor: Michael Krebs , Yingjie Li , Ingolf Scheffler
IPC: C09J17504
CPC classification number: C08G18/6254 , C08G18/12 , C08G18/4063 , C08G18/6229 , C08G2170/20 , Y10T428/31551 , C08G18/307
Abstract: Hotmelt polyurethane adhesive compositions which are solid at room temperature and capable of being cured by moisture are obtained by combining the reaction product of a polyisocyanate and a low molecular weight polymer derived from ethylenically unsaturated monomers and containing active hydrogen groups such as hydroxyl with an isocyanate-containing polyurethane prepolymer derived from one or more polyols. The low molecular weight polymer component may, for example, be obtained by free radical polymerization of mixtures of unsaturated monocarboxylic acids, alkyl esters of unsaturated monocarboxylic acids, and/or hydroxyalkyl esters of unsaturated monocarboxylic acids.
Abstract translation: 通过将多异氰酸酯和衍生自烯键式不饱和单体的低分子量聚合物的反应产物和含有活性氢基团如羟基的异氰酸酯 - 共聚物混合,得到在室温下固化并能够被水分固化的热熔聚氨酯粘合剂组合物, 衍生自一种或多种多元醇的含聚氨酯预聚物。 低分子量聚合物组分可以例如通过不饱和一元羧酸,不饱和一元羧酸的烷基酯和/或不饱和一元羧酸的羟烷基酯的混合物的自由基聚合获得。
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公开(公告)号:US5994493A
公开(公告)日:1999-11-30
申请号:US750262
申请日:1996-12-03
Applicant: Michael Krebs
Inventor: Michael Krebs
CPC classification number: C08G18/6607 , C08G18/089 , C08G18/12 , C08G2170/20 , Y10S528/905
Abstract: Reactive hotmelt adhesives based on liquid polyether polyols and/or polyester polyols and aromatic diols with at least one diisocyanate have a very low melt viscosity and high early strength. They are particularly suitable for the bonding of substrates of poor thermal conductivity, such as foams and nonwoven materials, and heat-sensitive substrates.
Abstract translation: PCT No.PCT / EP95 / 02017 371日期1996年12月3日第 102(e)日期1996年12月3日PCT提交1995年5月26日PCT公布。 公开号WO95 / 33783 日期1995年12月14日基于液体聚醚多元醇和/或聚酯多元醇和至少一种二异氰酸酯的芳族二醇的反应性热熔粘合剂具有非常低的熔体粘度和高的早期强度。 它们特别适用于粘合不良导热性的基材,如泡沫和非织造材料,以及热敏基材。
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公开(公告)号:US5368706A
公开(公告)日:1994-11-29
申请号:US180830
申请日:1993-01-12
Applicant: Mark L. Bowers , David Buttaro , W. Michael Krebs
Inventor: Mark L. Bowers , David Buttaro , W. Michael Krebs
CPC classification number: G01N27/49
Abstract: An improved electrochemical detection cell comprising a palladium reference electrode.
Abstract translation: 一种改进的电化学检测电池,包括钯参比电极。
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公开(公告)号:US09637667B2
公开(公告)日:2017-05-02
申请号:US10822625
申请日:2004-04-12
Applicant: Michael Krebs , Katja Brosa , Andreas Brenger , Uwe Franken , Christoph Lohr
Inventor: Michael Krebs , Katja Brosa , Andreas Brenger , Uwe Franken , Christoph Lohr
IPC: C08G18/10 , C08G18/76 , C09J175/04
CPC classification number: C09J175/04 , C08G18/10 , C08G18/7671 , C08G18/307
Abstract: The present invention describes reaction products from 2,4′-diphenylmethane diisocyanate with a content of at least 95 wt. % of 2,4′ isomer with at least one polyether-polyol and/or polyalkylene glycol with a molecular weight of less than 1,000 and/or one crystalline or partly crystalline or vitreously amorphous polyester-polyol and optionally polyester-polyols and/or polyether-polyols which are liquid at room temperature and have molecular weights of greater than 1,000 can be converted into adhesive compositions which have a very low content of monomeric diisocyanate of less than 0.5, preferably less than 0.25 wt. %. Such hot melt adhesive compositions have a high melt stability and a low viscosity, in addition to the low content of monomeric diisocyanate.
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公开(公告)号:US20100184121A1
公开(公告)日:2010-07-22
申请号:US12691421
申请日:2010-01-21
Applicant: Hanns Misiak , Michael Krebs , Timothy O'Connell , Karl-Heinz Maurer , Cornelia Kluin , Inken Prüser
Inventor: Hanns Misiak , Michael Krebs , Timothy O'Connell , Karl-Heinz Maurer , Cornelia Kluin , Inken Prüser
CPC classification number: C08G18/289 , C09K3/1018
Abstract: The present invention relates to the use of enzymes and/or whole-cell catalysts for the removal of undesired by-products from crosslinkable preparations.
Abstract translation: 本发明涉及酶和/或全细胞催化剂用于从可交联制剂中除去不需要的副产物的用途。
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