N-(heterocyclylcarbonyl)sulfonamide herbicides
    1.
    发明授权
    N-(heterocyclylcarbonyl)sulfonamide herbicides 失效
    N-(杂环羰基)磺酰胺除草剂

    公开(公告)号:US6117821A

    公开(公告)日:2000-09-12

    申请号:US309432

    申请日:1999-05-11

    摘要: This invention relates to herbicidal N-(heterocyclylcarbonyl)sulfonamide compounds, compositions comprising N-(heterocyclylcarbonyl)sulfonamide herbicides and an agronomically acceptable carrier, and the use thereof as broad spectrum herbicides which are effective against both monocot and dicot weed species in both preemergence and postemergence applications. This invention also teaches methods of preparing these compounds as well as methods of using the compounds as herbicides.

    摘要翻译: 本发明涉及除草N-(杂环基羰基)磺酰胺化合物,包含N-(杂环基羰基)磺酰胺除草剂和农艺学上可接受的载体的组合物,以及其作为广谱除草剂的用途,其在芽前和芽前均有效地对单子叶植物和双子叶杂草物种 出生后应用程序。 本发明还教导了制备这些化合物的方法以及使用该化合物作为除草剂的方法。

    5-aryl-isoxazolinones and herbicidal use thereof
    3.
    发明授权
    5-aryl-isoxazolinones and herbicidal use thereof 失效
    5-芳基 - 异恶唑啉酮及其除草用途

    公开(公告)号:US5723414A

    公开(公告)日:1998-03-03

    申请号:US786573

    申请日:1997-01-21

    摘要: A class of 5-aryl-isoxazolinones and compositions thereof which are useful in the control of weeds is of the general formula ##STR1## wherein Ar is a substituted or unsubstituted aryl or heteroaryl; R.sup.2 is alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl or alkoxyalkyl, all of which may be substituted with one or more halogen atoms; R.sup.4 is alkynyl or alkoxyalkyl, both of which may be substituted with one or more halogen atoms; and X is an oxygen or a sulfur atom.

    摘要翻译: 一类可用于防治杂草的5-芳基 - 异恶唑啉酮及其组合物具有通式“IMAGE”,其中Ar是取代或未取代的芳基或杂芳基; R2是烷基,环烷基,烯基,环烯基,炔基或烷氧基烷基,它们都可以被一个或多个卤素原子取代; R4是炔基或烷氧基烷基,它们都可以被一个或多个卤素原子取代; X是氧或硫原子。

    Halopyridyl triazolinone herbicides and herbicidal use thereof
    4.
    发明授权
    Halopyridyl triazolinone herbicides and herbicidal use thereof 失效
    卤吡啶基三唑啉酮除草剂及其除草用途

    公开(公告)号:US5733849A

    公开(公告)日:1998-03-31

    申请号:US814515

    申请日:1997-03-10

    CPC分类号: C07D401/04 A01N43/653

    摘要: Disclosed are herbicidal halopyridyl triazolinones, herbicidal compositions comprising the halopyridyl triazolinones, and herbicidal use of the compounds and compositions. Such compounds and compositions are useful as both preemergence and postemergence herbicides in a variety of crops.

    摘要翻译: 公开了除草卤代吡啶基三唑啉酮,包含卤代吡啶基三唑啉酮的除草组合物,以及化合物和组合物的除草用途。 这种化合物和组合物可用作各种作物中的芽前和芽后除草剂。

    High pressure process to produce 2-aryl-3-substituted pyrimidione
herbicides
    5.
    发明授权
    High pressure process to produce 2-aryl-3-substituted pyrimidione herbicides 失效
    产生2-芳基-3-取代的嘧啶除草剂的高压法

    公开(公告)号:US6107485A

    公开(公告)日:2000-08-22

    申请号:US467867

    申请日:1999-12-20

    IPC分类号: C07D239/36 C07D401/04

    CPC分类号: C07D239/36 C07D401/04

    摘要: This invention describes a new and convenient single step process for preparing 2-aryl-3-substituted-4(3H)-pyrimidinone herbicides by reacting a N-substituted amidine (or its hydrohalide salt) with a .beta.-keto ester under conditions of high pressure. The 2-aryl-3-substituted pyrimidinone compounds produced by the process of the present invention are very useful as herbicidal agents for the control of weeds in agronomically important crops.

    摘要翻译: 本发明描述了一种用于通过N-取代的脒(或其氢卤酸盐)与β-酮酯在高的条件下反应来制备2-芳基-3-取代-4(3H) - 嘧啶酮除草剂的新的和方便的单步方法 压力。 通过本发明方法生产的2-芳基-3-取代的嘧啶酮化合物作为用于控制农业重要作物中的杂草的除草剂是非常有用的。

    Process for pyrimidinone compounds
    6.
    发明授权
    Process for pyrimidinone compounds 失效
    嘧啶酮化合物的方法

    公开(公告)号:US6054582A

    公开(公告)日:2000-04-25

    申请号:US207547

    申请日:1998-12-08

    摘要: This invention relates to a process for the preparation of pyrimidinone compounds of the formula ##STR1## wherein Ar is an optionally substituted aryl or heteroaromatic moiety,R.sup.3 is an optionally substituted alkyl, alkenyl or alkynyl,R.sup.5 is a hydrogen atom, halo, cyano or an optionally substituted alkyl, alkenyl, alkynyl, alkoxy or alkylthio, andR.sup.6 is a hydrogen atom, cyano, or an optionally substituted alkyl, cycloalkyl, alkenyl, alkynyl, aryl, aralkyl or heteroaryl. The process comprises reaction of an amidine and a malonic acid derivative to give a hydroxypyrimidinone followed by conversion of the resulting hydroxypyrimidinone to a sulfonyloxypyrimidinone followed by reaction of the resulting sulfonyloxypyrimidinone with an organometallic reagent to give the desired pyrimidinone. The hydroxypyrimidinones, wherein R.sup.6 is hydroxy and sulfonyloxypyrimidinones wherein R.sup.6 is a substituted sulfonyloxy moiety, are themselves new and useful intermediates in the preparation of the desired pyrimidinones.

    摘要翻译: 本发明涉及一种制备下式的嘧啶酮化合物的方法,其中Ar是任选取代的芳基或杂芳族部分,R 3是任选取代的烷基,烯基或炔基,R 5是氢原子,卤素,氰基或任选取代的 烷基,烯基,炔基,烷氧基或烷硫基,R6是氢原子,氰基或任意取代的烷基,环烷基,烯基,炔基,芳基,芳烷基或杂芳基。 该方法包括脒和丙二酸衍生物的反应,得到羟基嘧啶酮,随后将所得羟基嘧啶酮转化为磺酰氧基嘧啶酮,随后将所得的磺酰氧基嘧啶酮与有机金属试剂反应,得到所需的嘧啶酮。 其中R6是羟基的羟基嘧啶酮和其中R6是取代的磺酰氧基部分的磺酰氧基嘧啶酮本身是制备所需嘧啶酮的新的和有用的中间体。

    Process for pyrimidinone compounds

    公开(公告)号:US6051710A

    公开(公告)日:2000-04-18

    申请号:US207892

    申请日:1998-12-08

    摘要: This invention relates to a process for the preparation of pyrimidinone compounds of the formula ##STR1## wherein Ar is an optionally substituted aryl or heteroaromatic moiety,R.sup.3 is an optionally substituted alkyl, alkenyl or alkynyl,R.sup.5 is a hydrogen atom, halo, cyano or an optionally substituted alkyl, alkenyl, alkynyl, alkoxy or alkylthio, andR.sup.6 is a hydrogen atom, cyano, or an optionally substituted alkyl, cycloalkyl, alkenyl, alkynyl, aryl, aralkyl or heteroaryl.The process comprises reaction of an amidine and a malonic acid derivative to give a hydroxypyrimidinone followed by conversion of the resulting hydroxypyrimidinone to a sulfonyloxypyrimidinone followed by reaction of the resulting sulfonyloxypyrimidinone with an organometallic reagent to give the desired pyrimidinone. The hydroxypyrimidinones, wherein R.sup.6 is hydroxy and sulfonyloxypyrimidinones wherein R.sup.6 is a substituted sulfonyloxy moiety, are themselves new and useful intermediates in the preparation of the desired pyrimidinones.

    Process for pyrimidinone compounds
    8.
    发明授权
    Process for pyrimidinone compounds 失效
    嘧啶酮化合物的方法

    公开(公告)号:US5889184A

    公开(公告)日:1999-03-30

    申请号:US831174

    申请日:1997-04-02

    摘要: This invention relates to a process for the preparation of pyrimidinone compounds of the formula ##STR1## wherein Ar is an optionally substituted aryl or heteroaromatic moiety,R.sup.3 is an optionally substituted alkyl, alkenyl or alkynyl,R.sup.5 is a hydrogen atom, halo, cyano or an optionally substituted alkyl, alkenyl, alkynyl, alkoxy or alkylthio, andR.sup.6 is a hydrogen atom, cyano, or an optionally substituted alkyl, cycloalkyl, alkenyl, alkynyl, aryl, aralkyl or heteroaryl.The process comprises reaction of an amidine and a malonic acid derivative to give a hydroxypyrimidinone followed by conversion of the resulting hydroxypyrimidinone to a sulfonyloxypyrimidinone followed by reaction of the resulting sulfonyloxypyrimidinone with an organometallic reagent to give the desired pyrimidinone. The hydroxypyrimidinones, wherein R.sup.6 is hydroxy and sulfonyloxypyrimidinones wherein R.sup.6 is a substituted sulfonyloxy moiety, are themselves new and useful intermediates in the preparation of the desired pyrimidinones.

    摘要翻译: 本发明涉及一种制备下式的嘧啶酮化合物的方法,其中Ar是任选取代的芳基或杂芳族部分,R 3是任选取代的烷基,烯基或炔基,R 5是氢原子,卤素,氰基或 任选取代的烷基,烯基,炔基,烷氧基或烷硫基,R 6是氢原子,氰基或任选取代的烷基,环烷基,烯基,炔基,芳基,芳烷基或杂芳基。 该方法包括脒和丙二酸衍生物的反应,得到羟基嘧啶酮,随后将所得羟基嘧啶酮转化为磺酰氧基嘧啶酮,随后将所得的磺酰氧基嘧啶酮与有机金属试剂反应,得到所需的嘧啶酮。 其中R6是羟基的羟基嘧啶酮和其中R6是取代的磺酰氧基部分的磺酰氧基嘧啶酮本身是制备所需嘧啶酮的新的和有用的中间体。

    Various synergistic herbicidal compositions
    9.
    发明授权
    Various synergistic herbicidal compositions 失效
    各种协同除草组合物

    公开(公告)号:US5869425A

    公开(公告)日:1999-02-09

    申请号:US858427

    申请日:1997-05-19

    CPC分类号: A01N37/22

    摘要: The present invention relates to compositions, having herbicidal synergistic effects, comprising(i) propanil;(ii) a compound selected from asulam, butamifos and methazole; and(iii) an agronomically acceptable carrierfor the control of various grasses and broadleaf weeds in rice. More particularly, such compositions exhibit synergistic properties for selectively controlling weeds in rice, especially grassy weeds such is Barnyardgrass, Junglerice, Signalgrass and Sprangletop. This invention also relates to a method of controlling weed species in rice comprising applying a herbicidally effective amount of composition comprising (i) propanil, (ii) a compound selected from asulam, butamifos and methazole and (iii) an agronomically acceptable carrier to the weed, to the locus of the weed or to the growth medium of said weed.

    摘要翻译: 本发明涉及具有除草协同作用的组合物,其包含(i)脯氨酸; (ii)选自阿斯库姆,丁草胺和甲唑的化合物; 和(iii)用于控制水稻中各种草和阔叶杂草的农学上可接受的载体。 更具体地,这样的组合物显示出协同的性质,用于选择性地控制水稻中的杂草,特别是草地杂草,例如稗草,Junglerice,Signalgrass和Sprangletop。 本发明还涉及一种控制水稻杂草种类的方法,其中包括施用除草有效量的组合物,其包含(i)脯氨酸,(ii)选自阿斯鲁姆,butamifos和methazole的化合物和(iii)农艺学上可接受的载体至杂草 ,到杂草的位置或所述杂草的生长培养基。